An integrated approach for assessment of groundwater quality in and around uranium mineralized zone, Gogi region, Karnataka, India

  • S. Manoj
  • M. Thirumurugan
  • L. Elango
Original Paper


Assessment of groundwater quality is an important aspect of water security, which is the key to ensure sustainable development. The objective of the study is to bring out an integrated approach for assessment of groundwater quality for drinking and irrigation purposes. Gogi region, Karnataka, India was chosen as the study area due to the effect of the presence of medium-grade uranium deposits. An integrated approach including the concentration of major ions, trace elements and uranium was employed to investigate the quality of groundwater. Totally, 367 groundwater samples were collected periodically from 52 wells distributes over the Gogi region and the parameters such as pH, electrical conductivity, total dissolved solids (TDS), Ca2+, Mg2+, Na+, K+, Cl, SO4 2−, NO3 , Zn, Pb, Cu, and uranium of groundwater were analysed. Spatial distribution maps of various chemical constituents were prepared using geographic information system and its temporal variation was plotted in box and whisker plot. The analytical data were compared with Bureau of Indian Standards and World Health Organisation standards to determine drinking water quality and parameters such as salinity hazard, alkalinity hazard and percent sodium were estimated to assess the irrigation quality. Multivariate statistical analysis by cluster analysis was also performed which results in two groups consisting of wells with unsuitable water for drinking purposes. Groundwater in about 15% of the sampling wells were found to be unsuitable for domestic purpose based on TDS and about 17% were unsuitable based on uranium concentration. Finally, integration of spatial variation in TDS and uranium reveals that about 25% of the wells were unsuitable for domestic purposes. It is suggested that such an integrated approach needs to be formulated considering major ions, trace elements and radioactive elements for proper assessment of water quality. Implementation of managed aquifer recharge structures in the study area is suggested since it would potentially reduce the concentration of ions.


Hydrogeochemistry Trace elements Uranium Cluster analysis Water quality 


Funding information

The authors would like to thank the Board of Research in Nuclear Sciences, Department of Atomic Energy, Government of India (Grant No. 2009/36/71-BRNS/1690) for their financial support.


