Abstract
The present study was carried out to assess the drinking and irrigation water quality of groundwater resources of the Thettiyar watershed, Thiruvananthapuram district, Kerala, India. The water quality of the study area is explained by using multiple water quality analysis techniques, such as water quality index, spatial assessment of groundwater through GIS-based interpolation technique, and also multivariate statistical analysis. Piper trilinear diagram was used to recognize the water type in the study area. The USSL diagram and Wilcox diagram were used in this study to identify the suitability of the irrigation water. A total of 50 groundwater samples were taken during the pre-monsoon and the monsoon. The samples were tested for various physico-chemical parameters such as pH, EC, TDS, and the major cations and anions. The results show that the groundwater in the study area is acidic; during pre-monsoon, the pH varies from 4.5 to 7.8 with an average of 6.3 and in the monsoon, the pH of water samples is 4.26 to 7.6 with an average of 5.64. The concentration of all other parameters is within the permissible limit. Pollution index of groundwater (PIG) unveiled that the study area has insignificant pollution in terms of drinking water quality. Factor analysis of groundwater revealed three pre-monsoon factors and four monsoon seasonal factors were obtained from this analysis. The varifactors resulting from the factor analysis have shown that the quality fluctuations are mainly due to activities such as water-rock interaction, dilution activity, and anthropogenic activities. Various analytical and statistical studies in the region have shown that the quality of groundwater is influenced by the combined activities of natural activities and anthropogenic events. The detailed study revealed that groundwater sources in the Thettiyar watershed are suitable for drinking and irrigation purposes.
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References
Abdul-Wahab SA, Bakheit CS, Al-Alawi SM (2005) Principal component and multiple regression analysis in modelling of ground-level ozone and factors affecting its concentrations. Environ Model Softw 20:1263–1271. https://doi.org/10.1016/j.envsoft.2004.09.001
Adams S, Titus R, Pietersen K, Tredoux G, Harris C (2001) Hydrochemical characteristics of aquifers near Sutherland in the Western Karoo, South Africa. J Hydrol 241:91–103
Aiuppa A, Bellomo S, Brusca L, D’Alessandro W, Federico C (2003) Natural and anthropogenic factors affecting groundwater quality of an active volcano (Mt. Etna, Italy). Appl Geochem 18:863–882
Akwensioge M (2012)The influence of anthropogenic nitrate on groundwater quality in the Thaba Nchu area. A thesis report for University of the Free State Bloemfontein
Ananth M, Rajesh R, Amjith R, Achu AL, Valamparampil MJ, Harikrishnan M, Resmi MS, Sreekanth KB, Sara V, Sethulekshmi S, Prasannakumar V, Deepthi SK, Jemin AJ, Krishna DS, Anish TS, Insija IS, Nujum ZT (2018) Contamination of household open wells in an urban area of Trivandrum, Kerala State, India: a spatial analysis of health risk using geographic information system Environ Health Insights Volume 12: 1–9. https://doi.org/10.1177/1178630218806892
Anchal S, Ganguly R, Gupta AK (2020) Impact assessment of leachate pollution potential on groundwater: an indexing method. J Environ Eng 146(3):05019007. https://doi.org/10.1061/(ASCE)EE.1943-7870.0001647
Anna FR (2018) Correlation between conductivity and total dissolved solid in various type of water: A review. IOP Conf Ser: Earth Environ Sci 118:012019. https://doi.org/10.1088/1755-1315/118/1/012019
APHA (1995) Standard methods for the examination of water and wastewater, American Public Health Association, USA, 14th edition, Washington D.C
APHA (2005) Standard Methods for the Examination of Water and Wastewater. 21st Edition, American Public Health Association/American Water Works Association/Water Environment Federation, Washington DC.
