Effect of cryogenic rolling and annealing on the microstructure evolution and mechanical properties of 304 stainless steel

  • Jin-tao Shi
  • Long-gang HouEmail author
  • Jin-rong Zuo
  • Lin-zhong Zhuang
  • Ji-shan ZhangEmail author


Metastable 304 austenitic stainless steel was subjected to rolling at cryogenic and room temperatures, followed by annealing at different temperatures from 500 to 950°C. Phase transition during annealing was studied using X-ray diffractometry. Transmission electron microscopy and electron backscattered diffraction were used to characterize the martensite transformation and the distribution of austenite grain size after annealing. The recrystallization mechanism during cryogenic rolling was a reversal of martensite into austenite and austenite growth. Cryogenic rolling followed by annealing refined grains to 4.7 μm compared with 8.7 μm achieved under room-temperature rolling, as shown by the electron backscattered diffraction images. Tensile tests showed significantly improved mechanical properties after cryogenic rolling as the yield strength was enhanced by 47% compared with room-temperature rolling.


stainless steel cryogenic rolling annealing microstructural evolution mechanical properties recrystallization 


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This work was financially supported by the National Key Project of Research and Development Program of China (No. 2016YFB0300801), the National Natural Science Foundation of China (No. 51401016), and State Key Laboratory for Advanced Metals and Materials of China.


