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Journal of Optics

, Volume 46, Issue 2, pp 149–157 | Cite as

Synthesis, growth, structural, thermal, dielectric, linear and nonlinear optical studies of 2-amino 6-methylpyridinium salicylate single crystal

  • S. Venda
  • G. Peramaiyan
  • M. NizamMohideen
  • G. Vinitha
  • S. Srinivasan
Research Article
  • 116 Downloads

Abstract

Single crystal of 2-amino 6-methylpyridinium salicylate (2A6MPS) was grown for the first time by the slow evaporation method. Single crystal X-ray diffraction analysis was employed to estimate the cell parameters of the grown crystal. The third order nonlinear optical properties of 2A6MPS was studied by the Z-scan technique using 532 nm diode pumped CW Nd:YAG laser. Nonlinear refractive index, nonlinear absorption coefficient and nonlinear susceptibility of the grown crystal were found to be 10−8 cm2/W, 10−4 cm/W and 10−6 esu, respectively. Thermal stability of 2A6MPS was studied by thermogravimetry (TG) and differential thermal analyses (DTA). The optical transmittance window and the lower cut-off wavelength of 2A6MPS were identified by UV–Vis–NIR studies. From the dielectric measurements, the relative dielectric permittivities ε11 and ε33 values were determined.

Keywords

Crystal structure Crystal morphology Growth from solutions Single crystal growth Organic compounds Nonlinear optical materials 