Appelo CAJ, Postma D (2005) Geochemistry, groundwater and pollution (Amsterdam: CRC Oress, Taylor & Francais Group
Arvind G, Nagarajan M, Lalitha R, Baskar M (2020) GIS-based Assessment of groundwater quality for drinking and irrigation by water quality index. Int J Curr Microbiol App Sci 9(3):2361–2370. https://doi.org/10.20546/ijcmas.2020.903.269
Ashley RP, Lloyd JW (1978) An example of the use of factor analysis and cluster analysis groundwater chemistry interpretation. J Hydrol 39:355–364
Barbara GT, Linda SF (2001) Using multivariate statistics, fourth edition. Allyn & Bacon. ISBN 0-321-05677-9, Needham Heights, p 588
Barcelona M, Gibb J, Helfrich J, Garske E (1985) A practical guide for ground-water sampling. Practical Guide For Ground Water Sampling
Behera B, Das M (2018) Application of multivariate statistical techniques for the characterization of groundwater quality of Bacheli and Kirandul area, Dantewada District, Chattisgarh. J Geol Soc India 91(January 2018):76–80
Bengraïne K, Marhaba TF (2003) Using principal component analysis to monitor spatial and temporal changes in water quality. J Hazard Mater 100:179–195. https://doi.org/10.1016/S0304-3894(03)00104-3
Binoj Kumar RB, Divya MP (2012) Spatial evaluation of groundwater quality in Kazhakuttam block, Thiruvananthapuram district, Kerala. J Geol Soc India 80:48–56. https://doi.org/10.1007/s12594-012-0117-9
BIS (2012) Indian Standards Drinking Water Specifications IS 10500:2012. Bur Indian Stand Indian Stand Drink Water Specif 2:11
Brumelis G, Lapiņa L, Nikodemus O, Tabors G (2000) Use of an artificial model of monitoring data to aid interpretation of principal component analysis. Environ Model Softw 15:755–763. https://doi.org/10.1016/S1364-8152(00)00060-8
Burri NM, Weatherl R, Moeck C, Schirmer M (2019) A review of threats to groundwater quality in the anthropocene. Sci Total Environ 684:136–154. https://doi.org/10.1016/j.scitotenv.2019.05.236
Burrough PA, McDonnell RA (1998) Principles of geographical information systems. Oxford University Press, Oxford
Carreira PM, Marques JM, Nunes D (2014) Source of groundwater salinity in coastline aquifers based on environmental isotopes (Portugal): Natural vs. human interference. A review and reinterpretation. Appl Geochem 41:163–175
CGWB (2002) ‘Groundwater Balance. Mass Awareness Programme in Ernakulam District on January 5th 2002 By CGWB, Kerala Region’, Thriruvananthapuram, Kerala
CGWB (2014) Concept Note on Geogenic Contamination Of Ground Water In India with a special note on Nitrate. Central Ground Water Board Ministry of Water Resources Govt. of India. Faridabad
Chaitanya BP, Moharir K (2018) Spatial analysis of groundwater quality mapping in hard rock area in the Akola and Buldhana districts of Maharashtra, India. Appl Water Sci 8:106. https://doi.org/10.1007/s13201-018-0754-2
Chen TB, Zheng YM, Lei M et al (2005) Assessment of heavy metal pollution in surface soils of urban parks in Beijing, China. Chemosphere 60:542–551. https://doi.org/10.1016/j.chemosphere.2004.12.072
Cressie N (1993) Statistics for spatial data. Wiley, New York, p 900
Da Silva Peixoto F, Cavalcante IN, Gomes DF (2020) Influence of land use and sanitation issues on water quality of an urban aquifer. Water Resour Manag 34:653–674. https://doi.org/10.1007/s11269-019-02467-6
Dalton MG, Upchurch SB (1978) Interpretation of hydrochemical facies by factor analysis. Groundwater 16(4):228–233
Datta PS, Bhattacharya SK, Tyagi SK (1996) Studies on recharge of phreatic aquifers and groundwater flow-paths of mixing in the Delhi area. J Hydrol 176:25–36 water analyses. Trans. Amer. Geophys. Union, v.25, pp.914–928
Davis JC (1973) Statistics and Data Analysis in Geology. Wiley, New York
Dawoud MA, Raouf ARA (2009) Groundwater exploration and assessment in rural communities of Yobe State, Northern Nigeria. Water Resour Manag 23(3):581–601
Dhakate Mahesh J, Sankaran S, RaoVVS Gurunadha (2013) Multivariate Statistical Analysis for Assessment of Groundwater Quality in Talcher Coalfield Area, Odisha. Journal Geological Society of India 82:403–412
Dhok R, Patil A, Ghole V (2013) Hardness of groundwater resources and tts suitability for drinking purpose. Int J Pharm Chem Sci 2:169–172
Doneen LD (1962) The influence of crop and soil on percolating water. Proc. 1961 Biennial Conference on Groundwater Recharge, Pp.156-163
Drever JF (1988) The chemistry of natural waters, Vol 3. Prenticehall, New York
