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Mineralogical and geochemical characterization of weathered materials in the gold-bearing quartz veins, Mintom area, Southern Cameroon

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Abstract

The presence and nature of gold can be better understood through mineralogical and geochemical characterization of weathered materials which derived from weathering of gold-bearing quartz veins in a granitic environment. This study was carried out in the Mintom area, located in southern Cameroon in order to boost gold extraction. It is focused on panning weathered materials of profiles on the field where gold grains were selected alongside heavy minerals using the Duplaix (1958) technique. X-ray diffraction was performed in bulk materials for mineralogical analyses. Furthermore, inductively coupled plasma-atomic emission spectrometry (ICP/AES), inductively coupled plasma-mass spectrometry (ICP/MS), and electronic microprobe analyses (EMPA) on the polished gold grains were performed to respectively determine the geochemical data of gold-bearing materials and the chemical composition of gold grains with other heavy inclusions. It should be noted that coarse saprolite represents the most mineralized portion of the soil, while in certain profiles, the upper nodular and clay-sandy horizons could be barren. The heavy minerals that accompany gold are epidote, zircon, tourmaline, amphibole, rutile, andalusite, beryl, topaz, apatite, and garnet of magmatic and metamorphic origins. They are imprisoned in a matrix consisting essentially of quartz (30.3 to 64.5 wt.%), kaolinite (23 to 47.63 wt.%), smectite (19.7 to 27.3 wt.%), goethite (5.4 to 11.3 wt.%), and hematite (1.4 to 7.4 wt.%). Gold (Au) proportions in coarse saprolite samples (2280 ppb) are higher than the minimal contents of gold in a geomaterial (2000 ppb) leading them to be considered as ores. Gold in fine saprolite (from 40 to 50 ppb), glebular (from 30 to 40 ppb), and clay-sandy (from 10 to 20 ppb) horizons exceeds its background values, displaying a positive geochemical anomaly which justifies a vertical proximity to a higher grade of gold deposits. Higher gold concentration (from 97.75 to 99.51 wt.%) observed in gold grains of coarse saprolite developed from quartz veins revealed that the analyzed quartz veins of the Mintom area are mineralized rocks. However, the presence of gold pathfinders such as Bi, Mo, Cu, and S implies both primary magmatic and hydrothermal genetic conditions.

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References

  • Adeleke Oke S, Akinlolu FA, Rammlmair D (2014) Mineralogical and geochemical characterization of gold bearing quartz veins and soils in parts of Maru Schist Belt Area, northwestern Nigeria. J Geol Res 314214:1–17

    Google Scholar 

  • Baker WE, Carlisle D, Berry WL, Kaplan IR, Watterson J (1986) Biological systems and organic matter, in mineral exploration, (éd.). Prentice-hall, Englewood Cliffs, New Jersey 377-407

  • Bamba O (1996) L'or disséminé dans les albitites de Larafella (Burkina Faso), évolution dans les altérites et les cuirasses ferrugineuses. Thesis, University of Aix-Marseille III, France p. 225

  • Bocquier G, Muller J, Boulange B (1984) Latérites : connaissances et perspectives actuelles sur les mécanismes de leur différenciation. Livre jubilaire du cinquantenaire de l’AFES. 123–138

  • Bodnar RJ, Reynolds TJ, Kuehn CA (1985) Fluid-inclusion systematics in epithermal systems. Rev Econ Geol 2:73–97

    Google Scholar 

  • Bonatti E, Kraemer T, Rydell H (1972) Classification and genesis of submarine iron-manganese deposits,” in Proceedings of the Conference on Ferromanganese Deposits on the Ocean Floor, DR Horn (Ed.), Arden House, Harriman, NY, USA, pp. 149–166

  • Bowell RJ, Foster RP, Gize P (1993) The mobility of gold in tropical rain forest soils. Econ Geol 88:999–1016

