Abstract
Aqueous zinc-ion batteries (ZIBs) are deemed as the idea option for large-scale energy storage systems owing to many alluring merits including low manufacture cost, environmental friendliness, and high operations safety. However, to develop high-performance cathode is still significant for practical application of ZIBs. Herein, Ba0.23V2O5·1.1H2O (BaVO) nanobelts were fabricated as cathode materials of ZIBs by a typical hydrothermal synthesis method. Benefiting from the increased interlayer distance of 1.31 nm by Ba2+ and H2O pre-intercalated, the obtained BaVO nanobelts showed an excellent initial discharge capacity of 378 mAh·g−1 at 0.1 A·g−1, a great rate performance (e.g., 172 mAh·g−1 at 5 A·g−1), and a superior capacity retention (93% after 2000 cycles at 5 A·g−1).
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Acknowledgements
This work was supported by the National Natural Science Foundation of China (No. 21905037), the Doctoral research startup fund of Liaoning Province, China (No. 2020-BS-066), the China Postdoctoral Science Foundation (No. 2020M670719), and the Fundamental Research Funds for the Central Universities (No. 3132019328). Qiong-qiong Lu and Ai-kai Yang acknowledge the financial support from China Scholarship Council (CSC).
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Qin, Xh., Du, Yh., Zhang, Pc. et al. Layered barium vanadate nanobelts for high-performance aqueous zinc-ion batteries. Int J Miner Metall Mater 28, 1684–1692 (2021). https://doi.org/10.1007/s12613-021-2312-4
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DOI: https://doi.org/10.1007/s12613-021-2312-4