Abstract
The present paper reports an important amount of Ti-V-Ga and REE enrichments in the hitherto-unreported eighteen bodies of ferruginous and aluminous laterite capping over the Dhandraul Formation of the Vindhyan Supergroup, Eastern India. It is brown to deep reddish-brown, limonitic, massive, and having a pisolitic form which is mainly rounded to subrounded and filled up of clay, bauxite, limonite, hematite, goethite, and surface encrustation of ferruginous material. Laterites are chiefly composed of ferruginous minerals like hematite, magnetite along with secondary jaspery material and limonite, goethite, in association with silicates and clay minerals. The analyzed samples show high values of Ti, V, Ga, and LREE like La, Ce, Pr, Nd, and Eu along with some significant values of Sm, Gd, Dy, and Yb. TiO2 value is ranging from 0.72 to 18.84 % with an average of 9.77 wt. % which is twenty-two times higher than the crustal abundance. Values of vanadium vary from 48 to 1163 ppm with an average of 593 ppm, and gallium varies from 9 to 90 ppm with an average of 47 ppm, and these values are three to five times higher than the crustal abundance. The “REE is varying from 208.81 to 899.31 ppm with an average of 484.49 ppm which is three times higher than the crustal abundance. The other significant trace elements identified are in ppm: Co (5–135), Cr (76–970), Cu (5–17), Ni (7–48), Pb (6–143), and Zn (14–231 ppm). This finding has got an enormous impact on the future Ti-V-Ga and REE exploration in the Vindhyan Supergroup in the state of Bihar.
Similar content being viewed by others
References
Aleva, G.J.J. (1994) Laterites: Concepts, Geology, Morphology and Chemistry. International Soil Reference and Information Centre, Wageningen, the Netherlands, 169p.
Auden, J.B. (1933) Vindhyan Sedimentation in the Son Valley, Mirzapur District. Mem. Geol. SurvIndia, v.62(2), pp.141–250.
Bao, Z. and Zhao, Z. (2008) Geochemistry of mineralization with exchangeable REY in the weathering crusts of granitic rocks in South China. Ore GeolRev., v.33(3), pp.519–535.
Banerjee, I. (1974) Barrier coastline sedimentation model and the Vindhyan example. Jour. Geol. Min. Metall. SocIndia (Golden Jubilee), v.46, pp.101–127.
Bengtson, S., Sallstedt, T., Belivanova, V. and Whitehouse, M. (2017) Three-dimensional preservation of cellular and subcellular structures suggests 1.6 billion year- old crown-group red algae. PLoS Bio. v.15(3), pp. 1–38. DOI:https://doi.org/10.1371/journal.pbio., 2000735.
Bhattacharyya, A. (1996) Recent Advances in Vindhyan Geology. Mem. Geol. Soc. India, v.36, 331p.
Bhattacharyya, A. and Pal, T. (1986) Kaimur Sandstone along Chunar-Mirzapur Belt, Mirzapur District, Uttar Pradesh: A possible Proterozoic braided river deposit. Jour. Indian AssocSedi., v.6, pp.76–92.
Bhattacharya, A. and Morad, S. (1993) Proterozoic braided ephemeral fluvial deposits: an example from the Dhandraul Sandstone Formation of the Kaimur Group, Son Valley, Central India. Sedi. Geol., v.84(1–4), pp.101–114.
Bose, P.K., Sarkar, S., Chakraborty, S. and Banerjee, S. (2001) Overview of Meso- to Neoproterozoie evolution of the Vindhyan basin, Central India (1.4–0.55 Ga). SediGeol., v.141, pp.395–419.
Boynton, W.V. (1983) Cosmochemistry of the rare earth elements; meteorite studies. In:Henderson, P. (Ed.), Rare Earth Element Geochemistry, Elsevier, pp.63–114.
Chowdhury, R.M.K. (1986) Concepts on the origin of Indian laterite in historical perspective. Pro. Indian Nat. Sci. Aca., v.52A(6), pp.1307–1323.
Chowdhury, R.M.K., Venkatesh, V., Anandalwar, M.A. and Paul, D.K. (1965) Recent concepts on the origin of Indian laterite. Pro. Nat. Aca. Sci., India, Sec. A: Phy.l Sci., v.31A(6), pp.547–558.
