Abstract
The wall rocks of Sidi Driss mineralization contain continental molassic deposits: lacustrine limestones, ferruginous fragments, Ed Diss unit and Numidian unit fragments, rhyodacitic fragments, pyroclasts, and gneissic fragments. The ore is composed of pyrite, marcasite, sphalerite, galena, barite, celestite, siderite, calcite, and iron oxide-hydroxides. The abandoned wastes in Sidi Driss-Tamra district contain marcasite, galena, goethite, jarosite, anglesite, anhydrite, bassanite, and gypsum. It is very important to assess the hazards and risks that this material type poses to public health and the environment. However, evaluation of a part of toxic elements always poses problems since the associated matrix, the close relationships between some minerals, the grain sizes and their forms (oolites, compact collomorphes aggregate), the oxidation degree of metals, the chemical composition, and trace elements make it difficult to extract mobile metals from complex Sidi Driss tailings and minerals found in these acidic wastes. Nevertheless, there is no universal method that can systematically evaluate metal bioavailability. And the use of proposed sequential extraction procedures for sediments with simple mineralogical composition did not yield any reproducible results for this type of acid mine drainage sediments. Consequently, the methods of controlling and mitigating the risks of hazardous materials should be considered. Many extraction procedures have been applied to better evaluate the mobility of hazardous materials (metals), the characterization of their degree of toxicity, and their chemical behavior in these complex mine tailings. Reproducible results were obtained with lab-scale washing of sediments using distilled water, CaCl2 and Na2-EDTA solutions, and BCR sequential extraction. The results showed that the BCR extraction approach was the most efficient procedure for these types of wastes. The extraction with distilled water is recommended for identification of the total quantity of mobile Cr and Fe.
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Acosta JA, Faz A, Kalbitz K, Jansen B, Martínez-Martínez S (2014) Partitioning of heavy metals over different chemical fraction in street dust of Murcia (Spain) as a basis for risk assessment. J Geochem Explor 144:298–305
Adamo P, Zampella M (2008) Chemical speciation to assess potentially toxic metals (PTMs) bioavailability and geochemical forms in polluted soils. In: De Vivo, B., Belkin, H. E., Lima, A. (Eds.). Environ geochemistry: site characterization, data analysis and case histories 175–212
Adriano DC (2001) Trace elements in terrestrial environment: biogeochemistry, bioavailability and risks of metals, 2nd edn. Springer Verlag, New York
Adriano DC, Wenzel WW, Vangronsveld J, Bolan NS (2004) Role of assisted natural remediation in environmental cleanup. Geoderma 122:121–142
AFNOR (1979) France norms AFNOR www afnor fr
Anjos C, Magalhaes MCF, Abereu MM (2012) Metal (Al, Mn, Pb and Zn) soils extractable reagents for available fraction assessment: comparison using plants, and dry and moist soils from the Bracal abandoned lead mine area, Portugal. J Geochem Explor 113:45–55
Arain MB, Kazi TG, Jamali MK, Afridi HI, Jalbani N, Sarfraz RA, Baig JA, Kandhro GA (2008) Determination of arsenic levels in lake water, sediment, and foodstuff from selected area of Sindh, Pakistan: estimation of daily dietary intake. Memon J Hazard Mater 160:235–239
Azouzi R, Charef A, Hamzaoui AH (2015) Assessment of effect of pH, temperature and organic matter on zinc mobility in a hydromorphic soil. Environ Earth Sci 74:2967–2980
