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Investigation of Strongly Hydrophobic and Thick Porous Silicon Stain Films Properties

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Abstract

Porous silicon (PSi) structures with strong hydrophobicity have been achieved by chemical etching of p-type silicon substrates in a solution based on hydrofluoric acid solution (HF) and vanadium oxide (V2O5). The surface morphology and microstructure of the elaborated structured silicon surfaces were investigated using Scanning Electron Microscope (SEM), contact angle and Fourier Transform Infrared spectroscopy (FTIR). The results show that the obtained structures exhibit hierarchically porous surfaces with porous pillars of silicon (PPSi) and an important hydrophobicity of the surface. The electrical properties of those PPSi structures were investigated in presence of 10 ppm of NO2 gas. The response time was about 30s at room temperature. Our results demonstrate that PPSi/Si are highly hydrophobic for long time and suitable for applications in the field of self-cleaning and may be a good candidate in elaborating practical NO2 sensors.

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References

  1. Rahman A, Song G, Bhatt AI, Choy Wong Y, Wen C (2015). Adv Funct Mater 26(5):647–678

    Article  Google Scholar 

  2. Zhou W, Dai X, Fu TM, Xie C, Liu J, Lieber CM (2014). Nano Lett 14(3):1614–1619

    Article  CAS  Google Scholar 

  3. Zhang B, Jie J, Zhang X, Ou X, Zhang X (2017). ACS Appl Mater Interfaces 9(40):34527–34543

    Article  CAS  Google Scholar 

  4. Yang Y, Zhang H, Zhu G, Lee S, Lin Z-H, Wang ZL (2013). ACS Nano 7(1):785–790

    Article  CAS  Google Scholar 

  5. Ko MD, Rim T, Kim K, Meyyappan M, Baek CK (2015). Sci Rep 5:11646

    Article  Google Scholar 

  6. Lv J, Zhang T, Zhang P, Zhao Y, Li S (2018). Nanoscale Res Lett 13:110

    Article  Google Scholar 

  7. Fukata N, Subramani T, Jevasuwan W, Dutta M, Bando Y (2017). Small 13:1701713

    Article  Google Scholar 

  8. Wippermann S, He Y, Voros M, Galli G (2016). Appl Phys Rev 3:040807

    Article  Google Scholar 

  9. Chen C, Fan Y, Gu J, Wu L, Passerini S, Mai L (2018). J Phys D Appl Phys 51:11

    Google Scholar 

  10. Chan CK, Peng HL, Liu G, Mc Ilwrath K, Zhang XF, Huggins RA, Cui Y (2008). Nat Nanotechnol 3:31

    Article  CAS  Google Scholar 

  11. Dwivedi P, Dhanekar S, Das S (2018). Nanotechnology 29:275503

    Article  Google Scholar 

  12. Dwivedi P, Das S, Dhanekar S (2017). Superlattice Microst 104:547

    Article  CAS  Google Scholar 

  13. Hakim MMA, Lombardini M, Sun K, Giustiniano F, Roach PL, Davies DE, Howarth PH, Planque MRR, Morgan H, Ashburn P (2012). Nano Lett 12(4):1868

    Article  CAS  Google Scholar 

  14. Kolasinski KW, Barclay W (2013). Angew Chem Int Ed 52:6731–6734

    Article  CAS  Google Scholar 

  15. Kolasinski KW, Yadlovskiy J (2011). Phys Status Solidi C 8(6):1749–1753

    Article  CAS  Google Scholar 

  16. Sailor (2012) Porous silicon in practice: preparation, characterization and applications. Wiley, Weinheim, Germany

    Google Scholar 

  17. Kolasinski KW (2005). Curr Opin Solid State Mater Sci 9:73–83

    Article  CAS  Google Scholar 

  18. Barillaro G, Nannini A, Piotto M (2002). Sensors Actuators A 102:195–201

    Article  CAS  Google Scholar 

  19. Jane A, Dronov R, Hodges A, Voelcker NH (2009). Trends Biotechnol 27:230–239

    Article  CAS  Google Scholar 

  20. Li W, Ding C, Cai Y, Liu J, Wang L, Ren Q, XuM J (2018). Sensors 18:660

    Article  Google Scholar 

  21. Kandziolka M, Charlton JJ, Kravchenko II, Bradshaw J a, Merkulov I a, Sepaniak MJ, Lavrik NV (2013). Anal Chem 85:9031–9038