Eaton FM (1950) Significance of carbonates in irrigation waters. Soil Sci 69.2:123–134
Fetter CW (1988) Applied hydrogeology, Vol 2. Merrill Publishing Company, London
Flipse WJ Jr, Bonner FT (1985) Nitrogen-isotope ratios of nitrate in ground water under fertilized fields, Long Island, New York. Groundwater 23.1(1985):59–67
Ghandour El, Khalil JB, Atta SA, Giza (1983) Distribution of sodium and potassium in the groundwater of the Nile Delta Region Egypt. CATENA 10:175–187
Gulgundi MS, Shetty A (2018) Groundwater quality assessment of urban Bengaluru using multivariate statistical techniques. Appl Water Sci 8(2018):43. https://doi.org/10.1007/s13201-018-0684-z
Gupta SC (1992) Udaipur kshetra ke bhujal mein nitrate ka badhta star, Bhu-Jal News, 7, 17-19
Harter T (2003) Groundwater quality and groundwater pollution. Groundw Qual Groundw Pollut. https://doi.org/10.3733/ucanr.8084
Hem JD (1985) Study and interpretation of the chemical characteristics of natural water. 3rd Edition, US Geological Survey Water-Supply Paper 2254, University of Virginia, Charlottesville, 263 p
Islam M, Marandi A, Fatema S, Zahid A, Schüth C (2019) The evolution of the groundwater quality in the alluvial aquifers of the south-western part of Bengal Basin, Bangladesh. Environ Earth Sci 78(2019):705. https://doi.org/10.1007/s12665-019-8714-1
Jacks G, Sharma VP (1983) Nitrogen circulation and nitrate in groundwater in an agricultural catchment in southern India. Environ Geol 5(2):61–64
James AJ (2005) Groundwater sampling techniques for environmental projects https://doi.org/10.1002/047147844X.gw452
Jayakumar R, Siraz L (1997) Factor analysis in hydrogeochemistry of coastal aquifers – a preliminary study. Environ Geol 31:174–177
Jena V, Sinha D (2017) Ground water quality assessment by multivariate factor analysis. Res J Chem Environ 21:21–25
Jha BM, Sinha SK (2009) Towards better management of ground water resources in India. QJ 24 (4), 1–20
Kelly WP, Brown SM, Liebig F Jr (1940) Chemical effects of saline irrigation water on soils. Soil Sci 49:95–107
Knutsson G (1994) Acidification effects on groundwater - prognosis of the risks for the future. Futur Groundw Resour risk 3–17
Kumari M, Rai SC (2020) Hydrogeochemical evaluation of groundwater quality for drinking and irrigation purposes using water quality index in semi arid region of India J Geol Soc India Vol.95, February 2020, pp.159-168
Kuppusamy MR, Giridhar VV (2006) Factor analysis of water quality characteristics including trace metal speciation in the coastal environmental system of Chennai Ennore. Environ Int 32:174–179. https://doi.org/10.1016/j.envint.2005.08.008
Li P, Wu J (2019) Drinking water quality and public health. Expo Health 11:73–79.370. https://doi.org/10.1007/s12403-019-00299-8
Little J, Kalischuk A, Gross D, Sheedy C (2010) Assessment of water quality in Alberta’s irrigation districts. Alberta Agriculture and Rural Development, Alberta, Canada
Love D, Hallbauer D, Amos A, Hranova R (2004) Factor analysis as a tool in groundwater quality management: two southern African case studies. Phys Chem Earth 29:1135–1143. https://doi.org/10.1016/j.pce.2004.09.027
Manson SM, Burrough PA, McDonnell RA (1999) Principles of geographical information systems: spatial information systems and geostatistics. Econ Geogr 75:422. https://doi.org/10.2307/144481
Martinez L, Borrajo JL, De Miguel EG, Arrans JR, Estevez MCH, Castillo AJS (2008) Multivariate analysis of contamination in the mining district of Linares (Jaén, Spain). Appl Geochem 23:2324–2336
Mathew G, Dalton S, Upchurch B (1978) Interpretation of hydrochemical facies by factor analysis. Ground Water, v.16 (4), pp.228-233
Miljevic N, Boreli-Zadravkovic D (2013) Evaluation of the origin of sulphate at the groundwater sources Klux, Siberia Assessment of Seasonal Variation in Surface Water Quality of the Mooi and Vaal Rivers Network, South Africa Alusani Manyatshe, Elvis Fosso-Kankeu, Divan van der Berg, Nico Lemmer, Frans Waanders, Tutu Hlanganani Int
Mitra BK, Sasaki C, Enari K, Matsuyama N (2007) Suitability assessment of shallow groundwater for irrigation in Sand Dune area of Northwest Honshu Island, Japan. Int J Agric Res 2(6):518527
Murphy R, Curriero F, Ball W (2010) Comparison of spatial interpolation methods for water quality evaluation in the Chesapeake Bay. J Environ Eng ASCE 136. https://doi.org/10.1061/(ASCE)EE.1943-7870.0000121.