Baize D (1997) Teneurs totales en éléments traces métalliques dans les sols (France). Références et stratégies d’interprétation, Paris, INRA Éditions, 410p
Balci N, Mayer B, Shanks WC, Mandernack KW (2012) Oxygen and sulfur isotope systematics of sulfate produced during abiotic and bacterial oxidation of sphalerite and elemental sulfur. Geochim Cosmochim Acta 77:335–351
Belzile N, Devitre RR, Tessier A (1989) In situ collected of diagenetic of iron and manganese oxides-hydroxides from natural sediments. Nature 340:376–377
Bermond A, Ghestem JP, Yousfi I (1998) Kinetic approach to the chemical speciation of trace metals in soils. Analyst 123:785–789
Cappuyns V, Swennen R, Niclaes M (2007) Application of the BCR sequential extraction scheme to dredged pond sediments contaminated by Pb–Zn mining: a combined geochemical and mineralogical approach. J Geochem Explor 93:78–86
Chou ML, Jean JS, Yang CM, Hseu ZY, Chen YH, Wang HL, Das S, Chou LS (2016) Inhibition of ethylene diamine tetraacetic acid ferric sodium salt (EDTA-Fe) and calcium peroxide (CaO2) on arsenic uptake by vegetables in arsenic-rich agricultural soil. J Geochem Explor 163:19–27
Davidson CM, Thomas RP, Mcvey SE, Perala R, Littlejohn D, Ure AM (1994) Evaluation of a sequential extraction procedure for the speciation of heavy-metals in sediment. Anal Chim Acta 291(3):277–286
Davidson CM, Duncan AL, Littlejohn D, Ure AM, Garden LM (1998) A critical evaluation of the three-stage BCR sequential extraction procedure to assess the potential mobility and toxicity of heavy metals in industrially-contaminated land. Anal Chim Acta 363:45–55
Dean JR (2007) Bioavailability, bioaccessibility and mobility of environment contaminants. Analytical Techniques in the Sciences Wiley, Chichester 291p
Decrée S, De Putter T, Yans J, Dupuis C. (2008) Iron mineralisation in Mio-Pliocene sediments of the Tamra iron mine (Nefza mining district, Tunisia): Mixed influence of pedogenesis and hydrothermal alteration. Ore Geol Rev 33(3):397–410
Decrée S, Marignac C, Putter TD, Deloule E, Liégeois JP, Demaiffe D (2010) Pb–Zn mineralization in a Miocene regional extensional context: the case of the SidiDriss and the Douahria ore deposits (Nefza mining district, northern Tunisia). Ore Geol Rev 34:285–303
Favas PJC, Pratas J, Elisa M, Gomesa P, Calac V (2011) Selective chemical extraction of heavy metals in tailings and soils contaminated by mining activity: environmental implications. J Geochem Explor 111:160–171
Feng MH, Shan XQ, Zhang S, Wen B (2005) A comparison of the rhizosphere-based method with DTPA, EDTA, CaCl2, and NaNO3 extraction methods for prediction of bioavailability of metals in soil to barley. Environ Pollut 137:231–240
Fernández-Ondoño E, Bacchetta G, Lallena AM, Navarro FB, Ortiz I, Jiménez MN (2017) Use of BCR sequential extraction procedures for soils and plant metal transfer predictions in contaminated mine tailings in Sardinia. J Geochem Explor 172:133–141
Gottis CH, Stainfeld P (1952) Les gites metalliferes, anales des mines, Tunis, 122p
Gupta SK, Vollmer MK, Krebs R (1996) The importance of mobile, mobilisable and pseudo total heavy metal fractions in soil for three-level risk assessment and risk management. Sci Total Environ 178:11–20
Hakkou R, Benzaazoua M, Bussière B (2008) Acid mine drainage at the abandoned Kettara mine (Morocco):1. Environmental characterization. Mine Water Environ 27:145–159
Hammer D, Keller C (2002) Changes in the rhizosphere of metal-accumulating plants evidenced by chemical extractants. J Environ Qual 31:1561–1569
Hass A, fine P (2010) Sequential selective extraction procedures for the study of heavy metals in soils, sediments, and waste materials—a critical review. Critical reviews. Environ Sci Technol 40:365–399
