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Study on the Mechanism of the Interactions Between the Dendritic Macromolecule PAMAM and Silicic Acids in Neutral Solution

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Abstract

In this work, a molecular modeling method was used to investigate the interactions between PAMAM with different generations and silica acid molecules in neutral solution. The calculated results show that adsorption interactions of silicic acid molecules with the generation 2.0 PAMAM molecule are stronger than those with the generation 1.5 PAMAM molecule. The adsorption interactions are dominated by electrostatic interactions, vdW interactions as well as O⋯H-O and C-H⋯O H- bond interactions. We qualitatively discuss the effect of PAMAM molecules on the silica polymerization in neutral solution, where the inhibition effect of generation 2.0 is better than that of generation 1.5. The theoretical discussion is in reasonable agreement with experiment results.

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References

  1. Dubin L (1985) US Patent: 4532047

  2. Weng PF (1995) Desalination 2:59–67

    Article  Google Scholar 

  3. Flikkema E, Jelfs KE, Bromley ST (2012) Chem Phys Lett 554:117–122

    Article  CAS  Google Scholar 

  4. Tomalia D, Baker H, Dewald J, Hall M, Kallos G, Martin S, Roeck J, Ryder J, Smith P (1985) Polym J 17:117–132

    Article  CAS  Google Scholar 

  5. Tomalia DA (2005) Prog Polym Sci 30:294–324

    Article  CAS  Google Scholar 

  6. Yiyun C, Jiepin Y (2005) Color Technol 121:72–75

    Article  Google Scholar 

  7. Diallo MS, Christie S, Swaminathan P, Johnson JH, Goddard WA (2005) Environ Sci Technol 39:1366–1377

    Article  CAS  PubMed  Google Scholar 

  8. Zhang B, Sun P, Chen F, Li F (2012) Colloids Surf A Physicochem Eng Asp 410:159–169

    Article  CAS  Google Scholar 

  9. Demadis KD (2005) J Chem Technol Biotechnol 80:630–640

    Article  CAS  Google Scholar 

  10. Mavredaki E, Neofotistou E, Demadis KD (2005) Ind Eng Chem Res 44:7019–7026

    Article  CAS  Google Scholar 

  11. Neofotistou E, Demadis KD (2004) Colloids Surf A: Phys Eng Aspects 242:213–216

  12. Neofotistou E, Demadis KD (2004) Desalination 167:257–272

    Article  CAS  Google Scholar 

  13. Hädicke E, Rieger J, Rau IU, Boeckh D (1999) Phys Chem Chem Phys 1:3891–3898

    Article  Google Scholar 

  14. Chen CY, Lei W, Xia MZ, Wang FY, Gong XD (2013) Desalination 309:208–212

    Article  CAS  Google Scholar 

  15. Chen CY, Lei W, Xia MZ, Wang FY, Gong XD (2012) JMM 18:4007–4012

    Article  CAS  Google Scholar 

  16. Shi WY, Lei W, Xia MZ, Wang FY (2013) Desalination 322:137–143

    Article  CAS  Google Scholar 

  17. Ritwiset A, Krongsuk S, Johns JR (2016) Appl Surf Sci 380:23–31

    Article  CAS  Google Scholar 

  18. Shi WY, Ding C, Yan JL, Han XY, Lv ZM, Lei W, Xia MZ, Wang FY (2012) Desalination 291:8–14

    Article  CAS  Google Scholar 

  19. Materials Studio 4.0 (2007) Accelrys, San Diego

  20. Sheikholeslami R, Tan S (1999) Desalination 126:267–280

    Article  CAS  Google Scholar 

  21. Bremere I, Kennedy M, Mhyio S, Jaljuli A, Witkamp GJ, Schippers J (2000) Desalination 3:89–100

    Article  Google Scholar 

  22. Sun H (1998) J Phys Chem B 102:7338–7364

    Article  CAS  Google Scholar 

  23. Chen G, Lei W, Xia MZ, Wang FY, Gong XD (2014) J Phys Chem A 118:11471–11478

    Article  CAS  PubMed  Google Scholar 

  24. Chen G, Lei W, Xia MZ, Wang FY, Gong XD (2014) Can J Chem 92:849–854

    Article  CAS  Google Scholar 

  25. Zhong T, Ai P, Zhou J (2011) Fluid Phase Equilib 302:43–47

    Article  CAS  Google Scholar 

  26. Desiraju GR (2002) Acc Chem Res 35:565–573

    Article  CAS  PubMed  Google Scholar 

  27. Li C, Choi P (2008) J Phys Chem C 112:10145–10152

    Article  CAS  Google Scholar 

  28. Falcone JS (1982) ACS Symposium Series

  29. Chan S, Chen Z, He P (1995) J Heat Transfer 117:323–328

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was funded by “Jiangsu Youth Funding Program BK20150464”.

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Authors and Affiliations

  1. School of Metallurgy and Materials Engineering, Jiangsu University of Science & Technology, Zhangjiagang, 215600, China

    C. Y. Chen, Y. Zhang, L. N. Jiao & N. Bai

  2. School of Chemical Engineering, Shangdong University and Technology, Shangdong, 255049, China

    S. G. Zhang

  3. Chemistry Department, Nanjing University of Science & Technology, Nanjing, 210094, China

    M. Z. Xia

Authors
  1. C. Y. Chen
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  2. Y. Zhang
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  3. L. N. Jiao
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  4. N. Bai
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  5. S. G. Zhang
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  6. M. Z. Xia
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Correspondence to C. Y. Chen.

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Chen, C.Y., Zhang, Y., Jiao, L.N. et al. Study on the Mechanism of the Interactions Between the Dendritic Macromolecule PAMAM and Silicic Acids in Neutral Solution. Silicon 10, 1497–1502 (2018). https://doi.org/10.1007/s12633-017-9632-z

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  • DOI: https://doi.org/10.1007/s12633-017-9632-z

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