Abstract
In this work, blends of acrylonitrile–butadiene–styrene (ABS) and thermoplastic starch (TPS) were prepared by using a single screw extruder (SSE), the starch was plasticized in the single screw extruder by using glycerol as a plasticizer. The blends were characterized by studying rheological and mechanical properties. The rheological results indicated that ABS/TPS blend melts were pseudo plastic and exhibited shear–thinning behavior, and the viscosity of the blend decreased with increasing glycerol content. Also the values of flow activation energy at a constant shear stress (E τ ) of ABS1/TPS25G blend were determined, and it was found that E τ increased with increasing shear stress. Die swell measurements of the blend showed that die swell ratio increases with increasing shear stress and glycerol content in the blend, while it decreases with increasing L/R. Mechanical results showed that, the values of stress at break and strain at break decreased with increasing TPS content in the blend, which was attributed to the immiscibility between TPS and ABS.
Similar content being viewed by others
References
Liu H, Xie F, Yu L, Chen L, Li L (2009) Thermal processing of starch-based polymers. Prog Polym Sci 34:1348–1368
Ma XF, Yu JG, Wan JJ (2006) Urea and ethanolamine as a mixed plasticizer for thermoplastic starch. Carbohydr Polym 64:267–273
Ma X, Yu J (2004) The plasticizers containing amide groups for thermoplastic starch. Carbohydr Polym 57:197–203
Salcido CS, Gonzalez FJ, Hernandez ML, Esquivel JC (2008) Effect of morphology on the biodegradation of thermoplastic starch in LDPE/TPS blends. Polym Bull 60:677–688
Rosa DS, Guedes CGF, Carvalho CL (2007) Processing and thermal, mechanical and morphological characterization of post-consumer polyolefins/thermoplastic starch blends. J Mater Sci 42:551–557
Rosa DS, Bardi MAG, Machado LDB, Dias DB, Silva LGA, Kodama Y (2009) Influence of thermoplastic starch plasticized with biodiesel glycerol on thermal properties of PP blends. J Them Anal Calorim 97:565–570
Mihai M, Huneault MA, Favis BD (2007) Foaming of polystyrene/thermoplastic starch blends. J Cell Plast 43:215–236
Wang N, Yu J, Chang PR, Ma X (2008) Influence of formamide and water on the properties of thermoplastic starch/poly(lactic acid) blends. Carbohydr Polym 71:109–118
Wang N, Yu J, Ma X, Ying W (2007) The influence of citric acid on the properties of thermoplastic starch/linear low- density polyethylene blends. Carbohydr Polym 67:446–453
Schlemmer D, Sales MJA, Resck IS (2009) Degradation of different polystyrene/thermoplastic starch blends buried in soil. Carbohydr Polym 75:58–62
Schlemmer D, Oliveira ER, Sales MJA (2007) Polystyrene/thermoplastic starch blends with different plasticizers, preparation and thermal characterization. J Them Anal Calorim 87:635–638
Pimentel TAPF, Duraes JA, Drummond AL, Schlemmer D, Falcao R, Salas MJA (2007) Preparation and characterization of blends of recycled polystyrene with cassava starch. J Mater Sci 42:7530–7536
Yang JH, Yu JG, Ma XF (2006) A novel plasticizer for the preparation of thermoplastic starch. Chine Chem Lett 17:133–136
Yang JH, Yu JG, Ma XF (2008) Preparation and properties of ethylenebisformamide plasticized potato starch (EPTPS). Carbohydr Polym 63:218–223
Yang JH, Yu JG, Ma XF (2006) Study on the properties of ethylenebisformamide and sorbitol plasticized corn starch (ESPTPS). Carbohydr Polym 66:110–116
Suarez H, Barlow JW, Paul DR (1984) Mechanical properties of ABS/Polycarbonate blends. J Appl Polym Sci 29:3253–3259
Tasdemir M (2004) Properties of acrylonitrile–butadiene–styrene/polycarbonate blends with styrene–butadiene–styrene block copolymer. J Appl Polym Sci 93:2521–2527
Wu Js, Shen SC, Chang FC (1993) Effect of polycarbonate molecular weight on polymer blends of polycarbonate and ABS. J Appl Polym Sci 50:1379–1389
Xue ML, Yu YL, Chuah HH, Rhee JM, Kim NH, Lee JH (2007) Miscibility and compatibilization of poly(trimethylene terephthalate)/acrylonitrile–butadiene–styrene blends. Eur Polym J 43:3826–3837
Han CD (2007) Rheology and processing of polymeric materials (Polymer Rheology). Oxford University Press, New York
Bagley EB (1956) End correction in the capillary flow of polyethylene. J Appl Phys 28:624–627
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kaseem, M., Hamad, K. & Deri, F. Preparation and studying properties of thermoplastic starch/acrylonitrile–butadiene–styrene blend. Int J Plast Technol 16, 39–49 (2012). https://doi.org/10.1007/s12588-012-9027-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12588-012-9027-3