Skip to main content
Log in

Processing parameters affecting the nano scale-microstructure and mechanical strength of coal ash-based geopolymer

  • Published:
International Journal of Precision Engineering and Manufacturing Aims and scope Submit manuscript

Abstract

The coal ash-based geopolymer exhibits many excellent properties such as high compressive strength, low creep, good acid resistance and low shrinkage, so it is emerging as a promising new cement alternative in the field of building and construction materials, In this study, the coal reclamation ash-based geopolymers was fabricated to investigate the optimal processing conditions to enhance the mechanical strength. The processing parameter concerned were the concentration of the alkali activator, liquid/solid ratio and calcination temperature to remove the unburned carbon. Characterization of geopolymers were performing on the phase analysis, nano scale-microstructure observation and measurement of compressive strength of the geopolymers fabricated. The raw material coal reclamation ash had much unburned carbon of 7.5 wt% and is identified as the class F fly ash. The curing temperature for fabricating geopolymer was 70°C/24h. In conclusion, raising the recycling rate of coal reclamation ash and enhancing the mechanical strength of coal reclamation ash-based geopolymer will be tried.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Ahn, S. H., “An Evaluation of Green Manufacturing Technologies based on Research Databases,” Int. J. Precis. Eng. Manuf.-Green Tech., vol. 1, no. 1, pp. 5–9, 2014.

    Article  Google Scholar 

  2. Temuujin, J. and Van Riessen, A., “Effect of Fly Ash Preliminary Calcination on the Properties of Geopolymer,” Journal of Hazardous Materials, vol. 164, no. 2, pp. 634–639, 2009.

    Article  Google Scholar 

  3. Guo, X., Shi, H., and Dick, W. A., “Compressive Strength and Microstructural Characteristics of Class C Fly Ash Geopolymer,” Cement and Concrete Composites, vol. 32, no. 2, pp. 142–147, 2010.

    Article  Google Scholar 

  4. Park, C. W., Kwon, K. S., Kim, W. B., Min, B. K., Park, S. J., et al., “Energy Consumption Reduction Technology in Manufacturing-A Selective Review of Policies, Standards, and Research,” Int. J. Precis. Eng. Manuf., vol. 10, no. 5, pp. 151–173, 2009.

    Article  Google Scholar 

  5. Yunsheng, Z., Wei, S., and Zongjin, L., “Composition Design and Microstructural Characterization of Calcined Kaolin-based Geopolymer Cement,” Applied Clay Science, vol. 47, no. 3, pp. 271–275, 2010.

    Article  Google Scholar 

  6. Davidovits, J., “Geopolymers,” Journal of Thermal Analysis and Calorimetry, vol. 37, no. 8, pp. 1633–1656, 1991.

    Article  Google Scholar 

  7. Glukhovsky, V. D., “Ancient, Modern and Future Concretes,” Proc. of the 1st International Conference on Alkaline Cements and Concretes, pp. 1–9, 1994.

    Google Scholar 

  8. Ha, T. H., Muralidharan, S., Bae, J. H., Ha, Y. C., Lee, H. G., et al., “Effect of Unburnt Carbon on the Corrosion Performance of Fly Ash Cement Mortar,” Construction and Building Materials, vol. 19, no. 7, pp. 509–515, 2005.

    Article  Google Scholar 

  9. Silverstrim, T., Rostami, H., Larralde, J. C., and Samadi-Maybodi, A., “Fly Ash Cementitious Material and Method of Making a Product,” US Patent, No. 5601643A, 1997.

    Google Scholar 

  10. Duxson, P., Fernández-Jiménez, A., Provis, J., Lukey, G., Palomo, A., and Van Deventer, J., “Geopolymer Technology: The Current State of the Art,” Journal of Materials Science, vol. 42, no. 9, pp. 2917–2933, 2007.

    Article  Google Scholar 

  11. Shariq, M., Prasad, J., and Ahuja, A. K., “Strength Development of Cement Mortar and Concrete Incorporating GGBFS,” Asian Journal of Civil Engineering, vol. 9, no. 1, pp. 61–74, 2008.

    Google Scholar 

  12. Chindaprasirt, P., Jaturapitakkul, C., Chalee, W., and Rattanasak, U., “Comparative Study on the Characteristics of Fly Ash and Bottom Ash Geopolymers,” Waste Management, vol. 29, no. 2, pp. 539–543, 2009.

    Article  Google Scholar 

  13. Zuhua, Z., Xiao, Y., Huajun, Z., and Yue, C., “Role of Water in the Synthesis of Calcined Kaolin-based Geopolymer,” Applied Clay Science, vol. 43, no. 2, pp. 218–223, 2009.

    Article  Google Scholar 

  14. Lee, W. K. W. and Van Deventer, J. S. J., “The Effects of Inorganic Salt Contamination on the Strength and Durability of Geopolymers,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 211, no. 2, pp. 115–126, 2002.

    Article  Google Scholar 

  15. Svarla, J., Sisol, M., Botula, J., Kolesarova, M., and Krinicka, I., “The Potential Use of Fly Ash with a High Content of Unburned Carbon in Geopolymers,” Acta Geodynamica et Geomaterialia, vol. 7, no. 2, pp. 123–132, 2011.

    Google Scholar 

  16. Temuujin, J., Williams, R., and van Riessen, A., “Relational Utilisation of Fly Ash for Geopolymer Processing,” Proc. of CSRP Conference, 2008.

    Google Scholar 

  17. Kim, J. T., Seo, D. S., Kim, G. J., and Lee, J. K., “Influence of Alkaline-Activator Content on the Compressive Strength of Aluminosilicate-based Geopolymer,” Journal of the Korean Ceramic Society, vol. 47, no. 3, pp. 216–222, 2010.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Seung-Gu Kang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Won, JH., Kang, SG. Processing parameters affecting the nano scale-microstructure and mechanical strength of coal ash-based geopolymer. Int. J. Precis. Eng. Manuf. 16, 1335–1340 (2015). https://doi.org/10.1007/s12541-015-0175-1

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12541-015-0175-1

Keywords

Navigation