  1. [1]
    C. Herrera, R.L. Plaut, and A.F. Padilha, Microstructural refinement during annealing of plastically deformed austenitic stainless steels, Mater. Sci. Forum, 550(2007), p. 423.CrossRefGoogle Scholar
  2. [2]
    B.R. Kumar, S.K. Das, B. Mahato, and R.N. Ghosh, Role of strain-induced martensite on microstructural evolution during annealing of metastable austenitic stainless steel, J. Mater. Sci., 45(2010), No. 4, p. 911.CrossRefGoogle Scholar
  3. [3]
    A.F. Padilha, R.L. Plaut, and P.R. Rios, Annealing of cold-worked austenitic stainless steels, ISIJ Int., 43(2003), No. 2, p. 135.CrossRefGoogle Scholar
  4. [4]
    R.D.K. Misra, Z. Zhang, P.K.C. Venkatasurya, M.C. Somani, and L.P. Karjalainen, The effect of nitrogen on the formation of phase reversion-induced nanograined/ultrafine-grained structure and mechanical behavior of a Cr–Ni–N steel, Mater. Sci. Eng. A, 528(2011), No. 3, p. 1889.CrossRefGoogle Scholar
  5. [5]
    R.Z. Valiev, N.A. Krasilnikov, and N.K. Tsenev, Plastic deformation of alloys with submicron-grained structure, Mater. Sci. Eng. A, 137(1991), p. 35.CrossRefGoogle Scholar
  6. [6]
    D. Jia, Y.M. Wang, K.T. Ramesh, E. Ma, Y.T. Zhu, and R.Z. Valiev, Deformation behavior and plastic instabilities of ultrafine- grained titanium, Appl. Phys. Lett., 79(2001), No. 5, p. 611.CrossRefGoogle Scholar
  7. [7]
    Y. Iwahashi, J.T. Wang, Z. Horita, M. Nemoto, and T.G. Langdon, Principle of equal-channel angular pressing for the processing of ultra-fine grained materials, Scripta Mater., 35(1996), No. 2, p. 143.CrossRefGoogle Scholar
  8. [8]
    Y. Ivanisenko, R.K. Wunderlich, R.Z. Valiev, and H.J. Fecht, Annealing behaviour of nanostructured carbon steel produced by severe plastic deformation, Scripta Mater., 49(2003), No. 10, p. 947.CrossRefGoogle Scholar
  9. [9]
    F.K. Yan, N.R. Tao, and K. Lu, Tensile ductility of nanotwinned austenitic grains in an austenitic steel, Scripta Mater., 84-85(2014), p. 31.CrossRefGoogle Scholar
  10. [10]
    Y.F. Shen, X.X. Li, X. Sun, Y.D. Wang, and L. Zuo, Twinning and martensite in a 304 austenitic stainless steel, Mater. Sci. Eng. A, 552(2012), p. 514.CrossRefGoogle Scholar
  11. [11]
    J.L. Lv and H.Y. Luo, Effect of nano/ultrafine grain with orientation obtained by reversion transformation on tensile behaviour of austenitic stainless steel, Mater. Sci. Technol., 29(2013), No. 4, p. 456.CrossRefGoogle Scholar
  12. [12]
    K.L. Ye, H.Y. Luo, and J.L. Lv, Producing nanostructured 304 stainless steel by rolling at cryogenic temperature, Mater. Manuf. Processes, 29(2014), No. 6, p. 754.CrossRefGoogle Scholar
  13. [13]
    M.A. Meyers, Y.B. Xu, Q. Xue, M.T. Pérez-Prado, and T.R. McNelley, Microstructural evolution in adiabatic shear localization in stainless steel, Acta Mater., 51(2003), No. 5, p. 1307.CrossRefGoogle Scholar
  14. [14]
    L. Lu, X.H. Chen, X.X. Huang, and K. Lu, Revealing the maximum strength in nanotwinned copper, Science, 323(2009), No. 5914, p. 607.CrossRefGoogle Scholar
  15. [15]
    W.S. Lee and C.F. Lin, Comparative study of the impact response and microstructure of 304L stainless steel with and without prestrain, Metall. Trans. A, 33(2002), No. 9, p. 2801.CrossRefGoogle Scholar
  16. [16]
    W.S. Lee, C.F. Lin, T.H. Chen, and M.C. Yang, High temperature microstructural evolution of 304L stainless steel as function of pre-strain and strain rate, Mater. Sci. Eng. A, 527(2010), No. 13-14, p. 3127.CrossRefGoogle Scholar
  17. [17]
    P.L. Sun, Y.H. Zhao, J.C. Cooley, M.E. Kassner, Z. Horita, T.G. Langdon, E.J. Lavernia, and Y.T. Zhu, Effect of stacking fault energy on strength and ductility of nanostructured alloys: an evaluation with minimum solution hardening, Mater. Sci. Eng. A, 525(2009), No. 1-2, p. 83.CrossRefGoogle Scholar
  18. [18]
    Y.F. Shen, X.M. Zhao, X. Sun, Y.D. Wang, and L. Zuo, Ultrahigh strength of ultrafine grained austenitic stainless steel induced by accumulative rolling and annealing, Scripta Mater., 2014. Scholar
  19. [19]
    B.R. Kumar and D. Raabe, Tensile deformation characteristics of bulk ultrafine-grained austenitic stainless steel produced by thermal cycling, Scripta Mater., 66(2012), No. 9, p. 634.CrossRefGoogle Scholar
  20. [20]