Crawford A.R. and Compston, W. (1970) The age of Vindhyan system of peninsular India. Quar. Jour. Geol. SocLondon, v.125, pp.351–371.
Das, R., Halder, S. and Mahanta, B.N. (2019) Classification and genetic consideration of laterites of West Khasi Hills, Meghalaya. Indian JourGeosci., v.73(4), pp.281–290.
Gopalan, K., Kumar, S. and Vijayagopala, B. (2013) Depositional history of the Upper Vindhyan succession, central India: Time constraints from Pb-Pb isochron ages of its carbonate components. PrecamRes., v.233, pp.108–117.
Gu, J., Huang, Z., Fan, H., Jin, Z., Yan, Z. and Zhang, J. (2013) Mineralogy, geochemistry, and genesis of lateritic bauxite deposits in the Wuchuan-Zheng’an-Daozhen area, Northern Guizhou Province, China. Jour. GeochemExpl., v.130, pp.44–59.
Hass, J.R., Shock, E.L. and Sassani, D.C. (1995) Rare earth elements in hydrothermal system: Estimates of standard partial model thermodynamic properties of aqueous complexes of the rare earth elements at high pressure and temperature. Geochi. CosmochimActa, v.59(21), pp.4329–4350.
Krauskopf, K.B. (1967) Introduction to Geochemistry. McGraw-Hill International Series in the Earth and Planetary Sciences, McGraw-Hill Book Co., New York, 721p.
Maurya, A.K. and Dzuvichu, N. (2019) Final report on reconnaissance survey for strategic minerals (Ti, V, Ga) in laterite exposed in and around Adhaura area, parts of toposheet no. 63P/9 &10, Kaimur district, Bihar. Unpub. Rep. Geol. Surv. India, F.S. 2017–19.
Meenal, M. and Shinjana, S. (2008a) Geochemical Control on Grain Size Variation in Sedimentary Rocks of Kaimur Group from Vindhyan Supergroup, Markundi Ghat, Sonbhadra District (U.P.). [M]. 95th Indian Sci. Cong., Vishakapatnam.
Meenal, M. and Shinjana, S. (2008b) Geochemistry of sandstone and shales from Kaimur Group, Son valley, Central India: Implications for provenance, tectonic setting and palaeoenvironment. In Terrestrial Planets Evolution Through Time Held at Physical Research Laboratory, Ahmedabad. pp.208–209.
Misra, R.C. (1969) The Vindhyan system. Presidential Address, Proc.56th Indian SciCong., v.2, pp.111–142.
Morad, S., Battacharya, A. and Al-Aasam, L.S. (1991) Daigenesis of quartz in Late Proterozoic Kaimur Sandstones, Son Valley, India. Jour. SediGeol., v.73, pp.209–225.
Oldham, T. (1856) Remarks on the classification of rocks of Central India, resulting from the investigation of the Geological Survey. Jour. Asiatic SocBengal, v.25, pp.224–256.
Prakash R. and Dalela S. (1982) Geology of Vindhyachal (eds. Valdiya K.S. et al.) Hindustan Publishing Corp. (India), New Delhi. pp.55–79.
Prasad, T.K. and Parthasarathy, G.R. (2018) Laterite and Laterization — A Geomorphological Review. Inter. Jour. SciRes., v.7(4), pp.578–583.
Prakash, Om., Kumar, Y. and Singh, K.P. (1979) Report on the systematic geological mapping in parts of Rohtas district, Bihar. Unpub. Rep. Geol. Surv. India, F.S. 1974–75.
Quasim, M.A., Khan, I. and Ahmad, A.H.M. (2017) Integrated Petrographic, Mineralogical, and Geochemical Study of the Upper Kaimur Group of Rocks, Son Valley, India: Implications for Provenance, Source Area Weathering and Tectonic Setting. Jour. Geol. SocIndia, v.90, pp.467–484.
Ray, J.S., Martin, M.W., Veizer, J. and Bowring, S.A. (2002) U-Pb zircon dating and Sr isotope systematics of Vindhyan Supergroup, India. Geology, v.30(2), pp.131–134.
Ray, J.S., Veizer, J., and Davis, W.J. (2003) C, O, Sr and Pb isotope systematics of carbonate sequences of the Vindhyan Supergroup, India: age, diagenesis, correlations and implications for global events. PrecamRes., v.121(1), pp.103–140.