  1. Abdurabu WA, Saleh MA, Ramli AT, Heryansyah A (2016) Occurrence of natural radioactivity and corresponding health risk in groundwater with an elevated radiation background in Juban District, Yemen. Environ Earth Sci 75(20):1360. CrossRefGoogle Scholar
  2. Amer R, Sultan M, Ripperdan R, Ghulam A, Kusky T (2013) An integrated approach for groundwater potential zoning in shallow fracture zone aquifers. Int J Remote Sens 34(19):6539–6561. CrossRefGoogle Scholar
  3. Annapoorna H, Janardhana MR (2015) Assessment of groundwater quality for drinking purpose in rural areas surrounding a defunct copper mine. Aquat Procedia 4:685–692. CrossRefGoogle Scholar
  4. Ayotte JD, Gronberg JM, Apodaca LE (2011) Trace elements and radon in groundwater across the United States, 1992–2003. US Department of the Interior, US Geological SurveyGoogle Scholar
  5. BIS (Bureau of Indian Standards) (2012) Indian standard drinking water specification, second revision ISO: 10500:2012, Bureau of Indian Standards. DrinkingWater Sectional Committee, FAD25, New DelhiGoogle Scholar
  6. Brindha K, Elango L (2011) Hydrochemical characteristics of groundwater for domestic and irrigation purposes in Madhuranthakam, Tamil Nadu, India. Earth Sci Res J 15(2):101–108Google Scholar
  7. Brindha K, Elango L (2013a) Occurrence of uranium in groundwater of a shallow granitic aquifer and its suitability for domestic use in southern India. J Radioanal Nucl Chem 295(1):357–367. CrossRefGoogle Scholar
  8. Brindha K, Elango L (2013b) Causes for variation in bromide concentration in groundwater of a granitic aquifer. Int J Res Chem Environ 3:163–171Google Scholar
  9. Brindha K, Elango L, Nair RN (2011) Spatial and temporal variation of uranium in a shallow weathered rock aquifer in southern India. J Earth Syst Sci 120(5):911–920. CrossRefGoogle Scholar
  10. Buragohain M, Bhuyan B, Sarma HP (2010) Seasonal variations of lead, arsenic, cadmium and aluminium contamination of groundwater in Dhemaji district, Assam, India. Environ Monit Assess 170(1–4):345–351. CrossRefGoogle Scholar
  11. Carroll D (1962) Rainwater as a chemical agent of geologic processes: a review. US Government Printing OfficeGoogle Scholar
  12. Chaki A, Purohit RK, Mamallan R (2011) Low grade uranium deposits of India—a bane or boon. Energy Procedia 7:153–157. CrossRefGoogle Scholar
  13. Chen L, Feng Q (2013 Oct 1) Geostatistical analysis of temporal and spatial variations in groundwater levels and quality in the Minqin oasis, Northwest China. Environ Earth Sci 70(3):1367–1378. CrossRefGoogle Scholar
  14. Central Groundwater Board (2012) Groundwater information booklet—Yadgir district, Karnataka. CGWB South Western region BangaloreGoogle Scholar
  15. Central Groundwater Board (2013) Groundwater information booklet—Yadgir district, Karnataka. CGWB South Western region BangaloreGoogle Scholar
  16. Connor R (2015) The United Nations World Water Development Report 2015: water for a sustainable world. UNESCO PublishingGoogle Scholar
  17. Dar IA, Dar MA, Sankar K (2010) Nitrate contamination in groundwater of Sopore town and its environs, Kashmir, India. Arab J Geosci 3(3):267–272. CrossRefGoogle Scholar
  18. Davis SN, DeWiest RJ (1966) Hydrogeology. Wiley, New YorkGoogle Scholar
  19. Fashae OA, Tijani MN, Talabi AO, Adedeji OI (2014) Delineation of groundwater potential zones in the crystalline basement terrain of SW-Nigeria: an integrated GIS and remote sensing approach. Appl Water Sci 4(1):19–38. CrossRefGoogle Scholar
  20. Foote RB (1876) Geological features of the South Mahratta country and adjoining districts. Mem Geol Surv India 12(2):70–138Google Scholar
  21. Garg VK, Yadav A, Singh K, Singh M, Bishnoi M, Pulhani V (2014) Uranium concentration in groundwater in Hisar city, India. Int J Occup Environ Med 5(2 April):374–112Google Scholar
  22. Gilkeson RH, Cowart JB (1987) Radium, radon and uranium isotopes in groundwater from Cambrian-Ordovician sandstone aquifers in Illinois. In radon, radium, and other radioactivity in ground water: hydrogeologic impact and application to indoor airborne contaminationGoogle Scholar
