Abstract
A study of optical and gamma rays shielding properties was performed in the glassy system of (70-x)%B2O3-x%Bi2O3-15%ZnO-15%Na2O where x = 5, 10, 15, 20, 25. The samples were prepared by the melt quenching technique. The amorphous nature of the glass samples was proved using x-ray diffraction. The optical absorption spectra were obtained and the band gap was estimated. The effect of bismuth on the structural properties of the studied glasses was investigated through density ρ and molar volume vm. Optical band gap and Urbach energy were evaluated using optical data of UV-Visible measurements. The Gamma ray attenuation coefficient was measured at gamma ray energies 88.99, 302, 356.01, 661.64, 1173.23 and 1332.51 keV emitted from 137Cs and 60Co radioactive sources. The mass attenuation coefficient measurements show that the investigated system exhibits promising shielding properties.
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Saeed A, El Shazly RM, Elbashar YH, Abou El-azm AM, El-Okr MM, Comsan MNH, Osman AM, Abdal-monem AM, El-Sersy AR (2014) Gamma ray attenuation in a developed borate glassy system. Radiat Phys Chem 102:167–170
Manohara SR, Hanagodimath SM, Gerward L (2009) Photon interaction and energy absorption in glass: a transparent gamma ray shield. J Nucl Mater 393(3):465–472
Singh H, Singh K, Gerward L, Singh K, Sahota HS, Nathuram R (2003) ZnO– PbO–B2O3 glasses as gamma-ray shielding materials. Nucl Instr Meth B 207(3):257–262
Singh K, Singh H, Sharma G, Gerward L, Khanna A, Kumar R, Nathuram R, Sahota HS (2005) Gamma-ray shielding properties of CaO–SrO–B2O3 glasses. Radiat Phys Chem 72:225–228
Singh K, Singh H, Sharma V, Nathuram R, Khanna A, Kumar R, Bhatti SS, Sahota HS (2002) Gamma-ray attenuation coefficient in bismuth borate glass. Nucl Instr Meth B 194(1):1–6
Singh KJ, Singh N, Kaundal RS, Singh K (2008) Gamma-ray shielding and structural properties of PbO–SiO2 glass. Nucl Instr Meth B 266 (6):944–948
Singh N, Singh KJ, Singh K, Singh H (2004) Comparative study of lead borate and bismuth lead borate glass system as gamma-radiation shielding materials. Nucl Instr Meth B 225:305– 309
Singh N, Singh KJ, Singh K, Singh H (2006) Gamma-ray attenuation studies of PbO–BaO–B2O3 glass system. Radiat Meas 41(1):84–88
Insiripong S, Chimalawong P, Kaewkhao J, Limsuawan P (2011) American J App Sci 8(6):574–578
Bhatia B, Parihar V, Singh S, Verma AS (2013) Spectroscopic properties of Pr3? in lithium bismuth borate glasses. Am J Condens Matter Phys 3(3):80–88
Kaur S, Singh GP, Kaur P, Singh DP (2013b) Cerium luminescence in borate glass and effect of aluminium on blue green emission of cerium ions. J Lumin 143:31–37
Prajna Shree M, Wagh A, Raviprakash Y, Sangeetha B, Kamath SD (2013) Characterization of Pr6O11 doped zinc fluoroborate glass. Eur Sci J 9(18):83–92
Srinivasa Rao CH, Rao MC, Srikumar T (2013) Optical absorption behaviour of NaF–Al2O3–B2O3 glass doped with Ho2O3. Int J Adv Pharm Biol Chem 2(3):549–553
Knoll GF (2002) Radiation detection and measurement. University of Michigan, Ann. Arbor
Limkitjaroenporn P, Kaewkhao J, Limsuwan P, Chewpraditkul W (2011) Physical optical structural and gamma-ray shielding properties of lead sodium borate glasses. J Phys Chem Solids 72:245–251
Arif B (2017) Determination of optical constants of ZnO growth by PECVD Method. J Mater Electron Devices 1:28–32
Dere A, Al-Ghamdi A (2017) Optical constants and dispersion energy parameters of n-type semi-insulating gallium phosphide single crystal wafer grown by liquid-encapsulated Czochralski (LEC) 1:67–71
Insiripong S, Chimalawong P, Kaewkhao J, Limsuwan P (2011) Optical and physical properties of bismuth borate glasses doped with Dy3?. Am J Appl Sci 8(6):574–578
Singh DP, Singh GP (2013) Conversion of covalent to ionic behavior of Fe2O3–CeO2–PbO–B2O3 glasses for ionic and photonic application. J Alloy Compd 546:224–228
Chakradhar RPS, Ramesh KP, Rao JL, Ramakrishna J (2003) Mixed Alkali Effect in Borate Glasses-EPR and Optical Absorption Studies in xNa2O-(30-x)-K2O-70B2O3 Glasses Doped with Mn+ 2. J Phys Chem Solids 64:641
Yasaka P, Pattanaboonmee N, Kim HJ, Limkitjaroenporn P, Kaewkhao J (2014) Gamma radiation shielding and optical properties measurements of zinc bismuth borate glasses. Ann Nucl Energy 68:4–9
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The authors extend their appreciation to the International Scientific Partnership Program ISPP at King Saud University for funding this research work through ISPP# 0046.
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Ghanem, A.H., Farag, A.T.M., Al-Sehemi, A.G. et al. Bismuth Borate Glass Based Nuclear Materials. Silicon 10, 1195–1201 (2018). https://doi.org/10.1007/s12633-017-9593-2
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DOI: https://doi.org/10.1007/s12633-017-9593-2