    Article  CAS  Google Scholar 

  22. Angelescu A, Kleps I, Mihaela M, Simion M, Neghina T, Petrescu S, Moldovan N, Paduraru C, Raducanu A (2003). Rev Adv Mater Sci 5:440–449

    Google Scholar 

  23. Xie C, Hanson L, Cui Y, Cui B (2011). Proc Natl Acad Sci U S A 108(10):3894–3899

    Article  CAS  Google Scholar 

  24. Mohamed Elsayed Y, Gouda A, Ismail Y, Swillam MA; (2018), Proc SPIE 10541; 1054127

  25. Park J-H, Gu L, von Maltzahn G, Ruoslahti E, Bhatia SN, Sailor MJ (2009). Nat Mater 8:331–336

    Article  CAS  Google Scholar 

  26. Oh J, Deutsch TG, Yuan H-C, Branz HM (2011). Energy Environ Sci 4:1690–1694

    Article  CAS  Google Scholar 

  27. Barberoglou M, Zorba V, Pagozidis A, Fotakis C, Stratakis E (2010). Langmuir 26:13007–13014

    Article  CAS  Google Scholar 

  28. Yeo CI, Kim JB, Song YM, Lee YT (2013). Nanoscale Res Lett 8:159

    Article  Google Scholar 

  29. Rong J, Masarapu C, Ni J, Zhang Z, Wei B (2010). ACS Nano 4:4683–4690

    Article  CAS  Google Scholar 

  30. Ge M, Fang X, Rong J, Zhou C (2013). Nanotechnology 24:422001

    Article  CAS  Google Scholar 

  31. Ayat M, Belhousse S, Boarino L, Gabouze N, Boukherroub R, Kechouane M (2014). Nanoscale Res Lett 9:482

    Article  Google Scholar 

  32. Li XJ, Hu X, Jia Y, Zhang YH (1999). Appl Phys Lett 75:2906–2908

    Article  CAS  Google Scholar 

  33. Xu H-J, Fu X-N, Sun X-R, Li X-J (2005). Acta Phys Sin 54:2352–2357

    CAS  Google Scholar 

  34. Koch BML, Amirfazli A, Elliott JAW (2014). J Phys Chem C 118:23777–23782

    Article  CAS  Google Scholar 

  35. Kalantar-zadeh K (2013) Sensors: an introductory course, vol. 9781461450528, pp. 1–196, 2013

    Book  Google Scholar 

  36. Boarino L, Baratto C, Geobaldo F, Amato G, Comini E, Rossi AM, Faglia G, Lerondel G, Sberveglieri G (2000). Mater Sci Eng B69–70:210–214

    Article  Google Scholar 

  37. Hui-Qing C, Ming H, Jing Z, Wei-Dan W (2012) Chin Phys B 21(5): 058201

  38. Pancheri L, Oton CJ, Gaburro Z, Soncini G, Pavesi L (2003). Sensors Actuators B 89:237–239

    Article  CAS  Google Scholar 

  39. Gaburro Z, Oton C, Pavesi L, Pancheri L (2004). Appl Phys Lett 84(22):4388–4390

    Article  CAS  Google Scholar 

  40. Li XJ, Chen SJ, Feng CY (2007). Sensors Actuators B 123:461–465

    Article  CAS  Google Scholar 

  41. Yan D, Li S, Liu S, Tan M, Cao M (2018). J Alloys Compd 735:718–727

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was funded under the Algerian General Directorate of Scientific Research and Technological Development (DGRSDT).

SEM characterizations and gas sensing experiments have been performed at the Nanofacility Division, Piemonte, Torino in the framework of the EU Project NAS-ERA.

A special acknowledgment, to Pr. Leigh T. Canham for his participation in the preparation of the present manuscript.

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Correspondence to Maha Ayat.

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Ayat, M., Kechouane, M., Yaddadene, C. et al. Investigation of Strongly Hydrophobic and Thick Porous Silicon Stain Films Properties. Silicon 11, 2669–2674 (2019). https://doi.org/10.1007/s12633-018-0055-2

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  • DOI: https://doi.org/10.1007/s12633-018-0055-2

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