    S. Sabooni, F. Karimzadeh, M.H. Enayati, and A.H.W. Ngan, The role of martensitic transformation on bimodal grain structure in ultrafine grained AISI 304L stainless steel, Mater. Sci. Eng. A, 636(2015), p. 221.CrossRefGoogle Scholar
  21. [21]
    J. Das, Evolution of nanostructure in a-brass upon cryorolling, Mater. Sci. Eng. A, 530(2011), No. 1, p. 675.CrossRefGoogle Scholar
  22. [22]
    B. Roy, N.K. Kumar, P.M.G. Nambissan, and J. Das, Evolution and interaction of twins, dislocations and stacking faults in rolled a-brass during nanostructuring at sub-zero temperature, AIP Adv., 4(2014), No. 6, art. No. 067101.Google Scholar
  23. [23]
    N.K. Kumar, B. Roy, and J. Das, Effect of twin spacing, dislocation density and crystallite size on the strength of nanostructured a-brass, J. Alloys Compd., 618(2015), p. 139.CrossRefGoogle Scholar
  24. [24]
    V.A. Moskalenko, A.R. Smirnov, and R.V. Smolyanets, Low-temperature plastic deformation and strain-hardening of nanocrystalline titanium, Low Temp. Phys., 40(2014), p. 837.CrossRefGoogle Scholar
  25. [25]
    B. Roy, R. Kumar, and J. Das, Effect of cryorolling on the microstructure and tensile properties of bulk nano-austenitic stainless steel, Mater. Sci. Eng. A, 631(2015), p. 241.CrossRefGoogle Scholar
  26. [26]
    P.Y. Li, Y. Xiong, L.F. Chen, F.Z. Ren, and X.G. Wang, Effect of cryorolling on microstructure and mechanical properties of AISI 310S stainless steel, Trans. Mater. Heat Treat., 36(2015), No. 3, p. 112.Google Scholar
  27. [27]
    Y. Xiong, J.B. Wang, L.F. Chen, Y. Lu, F.Z. Ren, L.L. Zhang, and J.L. Ma, Effect of annealing process on microstructure and mechanical properties of cryorolled AISI310S austenite stainless steel, Trans. Mater. Heat Treat., 37(2016), No. 4, p. 101.Google Scholar
  28. [28]
    J.T. Shi, L.G. Hou, J.R. Zuo, L. Lu, H. Cui, and J.S. Zhang, Quantitative analysis of the martensite transformation and microstructure characterization during cryogenic rolling of a 304 austenitic stainless steel, Acta Metall. Sin., 52(2016), No. 8, p. 945.Google Scholar
  29. [29]
    N.H. Moser, T.S. Gross, and Y.P. Korkolis, Martensite formation in conventional and isothermal tension of 304 austenitic stainless steel measured by X-ray diffraction, Metall. Mater. Trans. A, 45(2014), No. 11, p. 4891.CrossRefGoogle Scholar
  30. [30]
    B.D. Cullity and S.R. Stock, Elements of X-ray Diffraction, 3rd Ed., Prentice Hall, New Jersey, 2001, p. 40.Google Scholar
  31. [31]
    A.K. De, D.C. Murdock, M.C. Mataya, J.G. Speer, and D.K. Matlock, Quantitative measurement of deformation-induced martensite in 304 stainless steel by X-ray diffraction, Scripta Mater., 50(2004), No. 12, p. 1445.CrossRefGoogle Scholar
  32. [32]
    X.M. Huang and T. Jie, Material Analysis Test Method, National Defense Industry Press, Beijing, 2008, p. 206.Google Scholar
  33. [33]
    Z.Y. Xu, Martensite Transformation and Martensite, Science Press, Beijing, 1980, p. 479.Google Scholar
  34. [34]
    T. Shintani and Y. Murata, Evaluation of the dislocation density and dislocation character in cold rolled type 304 steel determined by profile analysis of X-ray diffraction, Acta Mater., 59(2011), No. 11, p. 4314.CrossRefGoogle Scholar
  35. [35]
    W.M. Mao and X.B. Zhao, Recrystallization and Grain Growth, Metallurgical Industry Press, Beijing, 1994, p. 218.Google Scholar
  36. [36]
    F. Forouzan, A. Kermanpur, A. Najafizadeh, and A. Hedayati, Processing of nano/submicron grained stainless steel 304L by an advanced thermomechanical process, Int. J. Mod. Phys. Conf. Ser., 5(2012), p. 383.CrossRefGoogle Scholar
  37. [37]
    I. Shakhova, V. Dudko, A. Belyakov, K. Tsuzaki, and R. Kaibyshev, Effect of large strain cold rolling and subsequent annealing on microstructure and mechanical properties of an austenitic stainless steel, Mater. Sci. Eng. A, 545(2012), p. 176.CrossRefGoogle Scholar
  38. [38]
    Y.Q. Ma, J.E. Jin, and Y.K. Lee, A repetitive thermomechanical process to produce nano-crystalline in a metastable austenitic steel, Scripta Mater., 52(2005), No. 12, p. 1311.CrossRefGoogle Scholar

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© University of Science and Technology Beijing and Springer-Verlag Berlin Heidelberg 2017

Authors and Affiliations

  1. 1.State Key Laboratory for Advanced Metals and MaterialsUniversity of Science and Technology BeijingBeijingChina

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