  23. Idiz EF, Carlisle D, Kaplan IR (1986) Interaction between organic matter and trace metals in a uranium rich bog, Kern County, California, USA. Appl Geochem 1(5):573–590. CrossRefGoogle Scholar
  24. Jagadeshan G, Kalpana L, Elango L (2015) Major ion signatures for identification of geochemical reactions responsible for release of fluoride from geogenic sources to groundwater and associated risk in Vaniyar River basin, Dharmapuri district, Tamil Nadu, India. Environ Earth Sci 74(3):2439–2450. CrossRefGoogle Scholar
  25. Kanagaraj G, Elango L (2016 Dec 1) Hydrogeochemical processes and impact of tanning industries on groundwater quality in Ambur, Vellore district, Tamil Nadu, India. Environ Sci Pollut Res 23(23):24364–24383. CrossRefGoogle Scholar
  26. Komarnicki GJ (2005) Lead and cadmium in indoor air and the urban environment. Environ Pollut 136(1):47–61. CrossRefGoogle Scholar
  27. Leung CM, Jiao JJ (2006 Feb 28) Heavy metal and trace element distributions in groundwater in natural slopes and highly urbanized spaces in Mid-Levels area, Hong Kong. Water Res 40(4):753–767. CrossRefGoogle Scholar
  28. Li P, Wu J, Qian H (2013) Assessment of groundwater quality for irrigation purposes and identification of hydrogeochemical evolution mechanisms in Pengyang County, China. Environ Earth Sci 69(7):2211–2225. CrossRefGoogle Scholar
  29. Mahlknecht J, Merchán D, Rosner M, Meixner A, Ledesma-Ruiz R (2017) Assessing seawater intrusion in an arid coastal aquifer under high anthropogenic influence using major constituents, Sr and B isotopes in groundwater. Sci Total Environ 587:282–295CrossRefGoogle Scholar
  30. Mandal A, Sengupta D (2005) Radionuclide and trace element contamination around Kolaghat Thermal Power Station, West Bengal—environmental implications. Curr Sci 88(4):617–624Google Scholar
  31. Marchuk A (2013) Effect of cations on structural stability of salt-affected soils. (Doctoral dissertation)Google Scholar
  32. Matzeu A, Secci R, Uras G (2017) Methodological approach to assessment of groundwater contamination risk in an agricultural area. Agric Water Manag 184:46–58. CrossRefGoogle Scholar
  33. Meinrath A, Schneider P, Meinrath G (2003) Uranium ores and depleted uranium in the environment, with a reference to uranium in the biosphere from the Erzgebirge/Sachsen, Germany. J Environ Radioact 64(2):175–193. CrossRefGoogle Scholar
  34. Mondal NC, Singh VP, Singh VS, Saxena VK (2010a) Determining the interaction between groundwater and saline water through groundwater major ions chemistry. J Hydrol 388(1):100–111. CrossRefGoogle Scholar
  35. Mondal NC, Singh VS, Puranik SC, Singh VP (2010b) Trace element concentration in groundwater of Pesarlanka Island, Krishna Delta, India. Environ Monit Assess 163(1–4):215–227. CrossRefGoogle Scholar
  36. Nahar MN, Inaoka T, Fujimura M, Watanabe C, Shimizu H, Tasnim S, Sultana N (2014) Arsenic contamination in groundwater and its effects on adolescent intelligence and social competence in Bangladesh with special reference to daily drinking/cooking water intake. Environ Health Prev Med 19(2):151–158. CrossRefGoogle Scholar
  37. Nriagu J, Nam DH, Ayanwola TA, Dinh H, Erdenechimeg E, Ochir C, Bolormaa TA (2012) High levels of uranium in groundwater of Ulaanbaatar, Mongolia. Sci Total Environ 414:722–726. CrossRefGoogle Scholar
  38. Oyem HH, Oyem IM, Usese AI (2015) Iron, manganese, cadmium, chromium, zinc and arsenic groundwater contents of Agbor and Owa communities of Nigeria. SpringerPlus 4(1):1CrossRefGoogle Scholar
  39. Raghunath HM (1987) Groundwater, vol 563. Wiley Eastern Ltd., DelhiGoogle Scholar
  40. Rahmati O, Melesse AM (2016) Application of Dempster–Shafer theory, spatial analysis and remote sensing for groundwater potentiality and nitrate pollution analysis in the semi-arid region of Khuzestan, Iran. Sci Total Environ 568:1110–1123. CrossRefGoogle Scholar