Hirner AV (1992) Trace element speciation in soil and sediment using sequential chemical extraction methods. Int J Environ Anal Chem 46:77–85
Houba, VJG, Novozamsky I, Lexmond ThM, Vander Lee JJ (1990) Applicability of 0.01 M CaCl2 as single extraction solution for the assessment of the nutrient status of soils and other diagnostic purposes. Soil Sci Plant Anal 21:2281–2290
Jenning SR, Dollhopf DJ, Inskeep WP (2000) Acid production from sulfide minerals using hydrogen peroxide weathering. Appl Geochem 15(2):247–255
Juste C (1988) Appréciation de la mobilité et de la biodisponibilité des éléments en traces du sol. Sci Sol 26:103–111
Juste C (1989) Mobilité et biodisponibilité des oligo-éléments, in: Les oligo-éléments et le sol, 2e journées de l’analyse de terre, GEMAS, Éditions Frontières, 5–15
Kabata-Pendias A (1993) Behavioral properties of trace metals in soils. Appl Geochem, Suppl 2:3–9
Kabata-Pendias A (2004) Soil–plant transfer of trace elements-an environmental issue. Geoderma 122:143–149
Kennedy VH, Sánchez AL, Oughton DH, Rowland AP (1997) Use of single and sequential chemical extractants to assess radionucleide and heavy metals availability from soil for root aptake. Analyst 122:89–100
Lee SH, Lee JS, Choi YJ, Kim JG (2009) In situ stabilization of cadmium, lead, and zinc contaminated soil using various amendments. Chemosphere 77:1069–1075
Leleyter L, Baraud F (2005) Évaluation de la mobilité des métaux dans les sédiments fluviaux du bassin de la Vire (Normandie, France) par extractions simples ou séquentielles. Compt Rendus Geosci 337:571–579
Leleyter L, Rousseau C, Biree L, Baraud F (2012) Comparison of EDTA, HCl and sequential extraction procedures, for selected metals (Cu, Mn, Pb, Zn), in soils, riverine and marine sediments. J Geochem Explor 116:51–59
Li XD, Thornton I (2001) Chemical partitioning of trace and major elements in soils contaminated by mining and smelting activities. Appl Geochem 16:1693–1706
Lin Z, Qvarfort U (1996) Predicting the mobility of Zn, Fe, Cu, Pb, Cd from roasted sulfide (pyrite) residues—a case study of wastes from the sulfuric acid industry in Sweden. Waste Manag 16(8):671–681
Maiz I, Esnaola MV, Millan E (1997) Evaluation of heavy metal availability in contaminated soils by a short sequential extraction procedure. Sci Total Environ 206:107–115
Maiz I, Arambarri I, Garcia R, Millan E (2000) Evaluation of heavy metal availability in polluted soils by two sequential extraction procedures using factor analysis. Environ Pollut 110:3–9
Marković J, Jović M, Smičiklas I, Pezo L, Šljivić-Ivanović M, Onjia A, Popović A (2016) Chemical speciation of metals in unpolluted soils of different types: correlation with soil characteristics and an ANN modelling approach. J Geochem Explor 165:71–80
Martínez-Fernández M, Barciela-Alonso MC, Moreda-Piñeiro A, Bermejo-Barrera P (2011) Matrix solid phase dispersion-assisted BCR sequential extraction method for metal partitioning in surface estuarine sediments. Talanta 83:840–849
Mokma DL, Yli-Halla M, Hartikainen H (2000) Soils in a young landscape on the coast of southern Finland. Agric Food Sci Finland 9:291–302
Moore G, Righter K, Carmichael ISE (1995) The effect of dissolved water on the oxidation state of iron in natural silicate liquids. Contrib Mineral Petrol 120:170–179
Naidu R, Harter RD (1998) Effectiveness of different organic ligands on sorption and extractability of cadmium by soils. Soil Sci Soc Am J 62:644–650
Negra L (1987) Pétrologie, minéralogie et géochimie des minéralisations et des roches encaissantes des basins associés aux structures tectoniques et magmatiques de l’Oued Bélif et du Jebel Haddada (Nord des Nefza, Tunisie septentrionale). Unpublished PhD thesis Paris Sud University France 223p
