Abstract
Daraban leucogranite occurs as cactus-like dykes hosted in serpentinized harzburgite in the mantle section of the Mawat ophiolite, Kurdistan region, northeastern Iraq. It has a primary mineral assemblage of quartz + orthoclase + albite + tourmaline + muscovite, with Mg-rich biotite, phlogopite, zircon, ilmenite–titanohematite exsolution, xenotime, and monazite as the most abundant accessory minerals. New laser ablation inductively coupled plasma mass spectrometry U–(Th)–Pb dating of zircon, monazite, and xenotime reveal a single episode of leucogranite magmatism in the Mawat ophiolite at 92.6 ± 1.2 Ma. These data indicate that the intrusion ages of leucogranite rocks postdate the 105 ± 5 Ma formation age of Mawat ophiolite obtained by K–Ar hornblende method. The leucogranite magma originated by anatexis of pelagic sediments during the late Cretaceous subduction in the Neo-Tethys Ocean, leading to the formation of the Mawat ophiolite as part of the main Zagros ophiolite belt in Iraq and Iran. Tourmaline and biotite from leucogranite dykes were examined regarding their microchemistry and formation environment. Electron microprobe studies show that the tourmalines form mainly dravite–schorl solid solutions with a tendency to schorl compositions. Biotites in the leucogranite have bimodal composition represents by phlogopite and Mg-rich biotite. The tourmaline and biotite compositions, as well as field observations, appear to exclude a late-stage magmatic differentiation origin for the leucogranite. A probable source is S-type granitic magma rich in boron that resulted from the anatexis of silica-rich Ca-poor subduction wedge sediments like those of the Qulqula group. This intruded the ophiolites during the subduction stage. Calculated biotite and Fe–Ti oxide equilibria indicate that the parent magma formed along the subduction zone and solidified in the mantle wedge at a pressure 3.8–4.2 kbar, equivalent to 12.5–13.8 km depth.
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References
Abdel-Rahman AM (1994) Nature of biotites from alkaline, calc-alkaline, and peraluminous magmas. J Petrol. 35:525–541
Abbot RN, Clarke BD (1979) Hypothetical liquidus relationships in the subsystem Al2O3–FeO–MgO projected from quartz, alkali feldspar and plagioclase for (H2O) < 1. Can Mineral. 17:549–560
Abdulla KL (2015) Petrogenesis and geochronology of plagiogranite rocks in Penjween ophiolite, Kurdistan region, NE Iraq. Unpublished M.Sc Thesis, University of Sulaimani, p 92
Aleinikoff JN, Schenck WS, Plank MO, Srogi LA, Fanning CM, Sandra L, Kamo SL, Bosbyshell H (2006) Deciphering igneous and metamorphic events in high-grade rocks of the Wilmington Complex, Delaware: Morphology, cathodoluminescence and backscattered electron zoning, and SHRIMP U-Pb geochronology of zircon and monazite. Bull. Geol. Soc. Am. 118:39–64
Aldiss DT (1978) Granitic rocks of ophiolites. Ph.D Thesis, Open University, UK
Ali SA, Buckman S, Aswad KJ, Jones BG, Ismail SA, Nutman AP (2013) The tectonic evolution of a Neo-Tethyan (Eocene–Oligocene) island-arc (Walash and Naopurdan groups) in the Kurdistan region of the Northeast Iraqi Zagros Suture Zone. Isl Arc. 22:104–125
Al-Mehidi HM (1975) Tertiary nappe in Mawat range. J. Geol. Soc. Iraq. VIII:31–44
Al-Saffi IK, Hadi A, Aqrawi AM (2012) Petrology of gabbroic rocks of Mawat ophiolite complex (central sector) NE Iraq. Iraqi bulletin of geology and mining. 8:65–85
Aswad KJ, Elias EM (1988) Petrogenesis, geochemistry and metamorphism of spilitized subvolcanic rocks, Mawat ophiolite complex, NE Iraq. Ofioliti. 13:95–109