  41. Rahmati O, Samani AN, Mahmoodi N, Mahdavi M (2015) Assessment of the contribution of N-fertilizers to nitrate pollution of groundwater in western Iran (case study: Ghorveh–Dehgelan aquifer). Water Qual Expo Health 7(2):143–151. CrossRefGoogle Scholar
  42. Rajesh R, Brindha K, Elango L (2015) Groundwater quality and its hydrochemical characteristics in a shallow weathered rock aquifer of southern India. Water Qual Expo Health 7(4):515–524. CrossRefGoogle Scholar
  43. Rajmohan N, Elango L (2004) Identification and evolution of hydrogeochemical processes in the groundwater environment in an area of the Palar and Cheyyar River basins, southern India. Environ Geol 46(1):47–61Google Scholar
  44. Robins NS (2002) Groundwater quality in Scotland: major ion chemistry of the key groundwater bodies. Sci Total Environ 294(1):41–56. CrossRefGoogle Scholar
  45. Sekhon GS (1995) Fertilizer-N use efficiency and nitrate pollution of groundwater in developing countries. J Contam Hydrol 20(3–4):167–184Google Scholar
  46. Senthil Kumar P, Srinivasan R (2002) Fertility of Late Archaean basement granite in the vicinity of U-mineralized Neoproterozoic Bhima basin, peninsular India. Curr Sci 82(5):571–576Google Scholar
  47. Singh HK, Kumar Y, Chandrasekharam D, Gurav T, Singh B (2014) High-heat-producing granites of East Dharwar Craton around Gugi, Karnataka, and their possible influence on the evolution of Rajapur thermal springs, Deccan Volcanic Province. India Geothermal Energy 2(1):1CrossRefGoogle Scholar
  48. Stamatis G, Alexakis D, Gamvroula D, Migiros G (2011) Groundwater quality assessment in Oropos–Kalamos basin, Attica, Greece. Environ Earth Sci 64(4):973–988. CrossRefGoogle Scholar
  49. Vetrimurugan E, Brindha K, Elango L, Ndwandwe OM (2016) Human exposure risk to heavy metals through groundwater used for drinking in an intensively irrigated river delta. Appl Water Sci:1–4Google Scholar
  50. Wagner SE, Burch JB, Bottai M, Puett R, Porter D, Bolick-Aldrich S, Temples T, Wilkerson RC, Vena JE, Hébert JR (2011) Groundwater uranium and cancer incidence in South Carolina. Cancer Causes Control 22(1):41–50. CrossRefGoogle Scholar
  51. WHO (2011) Guidelines for drinking-water quality, 4th edn. World Health Organization, GenevaGoogle Scholar
  52. Wick K, Heumesser C, Schmid E (2012) Groundwater nitrate contamination: factors and indicators. J Environ Manag 111:178–186. CrossRefGoogle Scholar
  53. Wilcox L. Classification and use of irrigation waters. 1955Google Scholar
  54. Williams KH, Bargar JR, Lloyd JR, Lovley DR (2013) Bioremediation of uranium-contaminated groundwater: a systems approach to subsurface biogeochemistry. Curr Opin Biotechnol 24(3):489–497. CrossRefGoogle Scholar
  55. Wu Y, Wang Y, Xie X (2014) Occurrence, behavior and distribution of high levels of uranium in shallow groundwater at Datong basin, northern China. Sci Total Environ 472:809–817. CrossRefGoogle Scholar
  56. Wu M, Wu J, Liu J, Wu J, Zheng C (2015) Effect of groundwater quality on sustainability of groundwater resource: a case study in the North China Plain. J Contam Hydrol 179:132–147. CrossRefGoogle Scholar
  57. Yang Q, Li Z, Ma H, Wang L, Martín JD (2016) Identification of the hydrogeochemical processes and assessment of groundwater quality using classic integrated geochemical methods in the southeastern part of Ordos basin, China. Environ Pollut 218:879–888. CrossRefGoogle Scholar
  58. Yesilnacar MI, Kadiragagil Z (2013 Dec 1) Effects of acid mine drainage on groundwater quality: a case study from an open-pit copper mine in eastern Turkey. Bull Eng Geol Environ 72(3–4):485–493. CrossRefGoogle Scholar
  59. Zahedi S, Azarnivand A, Chitsaz N (2017) Groundwater quality classification derivation using multi-criteria-decision-making techniques. Ecol Indic 78:243–252. CrossRefGoogle Scholar
  60. Zapecza OS, Szabo Z (1986) Natural radioactivity in ground water—a review. US Geol Surv Natl Water Summ:50–57Google Scholar

Copyright information

© Saudi Society for Geosciences 2017

Authors and Affiliations

  1. 1.Department of GeologyAnna UniversityChennaiIndia

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