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Fabrication of porous lanthanum strontium manganite films by electrostatic spray deposition

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Abstract

In this work, electrostatic deposition was used to prepare porous lanthanum strontium manganite (LSM) films on a silicon substrate for cathode application in solid oxide fuel cells (SOFCs). The precursor solution was prepared by dissolving lanthanum nitrate hydrate, manganese nitrate hexahydrate and strontium chloride hexahydrate into a mixture of methanol and water. The morphology of the LSM film depended on process parameters such as substrate temperature, precursor flow rate, nozzle-substrate distance, and deposition time. The effect of heating temperature on the film’s crystal structure was investigated with X-ray diffraction in the heating temperature range of 700 °C to 900 °C. Porous LSM film was successfully prepared in the solution flow rate range of 2 l/min to 4.5 l/min, substrate temperatures of 127 °C to 330 °C, the nozzle-substrate distance range of 3 cm to 8 cm, and deposition times of 1 min to 16 min.

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References

  1. I. Taniguchi, R.C. van Landschoot, and J. Schoonman, Solid State Ionics 160, 271 (2003).

    Article  CAS  Google Scholar 

  2. T. S. Zhang, J. Ma, Y. J. Leng, S. H. Chan, P. Hing, and J. A. Kilner, Solid State Ionics 168, 187 (2004).

    Article  CAS  Google Scholar 

  3. D. Xu, X. Liu, D. Wang, G. Yi, Y. Gao, D. Zhang, and W. Su, J. Alloys Compd. 429, 292 (2007).

    Article  CAS  Google Scholar 

  4. J. C. Boivin and G. Mairesse, J. Chem. Mater. 10, 2870 (1998).

    Article  CAS  Google Scholar 

  5. S. Zhu, C. Xia and G. Meng, J. Power Sources 115, 44 (2003).

    Article  Google Scholar 

  6. J. M. Im, H. J. You, Y. S. Yoon, and D. W. Shin, J. Euro. Cera. Soc. 27, 3671 (2007).

    Article  CAS  Google Scholar 

  7. Y. Liu, W. Rauch, S. Zha, and M. Liu, Solid State Ionics 116, 261 (2004).

    Article  Google Scholar 

  8. K.R. Reddy and K. Karan, J. Electroceram. 15, 45 (2005).

    Article  CAS  Google Scholar 

  9. K. metha, R. Xu, and A.V. Virkary, J. Sol-Gel Sci. Tech. 11, 203 (1998).

    Article  Google Scholar 

  10. Y. Zhang, J. Gao, G. A. Meng, and X. Liu, J. Appl. Electro-Chem. 34, 637 (2004).

    Article  CAS  Google Scholar 

  11. W. F. Chu, Solid State Ionics 52, 243 (1992).

    Article  CAS  Google Scholar 

  12. J. H. Song, S. I. Park, J. H. Lee, and H. S. Kim, J. Mater. Process. Technol. 18, 414 (2008).

    Article  Google Scholar 

  13. Y. Takahashi and T. Kawae, J. Cryst. Growth. 74, 409 (1986).

    Article  CAS  ADS  Google Scholar 

  14. H. Chen and R. Xu, Thin Solid Films 298, 151 (1997).

    Article  Google Scholar 

  15. L. G. Coccia, G. C. Tyrrell, J. A. Kilner, D. Waller, R. J. Chater, and I. W. Boyd, Appl. Surf. Sci. 96, 795 (1996).

    Article  ADS  Google Scholar 

  16. S. Park, J. Park, K. Nam, and G. Park, J. Kor. Phys. Soc. 49, 460 (2006).

    Google Scholar 

  17. K. Hayashi, O. Yamamoto, Y. Nishigaki, and H. Minoura, Solid State Ionics 98, 49 (1997).

    Article  CAS  Google Scholar 

  18. V. G. Prokhorov, V. A. Komashko, V. L. Svetchnikov, K. K. Yu, S. Y. Park, J. S. Park, Y. P. Lee, and J. H. Kang, J. Kor. Phys. Soc. 48, 1417 (2006).

    CAS  Google Scholar 

  19. I. H. Jung, Y. K. Lee, and J. W. Park, J. Kor. Inst. Met. & Mater. 37, 1539 (1999).

    CAS  Google Scholar 

  20. A. Jaworek and A.T. Sobczyk, J. Electrostat. 66, 197 (2008).

    Article  CAS  Google Scholar 

  21. I. Taniguchi and J. Schoonman, J. Mater. Synth. Proces. 10, 267 (2002).

    Article  CAS  Google Scholar 

  22. I. Taniguchi, R. C. van Landschoot, and J. Schoonman, Solid State Ionics 156, 1 (2003).

    Article  CAS  Google Scholar 

  23. D. Beckel, A. Dubach, A. R. Studart, and L. J. Gauckler, J. Electroceram. 16, 221 (2006).

    Article  CAS  Google Scholar 

  24. W. Balachandran, J. Electrostat. 50, 249 (2001).

    Article  CAS  Google Scholar 

  25. A. M. Ganan-Calvo, J. Davila, and A. Barrero, J. Aerosol Sci. 28, 249 (1997).

    Article  CAS  Google Scholar 

  26. A. M. Ganan-Calvo, J. Aerosol Sci. 30, 973 (1999).

    Article  Google Scholar 

  27. T. Nguyen and E. Djurado, Solid State Ionics 138, 191 (2001).

    Article  CAS  Google Scholar 

  28. J. M. Im, H. J. You, Y. S. Yoon, and D. W. Shin, J. Kor. Phys. Soc. 53, 2636 (2008).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Division of Materials Science & Engineering, Hanyang University, Seoul, 133-791, Korea

    Jongmo Im, Inyu Park, Sungeun Jang & Dongwook Shin

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  1. Jongmo Im
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  2. Inyu Park
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  3. Sungeun Jang
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  4. Dongwook Shin
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Correspondence to Dongwook Shin.

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Im, J., Park, I., Jang, S. et al. Fabrication of porous lanthanum strontium manganite films by electrostatic spray deposition. Met. Mater. Int. 15, 1049–1053 (2009). https://doi.org/10.1007/s12540-009-1049-9

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  • DOI: https://doi.org/10.1007/s12540-009-1049-9

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