Abstract
The capacity of the Allium cepa L. extract from peel (ACP) and bulb (ACB) as a natural corrosion inhibitor for carbon steel was evaluated. The corrosion characterization was performed by a gravimetric test, showing an inhibitor efficiency of 60% (ACP) and 67% (ACB). Electrochemical tests indicated higher corrosion resistance for carbon steel in the presence of the extracts, and the SEM images of steel samples confirm the results. These extracts were analyzed by the DPPH (2,2-diphenyl-1-picrylhydrazyl) method, confirming the antioxidant activity. The chemical characterization of the extracts by FTIR measurements revealed the presence of phenolic compounds with antioxidant capacity.
Graphic Abstract
Similar content being viewed by others
References
V. Gentil, Corrosion (LTC, Rio de Janeiro, 2003)
P.A. Schweitzer, Fundamentals of Corrosion: Mechanisms, Causes and Preventive Methods (Taylor and Francis Group, New York, 2010)
K. Hu, J. Zhuang, J. Ding, Z. Ma, F. Wang, X. Zeng, Influence of biomacromolecule DNA corrosion inhibitor on carbon steel. Corros. Sci. 125, 68–76 (2017)
J.K. Wessel, The Handbook of Advanced Materials: Enabling New Designs (Wiley, Hoboken, 2004)
M.A. Quraishi, R. Sardar, D. Jamal, Corrosion inhibition of mild steel in hydrochloric acid by some aromatic hydrazides. Mater. Chem. Phys. 71, 309–313 (2001)
J. Rodriguez, M. Mouanga, A. Roobroeck, D. Cossement, A. Mirisola, M.-G. Olivier, Study of the inhibition ability of benzotriazole on the Zn–Mg coated steel corrosion in chloride electrolyte. Corros. Sci. 132, 56–67 (2018). https://doi.org/10.1016/j.corsci.2017.12.025
I.L. Rozenfeld, Corrosion Inhibitors (McGraw-hill Inc, New York, 1982)
B.E.A. Rani, B.B.J. Basu, Green inhibitors for corrosion protection of metals and alloys: an overview. Int J Corros 2012, 1–15 (2011)
A. Khadraoui, A. Khelifa, H. Boutoumi, H. Hamitouche, R. Mehdaoui, B. Hammouti, S.S. Al-Deyab, Adsorption and inhibitive properties of Ruta chalepensis L. oil as a green inhibitor of steel in 1 M hydrochloric acid medium. Int. J. Electrochem. Sci. 9, 3334–3348 (2014)
A.Y. El-Etre, Inhibition of C-steel corrosion in acidic solution using the aqueous extract of zallouh root. Mater. Chem. Phys. 108, 278–282 (2008)
P. Mourya, S. Banerjee, M.M. Singh, Corrosion inhibition of mild steel in acidic solution by Tagetes erecta (Marigold flower) extract as a green inhibitor. Corros. Sci. 85, 352–363 (2014)
V.V. Torres, R.S. Amado, C.F. de Sá, T.L. Fernandez, C.A.S. Riehl, A.G. Torres, E. D'Elia, Inhibitory action of aqueous coffee extracts on the corrosion of carbon steel in HCl solution. Corros. Sci. 53, 2385–2392 (2011)
P.B. Raja, A.K. Qureshi, A.A. Rahim, K. Awang, M.R. Mukhtar, H. Osman, Indole alkaloids of Alstonia angustifolia var. latifolia as green inhibitor for mild steel corrosion in 1 M HCl media. J. Mater. Eng. Perform. 22, 1072–1078 (2013)
V.S. Sastri, Green Corrosion Inhibitors: Theory and Practice (Wiley, New Jersey, 2011)
O.K. Abiola, J.O.E. Otaigbe, O.J. Kio, Gossipium hirsutum L. extracts as green corrosion inhibitor for aluminum in NaOH solution. Corros. Sci. 51, 1879–1881 (2009)
M. Favre, D. Landolt, The influence of gallic acid on the reduction of rust on painted steel surfaces. Corros. Sci. 34, 1481–1494 (1993)
J. Mabrour, M. Akssira, M. Azzi, M. Zertoubi, N. Saib, A. Messaoudi, A. Albizane, S. Tahiri, Effect of vegetal tannin on anodic copper dissolution in chloride solutions. Corros. Sci. 46, 1833–1847 (2004)