    Article  Google Scholar 

  • Boyle RW (1979) The geochemistry of gold and its deposits. Geol Survey Bulletin. p. 280p

  • Boyle RW (1984) Gold deposits: their geology, geochemistry and origin. In Gold ’82: The geology, geochemistry and genesis of gold deposits, Foster RP, Balkema AA (éd.), pp 183–190

  • Burnham OM, Schweyer J (2004) Trace element analysis of geological samples by inductively coupled plasma-mass spectrometry at the Geoscience Laboratories: revised capacities due to improvements to instrumentation. Ontario Geol Surv Open File Rep 6145(54):1–20

    Google Scholar 

  • Chapman RJ, Leake RC, Bond DPG, Stedra V, Fairgrieve B (2009) Chemical and mineralogical signatures of gold formed in oxidizing chloride hydrothermal systems and their significance within populations of placer gold grains collected during reconnaissance. Econ Geol 104:563–585

    Article  Google Scholar 

  • Chapman RJ, Mileham TJ, Allan MM, Mortensen JK (2017) A distinctive Pd-Hg signature in detrital gold derived from alkalic Cu-Au porphyry systems. Ore Geol Rev 83:84–102

    Article  Google Scholar 

  • Clark JR, Williams-Jones AE (1990) Analogues of epithermal gold-silver deposition in geothermal well scales. Nature 346:644–645

    Article  Google Scholar 

  • Colin F, Viellard Ph (1991) Behavior of gold in lateritic equatorial environment weathering and surface dispersion of residual gold particles at Dondo Mobi. Appl Geochem 6:270–290

    Article  Google Scholar 

  • Colin F, Vieillard Ph, Rosi JP (1993) Quantitative approach to physical and chemical gold mobility in equatorial rain-forest lateritic environment. Earth Planet Sci Lett 114:269–285

    Article  Google Scholar 

  • Colin F (1992) L'or traceur de l'histoire chimique de l'altérosphère latéritique sous forêt équatoriale. Habilitation à diriger les recherches. Thesis, University of Aix-Marseille III, France p. 171

  • Cooke DR, Simmons SF (2000) Characteristics and genesis of epithermal gold deposits. Rev Econ Geol 13:221–244

    Google Scholar 

  • Douwe JJ, Van Hinsbergen SJH, Buiter TH, Torsvik CG, Webb SJ (2011) The formation and evolution of Africa from the Archaean to present. Geol Soc London, Spec Publ 357:1–8. https://doi.org/10.1144/SP357.1

    Article  Google Scholar 

  • Duplaix S (1958) Détermination microscopique des minéraux des tables. 2ème éd. Paris, Liége, Librairie polytechnique ch. Beranger p. 96

  • Edou-Minko A, Colin F, Lecomte P, Trescases JJ (1992) Altération latéritique du gîte aurifère d’Ovala (Gabon) et formation d’une anomalie superficielle de dispersion. Miner Deposita 25:90–100

    Google Scholar 

  • Edou-Minko A (1989) Pétrologie et géochimie des laterites à 'stone-line' du gîte d'or d’Ovala. Application à la prospection en zone équatoriale humide (Gabon). Thesis, University of Poitiers, France, p. 147

  • Freyssinet Ph (1993) Gold dispersion related to ferricrete pedogenesis in South Mali: application to geochemical exploration. Chron Rech Minière 510:25–40

    Google Scholar 

  • Freyssinet Ph, Lecomte P, Edimo A (1989a) Dispersion of gold and base metals in the Mborguéné lateritic profile, East Cameroon. J Geochem Expl 32:99–116

    Article  Google Scholar 

  • Freyssinet Ph, Zeegers H, Tardy Y (1989b) Morphology and geochemistry of gold grains in lateritic profile of southern Mali. J Geochem Expl 32:17–31

    Article  Google Scholar 

  • Gazel J, Hourcq V, Nikclès M (1956) Carte géologique du Cameroun au 1/1 000 000 : notice explicative. Paris : Direction des mines et de la géologie du Cameroun. Bulletin de la direction des mines et de la géologie

