Abstract
The biomedically important polymer blends, composed of natural polymer Xanthan gum and synthetic polymer Polyacrylamide have been prepared and miscibility studies were carried out by using various techniques over a range of composition in solution and solid states. Viscosity, Ultrasonic velocity and Density were measured at 30 and 40 °C. Using viscosity data, interaction parameters ‘μ’ and ‘α’ were computed to determine the miscibility of the blend in the solution state. These values revealed that, the blend is immiscible over entire composition range. Temperature had no significant effect on the miscibility. Ultrasonic velocity and density studies also confirmed the immiscibility of the blend. Solid films of the blends were analyzed by FTIR, SEM and DSC techniques and confirm the immiscible nature of the blend. TGA results showed that the thermal stability of Xanthan gum was found to be improved after blending with Polyacrylamide.
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References
Gupta RK, Gaba ID, Pande CP, Singh RP (1987) Polyimide. Ptenum Press, New York, pp 547–554
Krause S (1978) Polymer-Polymer compatibility in polymer blends Vol 1. Academic, New York
Olabisi O, Robeson LM, Shaw MT (1979) Polymer-Polymer Miscibility. Academic, New York
Changua L, Chaobo X, Hui L (2005) J Appl Polym Sci 95:1405–1411
Paladhi R, Singh RP (1994) Eur Polym J 30(2):251–257
Jacob J, Ramaswamy M, Battacharya M (2002) J Polym Sci Part A: Polym Chem 40(12):2003–2014
Sun H, Bin Y, Sheng J (2010) J Polym Plast Tech Engg 49(4):414–417
Caykara T, Demirci S (2007) J Polym Plast Tech Engg 46:737–741
Ismaila H, Ahmada Z, Nordina R, Rashid AR (2009) J Polym Plast Tech Engg 48(11):1191–1197
Lina S-W, Cheng Y-Y (2010) J Polym Plast Tech Engg 49(10):1001–1009
Siddaraiah M, Swamy TM (2007) J Macro Sci 44(3):321–327
Maria GC, Giovanni P, Luigi L, Niccoletta B (1997) J Appl Polym Sci 66:2089–2094
Paladhi R, Singh R (1994) P J Appl Polym Sci 51:1559
Guru GS, Prasad P, Shivakumar HR, Sheshappa Rai K (2010) Int J Plast Technol 14(2):234–245
Jayaraju J, Keshavayya J, Rai SK, Rama SR (2008) J Macro Sci 47(2):296–304
Uday T, Aminabhavi TM (2002) J Appl Polym Sci 85:2014–2019
Rochefort WE, Middleman S (1987) J Rheol 31:337
Gavrilin MV (2001) Pham Chem J 35(1):35–39
Varada R, Siddaramiah A, Reddy RL (1998) J Appl Polym Sci 70:1823
Lachke A (2004) Reson 10:25–33
Pelletien E, Viebke C, Meadows J, Williams PA (2001) Biopolymers 59:339
Sharma BR, Naresh L, Dhuldhoya NC, Merchant SU, Merchant UC (2006) Food Promot Chron 1(5):27–30
Gao B, Wu YC, Zhang ZG, Hua JJ, Yao KD, Hou X (2008) J Macmol Sci 47(3):544–554
Sowwan M, Maryan F (2008) Int J Phy Sci 3(6):144–147
Chee KK (1990) Eur Polym J 26:423–426
Sun Z, Wang W, Fung Z (1992) Eur Polym J 28:1259–1261
Prudhomme RE (1982) Polym Engg and Sci 22:1138–1142
Zheng S, Li J, Gao R (2003) J Macromol Sci Part B 42:351–362
Acknowledgments
The authors express their gratitude to BARC, Mumbai, for financial support under BRNS project No. 2009/34/19/BRNS and also gratefully acknowledge Late. Dr. Kurunji Venkataramana Gowda, Founder President, AOLE, Sullia and Dr. N. A. Jnanesh, Principal, KVG College of Engineering, Sullia, for providing infrastructure facilities.
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Bhat, V., Shivakumar, H.R., Sheshappa, R.K. et al. Preparation and study on miscibility, thermal behavior of biocompatible polymer blends of xanthan Gum-polyacrylamide. Int J Plast Technol 18, 183–191 (2014). https://doi.org/10.1007/s12588-014-9078-8
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DOI: https://doi.org/10.1007/s12588-014-9078-8