Ray, J.S. (2006) Age of the Vindhyan Supergroup: a review of recent findings. JourEarth Syst.Sci., v.115, pp.149–160.
Ray, J.S. and Chakraborty, C. (2006) Vindhyan geology status and perspectives. Special Issue Jour. Earth SystSci., v.115(1), pp.1–183.
Rasmussen, B., Bose, P.K., Sarkar, S., Banerjee, S., Fletcher, I.R. and McNaughton, N.J. (2002) 1.6 Ga U-Pb Zircon ages for the Chorhat sandstone, Lower Vindhyan, India: possible implication for early evolution of animals. Geology, v.30, pp.103–106.
Sadiq, M. and Umrao, R.K. (2020) Nb-Ta-rare earth element mineralization in titaniferous laterite cappings over Sung Valley ultramafic rocks in Meghalaya, India. Ore GeolRevi., v.120, pp.103439(1–13).
Sarangi, S., Gopalan, K. and Kumar, S. (2004) Pb-Pb age of earliest megascopic, eukaryotic alga bearing Rohtas Formation, Vindhyan Supergroup, India: implications for Precambrian atmospheric oxygen evolution. PrecamRes., v.132(1–2), pp.107–121.
Sarkar, A.N. (1981) Stratigraphy and structure of the Lower Vindhyan rocks of Palamau district, Bihar. Misc. Pub. Geol. SurIndia, v.50, pp.21–29.
Sastry, M.V.A. and Moitra, A.K. (1984) Vindhyan stratigraphy — A review. Mem. Geol. SurIndia, v.116, pp.109–148.
Schellmann, W. (1982) Eine neue Laterit definition. GeolJahrbuch D, v.58, pp.31–47.
Schellmann, W. (1986) A new definition of laterite. Mem. Geol. SurIndia, v.120, pp.1–7.
Singh, I.B. (1980) Precambrian sedimentary sequences of India: Their peculiarities and comparison with modern sediment. PrecamRes., v.12(1–4), pp.411–436.
Singh, S. P. (1998) Precambrian Straitigraphy of Bihar-An overview, In:Paliwal, B.S. (ed.). Indian Precam. Scient. Pub. (Indian), Jodhpur, pp.376–408.
Verma, S.K. and Deb Ray, D.K. (1986) Progress report on systematic geological mapping in parts of Rohtas district. Unpub. Report Geol. Surv. India, FS: 1981–82.
Verma, N.P., Reddy, K.K. and Singh, K.P., 1984: A report on the systematic geological mapping in parts of Rohtas district, Bihar. Unpub. Rep. Geol. Surv. India, F.S. 1979–80.
Vinogradov A.P., Tugarinov A.I., Zikhov C.I., Stanikova N., Ibibkova E.V., and Khorre K. (1964) Geochronology of the Indian Precambrian. Report 22nd Inter. GeolCong., v.10, pp.553–567.
Wadia, D.N. (1919) Geology of India. Macmillan and Co., Limited, St. Martin’s Street, London, 398p.
Yadav, P.K. and Das, M. (2019) Specialised Thematic Mapping in parts of Bhagwanpur-Karar-Bahadag areas of Rohtas district, Bihar for a reappraisal of the Vindhyan Stratigraphy and search for diamondiferous conglomerate horizons. Unpub. Rep. Geol. Surv. India, F.S. 2017–19.
Acknowledgements
Authors are highly indebted to the Director General, Geological Survey of India for giving permission to publish the paper. They are also thankful to the Deputy Director General and Shri Sukhendu Ray, Director, Geological Survey of India, SU: Bihar, for their cooperation, constant encouragement, guidance and valuable suggestions during the work. Authors would like to convey their sincere thanks to the anonymous reviewer for his critical comments and suggestions for a fruitful and substantial revision of the paper.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Yadav, P.K., Das, M. Geology, Structure and Geochemical Features of the Laterites with Anomalous Ti-V-Cr and REE of the Dhandraul Formation of the Vindhyan Supergroup, Eastern India. J Geol Soc India 97, 603–614 (2021). https://doi.org/10.1007/s12594-021-1735-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12594-021-1735-x