  • Groves DI, Phillips GN, Hose Henderson CA, Clarke E (1984) Controls on distribution of Achaean hydrothermal gold deposits in Western Australia. In gold’82: The geology, geochemistry and genesis of gold deposits, Foster RP, Balkema AA (edition) pp 689–712

  • Guilbert JM, Park CF (1986) The geology of ore deposits. W.H. Freeman, New York, NY, USA

    Google Scholar 

  • Hedenquist JW, Arribas A (2000) Gonzalez-Urien, E. Exploration for epithermal gold deposits. Rev Econ Geol 13:45–47

    Google Scholar 

  • Hedenquist JW, Lowenstern JB (1994) The role of magmas in the formation of hydrothermal ore deposits. Nature 370:519–527

    Article  Google Scholar 

  • Huang XW, Qi L, Gao JF, Zhou MF (2013) First reliable Re-Os ages of pyrite and stable isotope composition of Fe(Cu) deposit in the Hami region, Eastern Tianshan orogenic belt, NW China. Resour Geol 63:166–187

    Article  Google Scholar 

  • Keays RR (1984) Archean gold deposits and their source rocks: the upper mantle connection. In Gold’82: The geology, geochemistry and genesis of gold deposits, Foster RP, Balkema AA (éd.) pp. 689–712

  • Kouankap Nono GD, Bongsiysi EF, Azinwi Tamfuh P, Nyangono Abolo AJ, Fomekong Kehding B, Fontem Kibong N, Suh EC (2021) Gold deposit type and implication for exploration in the Abiete-Toko Gold District, South Cameroon: constraint from morphology and microchemistry of alluvial gold grains. Heliyon 7:e06758

    Article  Google Scholar 

  • Lerouge C, Cocherie A, Toteu SF, Penaye J, Milési JP, Tchameni R, Deloule E (2006) Shrimp U-Pb zircon age evidence for Paleoproterozoic sedimentation and 2.05 Ga syntectonic plutonism in the Nyong Group, South-Western Cameroon: consequences for the Eburnean-Transamazonian belt of NE Brazil and Central Africa. J Afri Earth Sci 44(4–5):413–427

    Article  Google Scholar 

  • Machairas G (1970) Contribution à I'étude minéralogique et métallogénique de l'or. Bulletin de Recherche Géologique et Minière (fr.) Bulletin. (2e Série), Section 2, (3)p. 1–109

  • Mann AW (1984) Mobility of gold and silver in lateritic weathering profiles. Some observations from Western Australia. Econ Geol 79:38–49

    Article  Google Scholar 

  • Mbenoun AM, Ngon Ngon GF, Bayiga EC, Yongue-Fouateu R (2013) Gold Behavior in weathering products of quartz vein in Mintom Area South Cameroon (Central Africa). Intern J Geosci 4(10):1401–1410

    Article  Google Scholar 

  • McDonough WF, Sun SS (1995) The composition of the Earth. Chem Geol 120(3–4):223–253

    Article  Google Scholar 

  • McLennan SM, Hemming S, McDaniel DK, Hanson GN (1993) Geochemical approaches to sedimentation, provenance, and tectonics. Spec Paper Geol Soc Am 284:21–40

    Google Scholar 

  • McLennan MS (2001) Relationships between the trace element composition of sedimentary rocks and upper continental crust. Geochem Geophy Geosyst 2 (2000GC000109)

  • Michel D (1993) Minéralisations aurifères et morphoscopie de l’or natif. Thesis, Institut National Polytechnique de Lorraine, France p. 292

  • Ndjigui PD, Badinane MFB, Nyeck B, Nandjip HPK, Bilong P (2013) Mineralogical and geochemical features of the coarse saprolite developed on orthogneiss in the SW of Yaoundé, South Cameroon. J Afri Earth Sci 79:125–142

