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Cycling performance of LiNi1−yMyO2 (M=Ni, Ga, Al and/or Ti) synthesized by wet milling and solid-state method

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Abstract

The LiNi1−yMyO2 specimens with compositions of LiNiO2, LiNi0.975Ga0.025O2, LiNi0.975Al0.025O2, LiNi0.995Ti0.005O2, and LiNi0.990Al0.005Ti0.005O2 were synthesized by wet milling and a solid-state reaction method. Among all the specimens, LiNi0.990Al0.005Ti0.005O2 has the largest first discharge capacity of 196.3 mAh/g at a rate of 0.1 C. At n=50, LiNiO2 has the largest discharge capacity of 126.7 mAh/g. LiNiO2 has the best cycling performance, its degradation rate of discharge capacity being 0.73 mAh/g/cycle. LiNi0.975Al0.025O2 shows the lowest decrease rate of the first discharge capacity with C rate. An equation describing the variation of the discharge capacity with the number of charge-discharge cycles, n, is obtained. The Williamson-Hall method is applied to calculate the crystallite size and the strain of the samples before and after charge-discharge cycling.

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Authors and Affiliations

  1. Division of Advanced Materials Engineering, Hydrogen & Fuel Cell Research Center, Engineering Research Institute, Chonbuk National University, Jeonju, 561-756, Korea

    Myoung Youp Song

  2. Department of Chemical Engineering and Materials Science, University of California Irvine, Irvine, CA, 92697-2575, USA

    Daniel R. Mumm

  3. Department of Hydrogen and Fuel Cells Engineering, Specialized Graduate School, Chonbuk National University, Jeonju, 561-756, Korea

    Chan Kee Park

  4. School of Applied Chemical Engineering, Chonnam National University, Gwangju, 500-757, Korea

    Hye Ryoung Park

Authors
  1. Myoung Youp Song
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  2. Daniel R. Mumm
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  3. Chan Kee Park
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  4. Hye Ryoung Park
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Correspondence to Myoung Youp Song.

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Song, M.Y., Mumm, D.R., Park, C.K. et al. Cycling performance of LiNi1−yMyO2 (M=Ni, Ga, Al and/or Ti) synthesized by wet milling and solid-state method. Met. Mater. Int. 18, 465–472 (2012). https://doi.org/10.1007/s12540-012-3013-3

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  • DOI: https://doi.org/10.1007/s12540-012-3013-3

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