Novozamsky I, Lexmond TM, Houba VJG (1993) A single extraction procedure of soil for evaluation of uptake of some heavy metals by plants. Int J Environ Anal Chem 51:47–58
Paul S (2008) Contamination en métaux lourds des eaux de surface et des sédiments du Val de Milluni (Andes Boliviennes) par des déchets miniers. Approches géochimique, minéralogique et hydrochimique, Phd thesis de l’université de Toulouse 381pp
Pourret O, Lange B, Houben D, Colinet G, Shtcha M, Faucon MP (2015) Modeling of cobalt and copper speciation in metalliferous soils from Katanga (Democratic Republic of Congo). J Geochem Explor 149:87–96
Quevauviller P (1998) Operationally defined extraction procedures for soil and sediment analysis. I Standardization. Trends Anal Chem 17:198–289
Quevauviller P, Van Der Sloot HA, Ure A, Muntau H, Gomez A, Rauret G (1996) Conclusions of the workshop: harmonization of leaching/extraction tests for environ risk assessment. Sci Total Environ 178:133–139
Rate AW, Robertson AE, Borg AT (2000) Distribution of heavy metals in near-shore sediments of the swan river estuary, Western Australia. Air Soil Poll 124:155–168
Rauret G (1998) Extraction procedures for the determination of heavy metals in contaminated soil and sediment. Talanta 46:449–455
Rauret G, López-Sánchez JF, Sahuquillo A, Quevauviller P (2000) Application of a Modified BCR Sequential Extraction (Three-step) Procedure for the Determination of Extractable Trace Metal Contents in a Sewage Sludge Amended Soil Reference Material (CRM 483), Complemented by a Three-year Stability Study of Acetic Acid and EDTA Extractable Metal Content. J Environ Monit 2(3):228–33
Sainfeld P (1952) Les gîtes plombo-zincifères de la Tunisie, Djebel Hallouf-Sidi Bou Aouane. Anna Mines Géol 9:72–78
Solignac M (1927) Etude géologique de la Tunisie septentrionale. Dir Géner Tx Publics Tunis, 736 p
Stefanov, STHR, Ouchev A (1972) Gisement plombo-zincifère de Sidi Driss. Rapport géol. Avec estimation de réserves. Unpublished internal report. Office National des Mines de Tunisie, 71p
Tessier A, Campbell PGC, Bisson M (1979) Sequential extraction procedure for the speciation of particulate trace metals. Anal Chem 51:844–851
Torres E, Auleda M (2013) A sequential extraction procedure for sediments affected by acid mine drainage. J Geochem Explor 128:35–41
Ure AM, Davis CM (2001) Chemical Speciation in the Environment Blackie Glasgow, 408p
Ure AM, Quevauviller P, Muntau H, Griepink B (1993) Speciation of heavy metals in soils and sediments. An account of the improvement and harmonization of extraction techniques undertaken under the auspices of the BCR of the Commission of the European Communities. Int J Environ Anal Chem 51(1–4):135–151
Weisener CG, Smart RSC, Gerson AR (2004) A comparison of the kinetics and mechanism of acid leaching of sphalerite containing low and high concentrations of iron. Int J Mineral Process 74(1–4):239–249
Yao Q, Wang X, Jian H, Chen H, Yu Z (2015) Characterization of the particle size fraction associated with heavy metals in suspended sediments of the Yellow River. Int J Environ Res Public Health 12:6725–6744
Zoo Z, Qiu R, Zhang W, Dong H, Zhao Z, Zhang T, Wei X, Cai X (2009) The study of operating variables in soil washing with EDTA. Environ Pollut 157:229–236
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Trifi, M., Dermech, M., Abdelkrim, C. et al. Extraction procedures of toxic and mobile heavy metal fraction from complex mineralogical tailings affected by acid mine drainage. Arab J Geosci 11, 328 (2018). https://doi.org/10.1007/s12517-018-3612-5
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DOI: https://doi.org/10.1007/s12517-018-3612-5