Nageswara RJ, Ramadurai (1970) Systematic geohydrological survey of coastal plains in Malappuram, Trichur and Eranakulam Districts, Unpublished GSI report
Nandakumaran P (2012) Changes in groundwater utilization in Kerala causes & consequences Conference Paper · January 2012 DOI: https://doi.org/10.13140/RG.2.1.4956.1769
Nicholas PC (1997) 4 - Groundwater Contamination, Editor(s): Nicholas P. Cheremisinoff, Groundwater remediation and treatment technologies, William Andrew Publishing, 1997, Pages 127-168, ISBN 9780815514114, https://doi.org/10.1016/B978-081551411-4.50006-5.
Pawar NJ (1996) Groundwater quality and management, IGNOU Publ. 10
Piper AM (1953) A graphic procedure in the geochemical interpretation of water analysis. USGS Groundwater Note no.12, 63 p
Purandara BK, Varadarajan N, Jayashree K (2003) Impact of sewageon groundwater quality A case study, Poll Res Environmedia, 22(2), pp 189198
Qian H, Chen J, Howard KWF (2020) Assessing groundwater pollution and potential remediation processes in a multi-layer aquifer system, Environ Pollut, Volume 263,PartA,2020,114669,ISSN0269-7491, https://doi.org/10.1016/j.envpol.2020.114669
Raghunath HM (1987) Groundwater. Wiley Eastern Ltd, Delhi, p 563
Raghunath HM (1987) Groundwater. Wiley Eastern Ltd., New Delhi, pp 344–369
Rajani V (2015) Groundwater pollution in Kerala- a review Em International, Publishers Of Quality International Journals Vol 34, Issue 1, 2015; Page No.(69-74)
Rana R, Ganguly R, Gupta AK (2018) Indexing method for assessment of pollution potential of leachate from non-engineered landfill sites and its effect on ground water quality. Environ Monit Assess 190:46. https://doi.org/10.1007/s10661-017-6417-1
Rani VR (2013) Ground water information booklet of Trivandrum District, Kerala Government of India Ministry of Water Resources Central Ground Water Board
Ratnakar D, Mahesh J, Sankaran S, Gurunadha Rao VVS (2015) Multivariate statistical analysis for assessment of groundwater quality in Talcher Coalfield area, Odisha J Geol Soc India Vol.82, October 2013, Pp.403-412
Ravikumar P, Somashekar RK (2012) Assessment and modelling of groundwater quality data and evaluation of their corrosiveness and scaling potential using environmetric methods in Bangalore South Taluk, Karnataka state, India. Water Res 39:446–473. https://doi.org/10.1134/S0097807812040112
Ravikumar P, Somashekar RK (2013) A geochemical assessment of coastal groundwater quality in the Varahi river basin, Udupi District, Karnataka State, India. Arab J Geosci 6:1855–1870. https://doi.org/10.1007/s12517-011-0470-9
Reddy SK (2013) Assessment of groundwater quality for irrigation of Bhaskar Rao Kunta watershed, Nalgonda District, India, Vol 5(7), pp. 418-425, July 2013
Reghunath R, Murthy TRS, Raghavan BR (2002) The utility of multivariate statistical techniques in hydrogeochemical studies: an example from Karnataka, India. Water Res 36:2437–2442. https://doi.org/10.1016/S0043-1354(01)00490-0
Richard LA (1954) Diagnosis and improvement of Saline and Alkali soils. – Agric. Handbook 60, (U.S. Dept. Agric., Washington, D.C., 160 pp
Rusydi AF (2019) Correlation between conductivity and total dissolved solid in various type of water: a review. IOP Conf Series: Earth Environ Sci 118(2018):012019. https://doi.org/10.1088/1755-1315/118/1/012019
Saha S, Reza AHMS, Roy MK (2019) Hydrochemical evaluation of groundwater quality of the Tista Floodplain, Rangpur, Bangladesh. Appl Water Sci 9:198 (2019). https://doi.org/10.1007/S13201-019-1085-7
