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Preparation and study on miscibility, thermal behavior of biocompatible polymer blends of xanthan Gum-polyacrylamide

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International Journal of Plastics Technology

Abstract

The biomedically important polymer blends, composed of natural polymer Xanthan gum and synthetic polymer Polyacrylamide have been prepared and miscibility studies were carried out by using various techniques over a range of composition in solution and solid states. Viscosity, Ultrasonic velocity and Density were measured at 30 and 40 °C. Using viscosity data, interaction parameters ‘μ’ and ‘α’ were computed to determine the miscibility of the blend in the solution state. These values revealed that, the blend is immiscible over entire composition range. Temperature had no significant effect on the miscibility. Ultrasonic velocity and density studies also confirmed the immiscibility of the blend. Solid films of the blends were analyzed by FTIR, SEM and DSC techniques and confirm the immiscible nature of the blend. TGA results showed that the thermal stability of Xanthan gum was found to be improved after blending with Polyacrylamide.

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References

  1. Gupta RK, Gaba ID, Pande CP, Singh RP (1987) Polyimide. Ptenum Press, New York, pp 547–554

    Google Scholar 

  2. Krause S (1978) Polymer-Polymer compatibility in polymer blends Vol 1. Academic, New York

    Google Scholar 

  3. Olabisi O, Robeson LM, Shaw MT (1979) Polymer-Polymer Miscibility. Academic, New York

    Google Scholar 

  4. Changua L, Chaobo X, Hui L (2005) J Appl Polym Sci 95:1405–1411

    Article  Google Scholar 

  5. Paladhi R, Singh RP (1994) Eur Polym J 30(2):251–257

    Article  CAS  Google Scholar 

  6. Jacob J, Ramaswamy M, Battacharya M (2002) J Polym Sci Part A: Polym Chem 40(12):2003–2014

    Article  Google Scholar 

  7. Sun H, Bin Y, Sheng J (2010) J Polym Plast Tech Engg 49(4):414–417

    Article  CAS  Google Scholar 

  8. Caykara T, Demirci S (2007) J Polym Plast Tech Engg 46:737–741

    Article  CAS  Google Scholar 

  9. Ismaila H, Ahmada Z, Nordina R, Rashid AR (2009) J Polym Plast Tech Engg 48(11):1191–1197

    Article  Google Scholar 

  10. Lina S-W, Cheng Y-Y (2010) J Polym Plast Tech Engg 49(10):1001–1009

    Article  Google Scholar 

  11. Siddaraiah M, Swamy TM (2007) J Macro Sci 44(3):321–327

    Article  Google Scholar 

  12. Maria GC, Giovanni P, Luigi L, Niccoletta B (1997) J Appl Polym Sci 66:2089–2094

    Article  Google Scholar 

  13. Paladhi R, Singh R (1994) P J Appl Polym Sci 51:1559

    Article  CAS  Google Scholar 

  14. Guru GS, Prasad P, Shivakumar HR, Sheshappa Rai K (2010) Int J Plast Technol 14(2):234–245

    Article  CAS  Google Scholar 

  15. Jayaraju J, Keshavayya J, Rai SK, Rama SR (2008) J Macro Sci 47(2):296–304

    Article  CAS  Google Scholar 

  16. Uday T, Aminabhavi TM (2002) J Appl Polym Sci 85:2014–2019

    Article  Google Scholar 

  17. Rochefort WE, Middleman S (1987) J Rheol 31:337

    Article  CAS  Google Scholar 

  18. Gavrilin MV (2001) Pham Chem J 35(1):35–39

    Article  CAS  Google Scholar 

  19. Varada R, Siddaramiah A, Reddy RL (1998) J Appl Polym Sci 70:1823

    Article  Google Scholar 

  20. Lachke A (2004) Reson 10:25–33

    Article  Google Scholar 

  21. Pelletien E, Viebke C, Meadows J, Williams PA (2001) Biopolymers 59:339

    Article  Google Scholar 

  22. Sharma BR, Naresh L, Dhuldhoya NC, Merchant SU, Merchant UC (2006) Food Promot Chron 1(5):27–30

    Google Scholar 

  23. Gao B, Wu YC, Zhang ZG, Hua JJ, Yao KD, Hou X (2008) J Macmol Sci 47(3):544–554

    CAS  Google Scholar 

  24. Sowwan M, Maryan F (2008) Int J Phy Sci 3(6):144–147

    Google Scholar 

  25. Chee KK (1990) Eur Polym J 26:423–426

    Article  CAS  Google Scholar 

  26. Sun Z, Wang W, Fung Z (1992) Eur Polym J 28:1259–1261

    Article  CAS  Google Scholar 

  27. Prudhomme RE (1982) Polym Engg and Sci 22:1138–1142

    Article  CAS  Google Scholar 

  28. Zheng S, Li J, Gao R (2003) J Macromol Sci Part B 42:351–362

    Article  Google Scholar 

Download references

Acknowledgments

The authors express their gratitude to BARC, Mumbai, for financial support under BRNS project No. 2009/34/19/BRNS and also gratefully acknowledge Late. Dr. Kurunji Venkataramana Gowda, Founder President, AOLE, Sullia and Dr. N. A. Jnanesh, Principal, KVG College of Engineering, Sullia, for providing infrastructure facilities.

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Correspondence to H. R. Shivakumar.

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Bhat, V., Shivakumar, H.R., Sheshappa, R.K. et al. Preparation and study on miscibility, thermal behavior of biocompatible polymer blends of xanthan Gum-polyacrylamide. Int J Plast Technol 18, 183–191 (2014). https://doi.org/10.1007/s12588-014-9078-8

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  • DOI: https://doi.org/10.1007/s12588-014-9078-8

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