Aydin F, Karsli O, Sadiklar M (2003) Mineralogy and chemistry of biotites from eastern pontide granitoid rocks, NETurkey: Some Petrological Implications for Granitoid Magmas. Chemie der Erde. 63:163–182
Aziz NR, Elias EM, Aswad KJ (2011) Rb-Sr and Sm-Nd isotopes study of serpentinites and their impact on the tectonic setting of Zagros suture zone, NE Iraq. Iraqi Bulletin of Geology and Mining. 7:67–75
Azizi H, Hadi A, Asahara Y, Mohammed YO (2013) Geochemistry and geodynamics of the Mawat mafic complex in the Zagros Suture zone, northeast Iraq. Cen Eur J Geosci. 5:523–537
Baziany MM (2014) Depositional systems and sedimentary basin analysis of the Qulqula Radiolarian Formation of the Zagros Suture Zone, Sulaimani Area, Iraqi Kurdistan Region. Unpublished Ph.D Thesis, University of Sulaimani, Iraq, p 198
Benard F, Moutou P, Pichavant M (1985) Phase relations of tourmaline leucogranites and the significance of tourmaline in silicic magma. J Geol. 93:271–291
Berberian M (1995) Master “blind” thrust faults hidden under the Zagros folds: active basement tectonics and surface morphotectonics. Tectonophysics. 241:193–224
Berberian M, King GCP (1981) Toward a paleogeography and tectonic evolution of Iran. Can J Earth Sci. 18:210–265
Black LP, Kamo SL, et al. (2004) Improved 206Pb/238U microprobe geochronology by the monitoring of a trace-element-related matrix effect; SHRIMP, ID-TIMS, ELA-ICP-MS and oxygen isotope documentation for a series of zircon standards. Chem Geol. 205:115–140
Buddington AF, Lindsley DH (1964) Iron-titanium oxide minerals and synthetic equivalents. J Petrol. 5:310–357
Buick IS, Lana C, Gregory C (2011) A LA-ICP-MS and SHRIMP U/Pb age constraint on the timing of REE mineralisation associated with Bushveld granites. S Afr J Geol. 114:1–14
Burkhard DJM (1991) Temperature and redox path of biotite-bearing intrusives: a method of estimation applied to S- and I-type granites from Australia. Earth Planet Sci Lett. 104:89–98
Burkhard DJM (1993) Biotite crystallization temperatures and redox states in granitic rocks as indicator for tectonic setting. Geol Mijnbouw. 71:337–349
Cherniak DJ, Watson EB (2000) Pb diffusion in zircon. Chem Geol. 172:5–24
Cheilletz A, Féraud G, Giuliani G, Ruffet G (1993) Emerald dating through 40Ar/39Ar step–heating and laser spot analysis of syngenetic phlogopite. Earth Planet Sci Lett. 120:473–485
Coleman RG, Peterman ZE (1975) Oceanic plagiogranite. J Geophy Res 80:1099–1108
Condamine P, Médard E (2014) Experimental melting of phlogopite-bearing mantle at 1 GPa: Implications for potassic magmatism. Earth Planet Sci Lett. 397:80–92
Cornell DH, Brander L, Zack T, Kristoffersen M (2013) The Plat Sjambok Anorthosite and its tonalitic country rocks: Mesoproterozoic pretectonic intrusions in the Kaaien Terrane, Namaqua–Natal Province, Southern Africa. Int Geol Rev. 55:1471–1489
Cox J, Searle M, Pedersen R (1999) The petrogenesis of leucogranitic dykes intruding the northern Semail ophiolite, United Arab Emirates: field relationships, grochemistry and Sr/Nd isotope systematics. Contrib Mineral Petrol. 137:67–287
Dodson MH, Mcclelland-Brown E (1985) Isotopic and paleomagnetic evidence for rates of cooling, uplift and erosion. Geological Society Memorier. 10:315–325
Dyar MD, Taylor ME, Lutz TM, Francis CA, Guidotti CV, Wise M (1998) Inclusive chemical characterization of tourmaline: Mössbauer study of Fe valence and site occupancy. Am Mineral. 83:848–864
Dymek RF (1983) Titanium, aluminum and interlayer cation substitutions in biotite from high-grade gneisses, West Greenland. Am Mineral. 68:880–899