K.C.R. Ferreira, R.F.B. Cordeiro, J.C. Nunes, H. Orofino, M. Magalhães, A.G. Torres, E. D'Elia, Corrosion inhibition of carbon steel in HCl solution by aqueous brown onion peel extract. Int. J. Electrochem. Sci. 11, 406–418 (2016)
Y. Qiang, S. Zhang, B. Tan, S. Chen, Evaluation of Ginkgo leaf extract as an eco-friendly corrosion inhibitor of X70 steel in HCl solution. Corros. Sci. 133, 6–16 (2018). https://doi.org/10.1016/j.corsci.2018.01.008
D. Veys-renaux, S. Reguer, L. Bellot-gurlet, F. Mirambet, E. Rocca, Conversion of steel by polyphenolic model molecules: corrosion inhibition mechanism by rutin, esculin, esculetol. Corros. Sci. 136, 1–8 (2018). https://doi.org/10.1016/j.corsci.2018.02.015
J.C. Rocha, J.A.C.P. Gomes, E. D'Elia, Corrosion inhibition of carbon steel in hydrochloric acid solution by fruit peel aqueous extracts. Corros Sci 52, 2341–2348 (2010)
S. Deng, X. Li, Inhibition by Ginkgo leaves extract of the corrosion of steel in HCl and H2SO4 solutions. Corros. Sci. 55, 407–415 (2012)
A.Y. El-Etre, Inhibition of acid corrosion of carbon steel using aqueous extract of olive leaves. J. Colloid Interface Sci. 314, 578–583 (2007)
O.S. Fayomi, A.P.I. Popoola, The inhibitory effect and adsorption mechanism of roasted Elaeis guineensis as the green inhibitor on the corrosion process of extruded AA6063 Al–Mg–Si alloy in simulated solution. Silicon 6, 137–143 (2014)
S.C. Nwigbo, V.N. Okafor, A.O. Okewale, Comparative study of Elaine Guinensis Exudates (palm wine) as a corrosion inhibitor for mild steel in acidic and basic solutions. Res. J. Appl. Sci. Eng. Technol. 4, 1035–1039 (2012)
J. Halambek, K. Berkovic, J. Vorkapic-Furac, The influence of Lavandula angustifolia L. on corrosion of Al–3Mg alloy. Corros. Sci. 52, 3978–3983 (2010)
N.B. Iroha, O. Akaranta, A.O. James, Red onion skin extract-formaldehyde resin as corrosion inhibitor for mild steel in hydrochloric acid solution. Int. Res. J. Pure Appl. Chem. 6, 174–181 (2015)
S. Sulaiman, A. Nor-Anuar, A.S. Abd-Razak, S. Chelliapan, A study of using Allium Cepa (Onion) as the natural corrosion inhibitor in industrial chill wastewater system. Res. J. Chem. Sci. 2, 10–16 (2012)
U.F. Ekanem, S.A. Umoren, I.I. Udousoro, A.P. Udoh, Inhibition of mild steel corrosion in HCl using pineapple leaves (Ananas comosus L.) extract. J. Mater. Sci. 45, 5558–5566 (2010)
H. Tian, W. Li, A. Liu, X. Gao, P. Han, R. Ding, C. Yang, D. Wang, Controlled delivery of multi-substituted triazole by metal–organic framework for efficient inhibition of mild steel corrosion in neutral chloride solution. Corros. Sci. 131, 1–16 (2018)
K. Azzaoui, E. Mejdoubi, S. Jodeh, A. Lamhamdi, E. Rodriguez-Castellón, M. Algarra, A. Zarrouk, A. Errich, R. Salghi, H. Lgaz, Ecofriendly green inhibitor Gum Arabic (GA) for the corrosion control of mild steel in hydrochloric acid medium. Corros. Sci. 129, 70–81 (2017)
E.C.C.A. de Souza, B.A. Ripper, D. Perrone, E. D'Elia, Roasted coffee extracts as corrosion inhibitors for mild steel in HCl solution. Mater. Res. 19, 1276–1285 (2016)
J. Bystrická et al., Bioactive components of onion (Allium cepa L.): a review. Acta Aliment. 42(1), 11–22 (2013)
D.I. Stajner, I.S. Varga, An evaluation of the antioxidant abilities of Allium species. Acta Biol. Szegediensis 47(1), 103–106 (2003)
