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Characterization of structural and electrical properties of ZnO tetrapods

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Abstract

ZnO tetrapods were synthesized by a typical thermal vapor-solid deposition method in a horizontal tube furnace. Structural characterization was carried out by transmission electron microscopy (TEM) and select-area electron diffraction (SAED), which shows the presence of zinc blende nucleus in the center of tetrapods while the four branches taking hexagonal wurtzite structure. The electrical transport property of ZnO tetrapods was investigated through an in-situ nanoprobe system. The three branches of a tetrapod serve as source, drain, and “gate”, respectively; while the fourth branch pointing upward works as the force trigger by vertically applying external force downward. The conductivity of each branch of ZnO-tetrapods increases 3–4 times under pressure. In such situation, the electrical current through the branches of ZnO tetrapods can be tuned by external force, and therefore a simple force sensor based on ZnO tetrapods has been demonstrated for the first time.

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References

  1. Z.L. Wang, ZnO nanowire and nanobelt platform for nanotechnology, Mater. Sci. Eng. R., 64(2009), No.3-4, p.33.

    Article  Google Scholar 

  2. M.H. Huang, Y.Y. Wu, H. Feick, et al., Catalytic growth of zinc oxide nanowires by vapor transport, Adv. Mater., 13(2001), No.2, p.113.

    Article  Google Scholar 

  3. Z.W. Pan, Z.R. Dai, and Z.L. Wang, Nanobelts of semiconducting oxides, Science, 291(2001), No.5510, p.1947.

    Article  Google Scholar 

  4. X.Y. Kong, Y. Ding, R.S. Yang, and Z.L. Wang, Single-crystal nanorings formed by epitaxial self-coiling of polar nanobelts, Science, 303(2004), No.5662, p.1348.

    Article  Google Scholar 

  5. P.X. Gao, Y. Ding, W.J. Mai, et al., Conversion of zinc oxide nanobelts into superlattice-structured nanohelices, Science, 309(2005), No.5741, p.1700.

    Article  Google Scholar 

  6. J. Carrasco, F. Illas, and S.T. Bromley, Ultralow-density nanocage-based metal-oxide polymorphs, Phys. Rev. Lett., 99(2007), No.23, art. No.235502.

  7. Y. Dai, Y. Zhang, Q.K. Li, and C.W. Nan, Synthesis and optical properties of tetrapod-like zinc oxide nanorods, Chem. Phys. Lett., 358(2002), No.1–2, p.83.

    Article  Google Scholar 

  8. A. Tsukazaki, A. Ohtomo, T. Onuma, et al., Repeated temperature modulation epitaxy for p-type doping and light-emitting diode based on ZnO, Nat. Mater., 4(2005), No.1, p.42.

    Article  Google Scholar 

  9. J.J. Cole, X. Wang, R.J. Knuesel, and H.O. Jacobs, Integration of ZnO microcrystals with tailored dimensions forming light emitting diodes and UV photovoltaic cells, Nano Lett., 8(2008), No.5, p.1477.

    Article  Google Scholar 

  10. C.S. Lao, Q. Kuang, Z.L. Wang, et al., Polymer functionalized piezoelectric-FET as humidity/chemical nanosensors, Appl. Phys. Lett., 90(2007), No.26. art. No.262107.

  11. J. Zhou, Y.D. Gu, P. Fei, et al., Flexible piezotronic strain sensor, Nano Lett., 8(2008), No.9, p.3035.

    Article  Google Scholar 

  12. J. Zhou, Y.D. Gu, Y.F. Hu, et al., Gigantic enhancement in response and reset time of ZnO UV nanosensor by utilizing Schottky contact and surface functionalization, Appl. Phys. Lett., 94(2009), No.19, art. No.191103.

  13. M.H. Huang, S. Mao, H. Feick, et al., Room-temperature ultraviolet nanowire nanolasers, Science, 292(2001), No.5523, p.1897.

    Article  Google Scholar 

  14. M. Law, L.E. Greene, J.C. Johnson, et al., Nanowire dye-sensitized solar cells, Nat. Mater., 4(2005), No.6, p.455.

    Article  Google Scholar 

  15. Z.L. Wang and J.H. Song, Piezoelectric nanogenerators based on zinc oxide nanowire arrays, Science, 312(2006), No.5771, p.242.

    Article  Google Scholar 

  16. Z.L. Wang, Towards self-powered nanosystems: from nanogenerators to nanopiezotronics, Adv. Funct. Mater., 18(2008), No.22, p.3553.

    Article  Google Scholar 

  17. Y. Ding, Z.L. Wang, T.J. Sun, and J.S. Qiu, Zinc-blende ZnO and its role in nucleating wurtzite tetrapods and twinned nanowires, Appl. Phys. Lett., 90(2007), No.15, art.No.153510.

  18. Y. Cui, U. Banin, M.T. Bjork, and A.P. Alivisatos, Electrical transport through a single nanoscale semiconductor branch point, Nano Lett., 5(2005), No.7, art. No.1519.

  19. Z.X. Zhang, L.F. Sun, Y.C. Zhao, et al., ZnO tetrapods designed as multiterminal sensors to distinguish false responses and increase sensitivity, Nano Lett., 8(2008), No.2, p.652.

    Article  Google Scholar 

  20. J. Zhou, P. Fei, Y.D. Gu, et al., Piezoelectric-potential-controlled polarity-reversible Schottky diodes and switches of ZnO wires, Nano Lett., 8(2008), No.11, p.3973.

    Article  Google Scholar 

  21. Y.D. Gu, J. Zhou, W.J. Mai, et al., Measuring the transport property of ZnO tetrapod using in-situ nanoprobes, Chem. Phys. Lett., 484(2010), No.1, p.96.

    Article  Google Scholar 

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Correspondence to Wen-jie Mai.

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This work was financially supported by the China Scholarship Council (CSC) (No.20083019), Fundamental Research Funds for the Central Universities (Nos.21611603, 21611424, and 216113143), Jinan University Start-up Funds (No.50624019), and the Knowledge Innovation Program of the Chinese Academy of Sciences (No.KJCX2-YW-M13).

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Gu, Yd., Mai, Wj. & Jiang, P. Characterization of structural and electrical properties of ZnO tetrapods. Int J Miner Metall Mater 18, 686–690 (2011). https://doi.org/10.1007/s12613-011-0497-7

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  • DOI: https://doi.org/10.1007/s12613-011-0497-7

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