    Article  Google Scholar 

  • Nesbitt HW (1979) Mobility and fractionation of rare earth elements during weathering of the granodiorite. Nature 279:206–210

    Article  Google Scholar 

  • Ouangrawa M, Grandin G, Parisot JC, Baras E (1996) Mechanical gold dispersion in surperficial materials: example of Piela auriferous site (Burkina-Faso). Distinguished Lecture, Pangea 25:26–40

    Google Scholar 

  • Parisot JC, Ventose V, Grandin G, Bourges F, Debat P, Tollon F, Millo L (1995) Dynamique de l’or et d’autres minéraux lourds dans un profil d’altération cuirassé du Burkina Faso, Afrique de l’Ouest. Conséquence sur l’origine des matériaux constituant les cuirasses de haut-glacis. Compte Rendus Acad Sci Paris 32:295–302

    Google Scholar 

  • Recoche G (1989) Les concentrations aurifères supergènes liées aux minéralisations sulfurées polymétalliques de la ceinture volcano-sédimentaire d'Ariab-Arbaat. Red Sea hills, Soudan. Thesis, University of Toulouse, France, Published p. 318

  • Rowland JV, Simmons SF (2012) Hydrologic, magmatic, and tectonic controls on hydrothermal flow, Taupo Volcanic Zone, New Zealand: implications for the formation of epithermal vein deposits. Econ Geol 107:427–457

    Article  Google Scholar 

  • Sababa E, Gentry FC, Ndjigui PD, Onana PN, Seyoa DT (2021) Petrography and geochemistry of sulfurous volcanic scoria from mount Cameroon area, Central Africa: implications for Au-PGE exploration. J Afri Earth Sci 176:104–144

    Google Scholar 

  • Sea F, Tanguay MG, Trudel P, Perrault G (1990) Résultats préliminaires d’une étude sur la dispersion de l’or en milieu latéritique autour de l’indice aurifère de Misséni, au Mali. Canadian J Earth Sci 27:1686–1698

    Article  Google Scholar 

  • Shikazono N, Shimizu M (1988) Electrum: chemical composition, mode of occurrence and depositional environment. Bulletin-University Museum, The University of Tokyo p. 32

  • Simmons SF, White NC, John DA (2005) Geological characteristics of epithermal precious and base metal deposits. In Economic Geology; JW Hedenquist, JFH Thompson, RJ Goldfarb, JP Richards, (Eds.); Society of Economic Geologists: Littleton, CO, USA, 100:485–522

  • Smith BH, Keele RA (1984) Some observations on the geochemistry of gold mineralization in the weathered zone at Norseman, Western Australian. J Geochem Expl 22:1–20

    Article  Google Scholar 

  • Stoffregen R (1986) Observation on the behavior of gold during supergene oxidation at Summitville, Colorado, U. S. A., and implications for electrum stability in the weathering environment. Appl Geochem 1:549–558

    Article  Google Scholar 

  • Taksavasu T, Monecke T, Reynolds TJ (2018) Textural characteristics of noncrystalline silica in sinters and quartz veins: implications for the formation of bonanza veins in low-sulfidation epithermal deposits. Minerals 8(331):1–18

    Google Scholar 

  • Tardy Y (1993) Pétrologie des latérites et des sols tropicaux. Masson Ed.,p. 459

  • Taylor SR, McLennan SM (1985) The continental crust: its composition and evolution. Blackwell, Oxford, UK

    Google Scholar 

  • Tchameni R (1997) Géochimie et géochronologie des formations de l’Archéen et du Paléoprotérozoïque du Sud-Cameroun (groupe du Ntem, craton du Congo). Thesis, University of Orléans, France p. 356

  • Tchaptchet TW, Tematio P, Guimapi, TN,. Happi E, Tiomo I, Momo NM (2020) Morphological, mineral and geochemical characterization of soil profiles in Meïganga as tools for rock weathering intensity and trend evaluation and residual ore deposit prospection in the mineralized domain of central Cameroon. https://doi.org/10.1144/SP502-2019-84