N. Benkeblia, Free-radical scavenging capacity and antioxidant properties of some selected onions (Allium cepa L.) and garlic (Allium sativum L.) extracts. Food Sci. Technol. 48(5), 753–759 (2005)
W. Breu, Allium cepa L. (onion) Part 1: chemistry and analysis. Phytomedicine 3(3), 293–306 (1996)
S.M. Borghi, S.S. Mizokami, F.A. Pinho-Ribeiro, V. Fattori, J. Crespigio, J.T. Clemente-Napimoga, M.H. Napimoga, D.L. Pitol, J.P.M. Issa, S.Y. Fukada, R. Casagrande, W.A. Verri Jr., The flavonoid quercetin inhibits titanium dioxide (TiO2)-induced chronic arthritis in mice. J. Nutr. Biochem. 53, 81–95 (2018)
L.S. Huber, D.B. Rodriguez-Amaya, Flavonols and flavones: brazilian sources and factors that influence food composition. Alim. Nutr. 19, 97–108 (2008)
S.G. Lee, J.S. Parks, H.W. Kang, Quercetin, a functional compound of onion peel, remodels white adipocytes to brown-like adipocytes. J. Nutr. Biochem. 42, 62–71 (2017). https://doi.org/10.1016/j.jnutbio.2016.12.018
K. Sharma, N. Mahato, Y.R. Lee, Systematic study on active compounds as antibacterial and antibiofilm agent in aging onions. J. Food Drug Anal. 26, 518–528 (2017)
C.M.O. Simões, E.P. Schenkel, G. Gosmann, J.C.P. de Mello, L.A. Mentz, P.R. Petrovick, Farmacognosia: da Planta ao medicamento (da Universidade/EFRGS/Ed. da UFSC, Porto Alegre/Florianópolis, 1999)
L.J. Wang, S. Su, J. Wu, H. Du, S.S. Li, J.W. Huo, Y. Zhang, L.S. Wang, Variation of anthocyanins and flavonols in Vaccinium uliginosum berry in Lesser Khingan Mountains and its antioxidant activity. Food Chem. 160, 357–364 (2014)
J.B. Silva, K.M.F.M. Costa, W.A.C. Coelho, K.A.R. Paiva, G.A.V. Costa, A. Salatino, C.I.A. Freitas, J.S. Batista, Quantificação de fenóis, flavonoides totais e atividades farmacológicas de geoprópolis de Plebeia aff. flavocincta do Rio Grande do Norte. Pesq. Vet. Bras. 36, 874–880 (2019)
R.M. Silverstein, F.X. Webster, D.J. Kiemle, Spectrometric Identification of Organi Compounds (LTC, Rio de Janeiro, 2007)
S. Zhang, P. Deng, Y. Xu, S. Lü, J. Wang, Quantification and analysis of anthocyanin and flavonoids compositions, and antioxidant activities in onions with three different colors. J. Integr. Agric. 15, 2175–2181 (2016)
Y. Zhang, Q. Li, H. Cui, J. Zhai, Removal of phenols from the aqueous solutions based on their electrochemical polymerization on the polyaniline electrode. Electrochim. Acta 55, 7219–7224 (2010)
A.O. James, O. Akaranta, Corrosion inhibition of aluminum in 2.0 M hydrochloric acid solution by the acetone extract of red onion skin. Afr. J. Pure Appl. Chem. 3, 212–219 (2009)
K.M. Hijazi, A.M. Abdel-Gaber, G.O. Younes, Electrochemical corrosion behavior of mild steel in HCl and H2SO4 solutions in presence of loquat leaf extract. Int. J. Electrochem. Sci. 10, 4366–4380 (2015)
A.M. Santos, I.P. Aquino, F. Cotting et al., Evaluation of palm kernel cake powder (Elaeis guineensis Jacq.) as corrosion inhibitor for carbon steel in acidic media. Met. Mater. Int. (2019). https://doi.org/10.1007/s12540-019-00559-x
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Galo, G.T., Morandim-Giannetti, A.d., Cotting, F. et al. Evaluation of Purple Onion (Allium cepa L.) Extract as a Natural Corrosion Inhibitor for Carbon Steel in Acidic Media. Met. Mater. Int. 27, 3238–3249 (2021). https://doi.org/10.1007/s12540-020-00679-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12540-020-00679-9