Abstract
The silicide hexaboride (B6Si) was irradiated with 60Co at room temperature to study the structural changes and weight kinetics. The B6Si samples were irradiated using a gamma source with a dose rate (D) of 0.27 Gy/s. At adsorption dose range of 9.7, 48.5, 97, 145.5 and 194 kGy. The samples were analysed using X-ray diffraction (XRD) and Energy dispersive spectroscopy (EDS) to study the microstructural and composition changes. The XRD results showed the crystalline structure for the sample before and after irradiation (with gamma irradiation dose 9.7, 48.5 and 97 kGy). Amorphization of the sample began at the gamma irradiation dose of 145.5 kGy. Increase in gamma irradiation dose had an inverse effect on the activation energy and had a directly proportional effect on the lattice volume.
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References
Aghajanian MK, Morgan BN, Singh JR, Mears J, Wolfee RA (2002). Ceram Trans 134:527–539
Armas B, Male G, Salanoljbat D, Chatillon C, Allibert M (1981). J Less Comm Metal 82:245–254
Chen HM, Qi HY, Zheng F, Liu LB, Jin ZP (2009). J Alloys Compd 481:182–189
Garibov AA, Agaev TN, Mirzoev MN, Aliev SM (2015). Protec Metal Phys Chem Surf 51:527–532
Garibov AA, Agaev TN, Mirzoev MN, Aliev SM (2015). Russ J Phys Chem A 89:1939–1943
Jerome R, Volodymyr B, Jean-Francois H, Roland G (2004). J Solid State Chem 177:4167–4174
Jijun W, Wenhui M, Duzuo T, Binjie J, Bin Y, Dachun L, Yongnian D (2012). Proc Engin 31:297–301
Khattak CP, Joyce DB, Schmid F (2002). Sol Energy Mater Sol Cells 74:77–89
Liu YS, Zhang LT, Cheng LF (2009). Corros Sci 51:820–826
Mallick D, Kayal TK, Ghosh J, Chakrabarti OP, Biswas S, Maiti HS (2009). Ceram Int 35:1667–1669
Matsushitaa J, Komarnenib S (2001). Mater Res Bull 36:1083–1089
Murakami T, Inui H (2014). Tribol Int 74:38–45
Shi FM, Yin XW, Fan XM (2010). J Eur Ceram Soc 30:1955–1962
Tea KK, Jaeyun M, Bryan VS, Dongwon C, Calvin JG, Jae-Young J, Gang W, Ch R, Zhaowei L, Yu Q, Sungho J (2014). Nano Energy 9:32–40
Tong CQ, Cheng LF, Yin XW, Zhang LT, Xu YD (2008). Compos Sci Technol 68:602–607
Vlasse M, Slack GA, Garbauskas M, Kasper JS, Viala JC (1986). J Solid State Chem 63:31–45
Wu JJ, Mu WH, Yang B, Dai YN, Morita K (2009). Trans Nonferrous Metals Soc China 19:463–467
Xiaoyu C, Xiaowei Y, Xiaokang M, Xiaomeng F, Laifei C, Litong Z (2015). Ceram Int 41:1695–1700
Zaitsev AI, Kodentsov AA (2001). J Phase Equil 22:126–135
Zhang B, Lailei W, Zhihong L (2017). RSC Adv 26:16109–16118
Zlokazov VB, Chernyshev VV (1992). J Appl Crystallogr 25:447–451
Mirzayev MN, Mammadov KhF, Garibov RG, Askerov EB (2018). High Temp 56(3):374–377
Mirzayev MN, Mehdiyeva RN, Garibov RG, Ismayilova NA, Jabarov SH (2018). Moder Phyis Letter B 32(14):1850151
Asgerov EB, Ismailov DI, Mehdiyeva RN, Jabarov SH, Mirzayev MN, Kerimova EM, Dang NT (2018). J Surf Investig 12 (4):688–691
Mirzayev MN, Mehdiyeva RN, Mammadov KhF, Jabarov SH, Asgerov EB (2018). Phys Partic Nucl Let 15(6):673–677
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Mirzayev, M.N., Jabarov, S.H., Asgerov, E.B. et al. X-ray diffraction and thermodynamics kinetics of SiB6 under gamma irradiation dose. Silicon 11, 2499–2504 (2019). https://doi.org/10.1007/s12633-018-0039-2
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DOI: https://doi.org/10.1007/s12633-018-0039-2