Sajinkumar KS, Revathy A, Rani VR (2017) Hydrogeochemistry and spatio-temporal changes of a tropical coastal wetland system: Veli-Akkulam Lake, Thiruvananthapuram, India. Appl Water Sci 7:1521–1534. https://doi.org/10.1007/s13201-015-0333-8
Salehi S, Chizari M, Sadighi H, Bijani M (2018) Assessment of agricultural groundwater users in Iran: a cultural environmental bias Hydrogeol J, 26 (1) (2018), Pp. 285-295, https://doi.org/10.1007/S10040-017-1634-9
Salifu M, Aidoo F, Hayford MS, Adomako D, Asare E (2017) Evaluating the suitability of groundwater for irrigational purposes in some selected districts of the Upper West region of Ghana. Appl Water Sci 7(2017):653–662. https://doi.org/10.1007/s13201-015-0277-z
Sameer V, Yamakanamardi, Hampannavar US, Purandara BK (2011) Assessment of chloride concentration in groundwater: a case study for Belgaum city Int J Environ Sci Volume 2, No 1, 2011 ISSN 0976 – 4402
Sawyer GN, McCarthy DL (1967) Chemistry of sanitary engineers, 2nd edn. Mc Graw Hill, New York, p 518
Sawyer C, McCarty P, Parkin G (1994) Chemistry for Environmental Engineering (Singapore: McGraw-Hill, Inc)
Sawyer C, McCarty P, Parkin G (2003) Chemistry for environmental and engineering Science. 5 th edition, McGraw Hill Inc, pp 587-590. ISBN-10: 0072480661
Schot PP, van der Wal J (1992) Human impact on regional groundwater composition through intervention in natural flow patterns and changes in land use. J Hydrol 134:297–313
Selvam S, Manimaran G, Sivasubramanian P et al (2013) GIS-based evaluation of water quality index of groundwater resources around Tuticorin coastal city, south India. Environ Earth Sci 71:2847–2867. https://doi.org/10.1007/s12665-013-2662-y
Selvam S, Singaraja C, Venkatramanan SJ, Chung SY (2018) Geochemical Appraisal of Groundwater Quality in Ottapidaram Taluk, Thoothukudi District, Tamil Nadu using Graphical and Numerical Method. Journal of the Geological Society of India 92:313–320
Shahbeik S, Afzal P, Moarefvand P (2014) Comparison between ordinary kriging (OK) and inverse distance weighted (IDW) based on estimation error. Case study: Dardevey iron ore deposit, NE Iran. Arab J Geosci 7(2014):3693–3704. https://doi.org/10.1007/s12517-013-0978-2
Simeonov V, Einax JW, Stanimirova I, Kraft JK (2002) Groundwater pollution in Kerala- a review Anal Bional Chem, v.374, pp.898.Vol 34, Issue 1, 2015; Page No.(69-74)
Soman K (2002) Geology of Kerala. Geological Society of India, Bangalore
Soman K (2016) Status report on ground water potential and use in Trivandrum District with special emphasis on Trivandrum City. Center for development study, Thiruvananthapuram
Soman K, Slukin AD (1987) Lateritization cycles and their relation to the formation and quality of kaolin deposits in south Kerala, India. Volume 60, Issues 1–4, 10 March 1987, Pages 273-280 https://doi.org/10.1016/0009-2541(87)90132-Xb
Subba Rao N (2012) PIG: a numerical index for dissemination of groundwater contamination zones. Hydrol Process 26(22):3344–3350
Subba Rao N, Sunitha B, Rambabu R, Nageswara Rao PV, Surya Rao P, Spandana BD, Sravanthi M, Marghade D (2018) Quality and degree of pollution of groundwater, using PIG from a rural part of Telangana State, India. Appl Water Sci 8:227. https://doi.org/10.1007/s13201-018-3950864-x