References

  1. 1.
    G.R. Desiraju, Engineering: from molecule to crystal. J. Am. Chem. Soc. 135, 9952 (2013)CrossRefGoogle Scholar
  2. 2.
    B. Ruiz, M. Jazbinsek, P. Günter, Handbook of organic materials for optical and (opto) electronic devices. Cryst. Growth Des. 8, 4173 (2008)CrossRefGoogle Scholar
  3. 3.
    L.L. Wen, Z.D. Lu, X.M. Ren, C.Y. Duan, Q.J. Meng, S. Gao, A two-dimensional rare earth metal-organic polymer with 3-carboxylate-4-sulfonatophenolate ligands. Cryst. Growth Des. 9, 227 (2009)CrossRefGoogle Scholar
  4. 4.
    M. Dhavamurthy, G. Peramaiyan, R. Mohan, Synthesis, growth, structural, thermal, dielectric and mechanical studies of an organic guanidinium p-nitroohenolate crystal. J. Cryst. Growth 399, 13 (2014)ADSCrossRefGoogle Scholar
  5. 5.
    P.V. Dhanaraj, N.P. Rajesh, J. Kalyana Sundar, S. Natarajan, G. Vinitha, Studies on growth, crystal structure and characterization of novel organic nicotinium trifluoroacetate single crystals. Mater. Chem. Phys. 129, 457 (2011)CrossRefGoogle Scholar
  6. 6.
    S. Manivannan, S. Dhanuskodi, K. Kirschbaum, S.K. Tiwari, Design of an efficient solution grown semiorganic NLO crystal for short wavelength generation: 2-amino-5-nitropyridinium tetrafluoroborate. Cryst. Growth Des. 5, 1463 (2005)CrossRefGoogle Scholar
  7. 7.
    Bruker APEX2, SAINT, XPREP and SADABS, Bruker AXS Inc., Madison, Wisconsin, USA (2004)Google Scholar
  8. 8.
    G.M. Sheldrick, A short history of SHELX. Acta Cryst. 64, 112–122 (2008)CrossRefGoogle Scholar
  9. 9.
    F.P. Anderson, J.F. Gallagher, P.T.M. Kenny, A.J. Lough, Bis(4-amino-pyridinium) tetra-chlorido-cobaltate(II). Acta Cryst. 61, o1351–o1353(2005)Google Scholar
  10. 10.
    K.S.S. Babu, G. Peramaiyan, M. NizamMohideen, R. Mohan, Crystal structure of 2-amino-5-nitro-pyridinium sulfamate. Acta Cryst. 70, o391–o392 (2014)Google Scholar
  11. 11.
    K. Syed Suresh Babu, G. Peramaiyan, M. NizamMohideenb, R. Mohana, 2-Amino-6-methyl-pyridinium 4-methyl-benzene-sulfonate. Acta Cryst. 70, o600–o601 (2014)Google Scholar
  12. 12.
    M.A. Rajkumar, S.S.J. Xavier, S. Anbarasu, P.A. Devarajan, M. NizamMohideen, 2-Amino-5-nitro-pyridinium hydrogen oxalate. Acta Cryst. 70, 473 (2014)Google Scholar
  13. 13.
    J. Bernstein, R.E. Davis, L. Shimoni, N.L. Chang, Patterns in hydrogen bonding: functionality and graph set analysis in crystals. Angew. Chem. Int. Ed. Engl. 34, 1555 (1995)CrossRefGoogle Scholar
  14. 14.
    O. Allen, F.H. Kennard, D.G. Watson, L. Brammer, A.G. Orpen, R. Taylor, Table of bond lengths determined by X-ray and neutron diffraction. J. Chem. Soc. Perkin Trans. 2, 1 (1987)CrossRefGoogle Scholar
  15. 15.
    I. Nahringbauer, A. Kvick, 2-Amino-5-methylpyridine. Acta Cryst. 33, 2902 (1977)CrossRefGoogle Scholar
  16. 16.
    H. Ishikawa, K. Iwata, H. Hamaguchi, Picosecond dynamics of stepwise double proton-transfer reaction in the excited state of the 2-aminopyridine/acetic acid system. J. Phys. Chem. 106, 2305 (2002)CrossRefGoogle Scholar
  17. 17.
    Z.M. Jin, Y.J. Pan, M.L. Hu, L. Shen, Crystal structure of 2-amino-3-methylpyridinium ortho-phthalate. J. Chem. Crystallogr. 31, 191 (2001)CrossRefGoogle Scholar
  18. 18.
    C. Balarew, R. Dehlew, Application of the hard and soft acids and bases concept to explain ligand coordination in double salt structures. J. Solid State Chem. 55, 1 (1984)ADSCrossRefGoogle Scholar
  19. 19.
    G. Peramaiyan, P. Pandi, R. Mohan Kumar, Bulk growth, optical, thermal, dielectric and mechanical studies of nonlinear optical crystal Triethylaminium picrate. J. Therm. Anal. Calorim. 9, 119 (2015)Google Scholar
  20. 20.
    B.M. Sornamurthy, G. Peramaiyan, P. Pandi, S. Das, G. Bhagavannarayana, V. Manivannan, R. MohanKumar, Studies on the growth, thermal and optical properties of 4-aminopyridinium p-aminobenzoate dihydrate single crystals. J. Cryst. Growth 397, 1 (2014)ADSCrossRefGoogle Scholar
  21. 21.
    G.C. Bhar, R.C. Smith, Phys. Status Solidi 13, 157 (1972)ADSCrossRefGoogle Scholar
  22. 22.
    G. Peramaiyan, G. Bhagavannarayana, R. Mohan Kumar, Crystal growth, structural, optical and dielectric studies of ammonium p-toluenesulfonate. J. Cryst. Growth 408, 14 (2014)ADSCrossRefGoogle Scholar
  23. 23.
    M. Sheik-Bahae, A.A. Said, T.H. Wei, D.J. Hagan, E.W. Van stryland, Sensitive measurement of optical nonlinearities using a single beam. IEEE J. Quantum Electron. 26, 760 (1990)ADSCrossRefGoogle Scholar
  24. 24.
    T.D. Krauss, F.W. Wise, Femtosecond measurement of nnonlinear absorption and refraction in CdS, ZnSe and ZnS. Appl. Phys. Lett. 65, 1739 (1994)ADSCrossRefGoogle Scholar
  25. 25.
    T. Cassano, R. Tommasi, M. Ferrara, F. Babudri, G.M. Farinola, F. Naso, Substituent-dependence of the optical nonlinearities in poly(2,5-dialkoxy-p-phenylenevinylene) polymers investigated by the Z-scan technique. Chem. Phys. 272, 111 (2001)ADSCrossRefGoogle Scholar
  26. 26.
    N. Ramamurthy, S. Dhanuskodi, M.V. Manjusha, J. Philip, Low power CW optical limiting properties of bis(2-aminopyridinium)-succinate-succinic acid (2APS) single crystal. Opt. Mater. 33, 607 (2011)ADSCrossRefGoogle Scholar

Copyright information

© The Optical Society of India 2016

Authors and Affiliations

  • S. Venda
    • 1
  • G. Peramaiyan
    • 2
  • M. NizamMohideen
    • 3
  • G. Vinitha
    • 4
  • S. Srinivasan
    • 1
  1. 1.Department of PhysicsPresidency CollegeChennaiIndia
  2. 2.Department of PhysicsVel Tech UniversityChennaiIndia
  3. 3.Department of PhysicsThe New College (Autonomous)ChennaiIndia
  4. 4.Department of PhysicsVIT UniversityChennaiIndia

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