  • Toteu SM, Van Schmus WR, Penaye J, Nyobe JB (1994) U-Pb and Sm-Nb evidence of Eburnean and Pan-Africain high – grade metamorphism in cratonic rock of southern Cameroon. Precamb Res 67:321–347

    Article  Google Scholar 

  • Toteu SF, Penaye J, Djomani YP (2004) Geodynamic evolution of the Pan-African belt in central Africa with special reference to Cameroon. Canadian J Earth Sci 41:73–85

    Article  Google Scholar 

  • Toteu SF, Penaye J, Deloule E, Van Schmus WR, Tchameni R (2006) Diachronous evolution of volcano-sedimentary basins north of the Congo craton, insights from U-PB Ion microprobe dating of zircons from Poli, Lom and Yaoundé groups (Cameroon). J Afr Earth Sci 44:428–442

    Article  Google Scholar 

  • Vicat JP (1998) Bilan des connaissances acquises sur les séries protérozoïques de la couverture du craton du Congo aux confins du Cameroun, du Centrafrique et du Congo. Géosciences au Cameroun, Vicat JP, et Bilong P, (éd.), Collection GEOCAM, 1/1998, Press Universitaire, Yaoundé I 3-1

  • Vidal C (1933) Etude de la Géologie Générale de la région de Yokadouma. Rapport Archivé de Série des Mines, Cameroun, (inédit)

  • Vishiti A, Suh CE, Lehmann B, Egbe JA, Shemang EM (2015) Gold grade variation and particle microchemistry in exploration pits of the Batouri gold district, SE Cameroon. J Afr Earth Sci 111:1–13

    Article  Google Scholar 

  • Vishiti A, Suh CE, Lehmann B, Shemang EM, Njumbe JN, Nfor Nshanji J, Fonkwo EC, Mongwe OY, Egbe AJ, Petersen S (2017) Mineral chemistry, bulk rock geochemistry, and S-isotope signature of lode-gold mineralization in the Bétaré Oya gold district, South-East Cameroon. Geological J 1–18https://doi.org/10.1002/gj.3093

  • White NC, Hedenquist JW (1995) Epithermal gold deposits: styles, characteristics and exploration. SEG Newsletters 23:9–13

    Google Scholar 

  • Wilson AF (1983) The economic significance of non-hydrothermal transport of gold, and the accretion of large gold nuggets in laterite and other weathering profiles in Australia. Spec Publ Geol Soc Sci Afr 7:229–234

    Google Scholar 

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Acknowledgements

The authors are grateful to the ‘‘Institut de Recherche pour le Développement’’ (IRD), France, for mineralogical analyses, ALS Chemex Analytical Laboratories, South Africa for geochemical analyses, and the SGS laboratories of Johannesburg, South Africa for electronic microprobe analyses (EMPA).

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Conceptualization: M.A.M. and G.F.N. Methodology: M.A.M., M.B.M., and G.F.N. Formal analysis: M.A.M., G.T.N., and G.F.N. Investigations: M.A.M., M.B.M., J.S.M., and G.F.N. Data curation: M.A.M., G.T.N., J.S.M., and G.F.N. Resources: M.A.M., G.T.N., and G.F.N. Supervision: G.F.N. and P.B. Visualization: M.A.M., G.F.N., and P.B. Writing original draft—preparation: M.A.M., M.B.M., and G.F.N. Writing—review and editing: M.A.M. and G.F.N. All authors have read and agreed to the published version of the manuscript.

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Correspondence to Gilbert François Ngon Ngon.

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Mbenoun, M.A., Ngon Ngon, G.F., Ngouabe, G.T. et al. Mineralogical and geochemical characterization of weathered materials in the gold-bearing quartz veins, Mintom area, Southern Cameroon. Arab J Geosci 16, 105 (2023). https://doi.org/10.1007/s12517-022-11120-3

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