Subba Rao N, Sunitha B, Adimalla N, Chaudhary M (2019) Quality criteria for groundwater use from a rural part of Wanaparthy District, Telangana State, India, through ionic spatial distribution (ISD), entropy water quality index (EWQI) and principal component analysis (PCA). Environ Geochem Health. https://doi.org/10.1007/s10653-019-00393-5
Subramani T, Elangos, Damodarasam R (2005) Groundwater quality and its suitability for drinking and agricultural use in Chitharriver Basin, Tamil Nadu, India. Environ Geol 47(2005):1099–1110. https://doi.org/10.1007/S00254-005-1243-0
Swati B, Khan MMA (2020) Assessment of ground water quality of central and southeast districts of NCT of Delhi J Geol Soc India Vol.95, January 2020, pp.95-103
Thirumalini S, Joseph K (2009) Correlation between electrical conductivity and total dissolved solids in natural waters. Malaysian J Sci 28:56–61. https://doi.org/10.22452/Mjs.Vol28no1.7
Todd DK (1959) Groundwater hydrology. John Wily & Sons, Inc., New York
Tubau I, Vázquez-Suñé E, Carrera J et al (2017) Quantification of groundwater recharge in urban environments. Sci Total Environ 592:391–402. https://doi.org/10.1016/j.scitotenv.2017.03.118
WHO (1996) Guidelines for drinking-water quality. Vol. 2, Health criteria and other supporting information, 2nd ed. World Health Organization
World Health Organization (WHO) (2004) Guidelines for drinking water quality. Recommendations, Geneva, Switzerland, Vol 3
World Health Organization (WHO) (2017) Guidelines for drinking-water quality, 4th edition, incorporating the 1st addendum ISBN: 978-92-4-154995-0
Wilcox LV (1948) The quality of water for irrigation use. Technical bulletin, vol 962. U.S. Department of Agriculture, Washington, DC, p 40
Wilcox L (1955) Classification and uses of irrigation waters. USDA Circular No. 969, Washington, DC
William RR (2016) The environmental fate of representative antistatic agents and components, pp 421-431
Yasrebi J, Saffari M, Fathi H, Karimian N, Moazallahi M, Gazni R (2009) Evaluation and comparison of ordinary kriging and inverse distance weighting methods for prediction of spatial variability of some chemical parameters. Res J Biol Sci 4:93–102
Zacheus OM, Martikainen PJ (1997) Physicochemical quality of drinking and hot waters in Finnish building originated from groundwater or surface water plants. Sci Total Environ 204:1–10
Zimmerman D, Pavlik C, Ruggles A, Armstrong MP (1999) An experimental comparison of ordinary and universal kriging and inverse distance weighting. Math Geol 31:375–390
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The author is grateful to the head of the Department of Geology, University of Kerala, Thiruvananthapuram, for providing laboratory facilities and IIUCNRM, University of Kerala, Kariavattom campus, Thiruvananthapuram, for aiding assistance and equipment during field. Authors are also grateful to Shri. A.P.C.V. Chockalingam (Secretary) and Dr. C.Veerabahu (Principal), V.O.Chidambaram College, Tuticorin for their support and guidance.
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Nath, A.V., Selvam, S., Reghunath, R. et al. Groundwater quality assessment based on groundwater pollution index using Geographic Information System at Thettiyar watershed, Thiruvananthapuram district, Kerala, India. Arab J Geosci 14, 557 (2021). https://doi.org/10.1007/s12517-021-06820-1
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DOI: https://doi.org/10.1007/s12517-021-06820-1