Etsuo U, Sho E, Mitsutosh M (2007) Relationship between solidification depth of granitic rocks and formation of hydrothermal ore deposits. Resource Geology. 57:47–56
Forster MD (1960) Interpretation of the composition of tri octahedral mica. US Geol Surv Prof Pap. 354:1–48
Fuchs Y, Lagache M, Linares J (1998) Fe-tourmaline synthesis under different T and fO2 conditions. Am Mineral. 83:525–534
Fyfe W, McBirney A (1975) Subduction and the structure of andesite volcanic belts. Am J Sci. 275-A:285–297
Gasquet D, Bertrand JM, Paquette JL, Lehmann J, Ratzov G, De Ascenção Guedes R, Tiepolo M, Boullier AM, Scaillet S, Nomade S (2010) Miocene to Messinian deformation and hydrothermal activity in a pre-Alpine basement massif of the French western Alps: new U-Th-Pb and argon ages from the Lauzière massif. Bull Soc Géol France. 181:227–241
Haase KM, Freund S, Koepke J, Hauff F, Erdmann M (2015) Melts of sediments in the mantle wedge of the Oman ophiolite. Geol. 43:275–278
Hacker B, Mosenfelder JL, Gnos E (1996) Rapid emplacement of the Oman ophiolite: thermal and geochronologic constraints. Tectonics. 15:1230–1247
Hawthorne FC, Dirlam DM (2011) Tourmaline the indicator mineral: from atomic arrangement to Viking navigation. Elements. 7:307–312
Hawthorne FC, Henry DJ (1999) Classification of the minerals of the tourmaline group. Eur J Mineral. 11:201–215
Heaman L, Parrish R (1991) U-Pb geochronology of accessory minerals. In: Heaman L, Ludden JN (eds) Short course handbook on applications of radiogenic isotope systems to problems in geology, Mineralogical Association of Canada, pp. 59–102
Hermann J, Spandler C (2008) Sediment melts at sub-arc depths: an experimental study. J Petrol. 49:717–740
Henry DJ, Dutrow BL (1996) Metamorphic tourmaline and its petrologic applications. In: Grew ES, Anovitz LM (eds) Boron: Mineralogy, Petrology and Geochemistry, Rev Mineral, vol 33, pp. 503–557
Henry DJ, Guidotti CV (1985) Tourmaline as a petrogenetic indicator mineral: An example from the staurolite-grade metapelites of NW Maine. Am Mineral. 70:1–15
Ishihara S (1977) The magnetite-series and ilmenite-series granitic rocks. Mining Geol. 27:293–305
Ismail SA, Mirza T, Carr P (2010) Platinum-group elements geochemistry in podiform chromitites and associated peridotites of the Mawat ophiolite, northeastern Iraq. J Asian Earth Sci. 37:31–41
Jackson S, Pearson NJ, Griffin WL, Belousova EA (2004) The application of laser ablation-inductively coupled plasma-mass spectrometry to in situ U–Pb zircon geochronology. Chem Geol. 211:47–69
Jolliff BL, Papike JJ, Shearer CK (1986) Tourmaline as a recorder of pegmatite evolution: Bob Ingersoll pegmatite, Black Hills, South Dakota. Am Mineral. 71:472–500
Johnson MC, Plank T (1999) Dehydration and melting experiments constrain the fate of subducted sediments. Geochem Geophys. doi:10.1029/1999GC000014
Kareem HJ (2015) Mineralogy and geochemistry of felsic pegmatite from Mawat ophiolite, Kurdistan region, northeastern Iraq. Unpublished M.Sc Thesis, University of Sulaimani, p 151
Karim KH, Koyi H, Baziany MM, Hessami K (2011) Significance of angular unconformities between Cretaceous and Tertiary strata in the northwestern segment of the Zagros fold– thrust belt, Kurdistan Region, NE Iraq. Geol Mag. 148:925–939
Karaoğlan F, Parlak O, Klotzi U, Thoni M, Koller F (2012) U–Pb and Sm–Nd geochronology of the ophiolites from the SE Turkey. Implications for the Neotethyan evolution. Geodinamica Acta. 25:146–161
Koepke J, Feig ST, Snow J, Freise M (2004) Petrogenesis of oceanic plagiogranites by partial melting of gabbros: an experimental study. Contrib Mineral Petrol. 146:414–432
Koepke J, Berndt J, Feig ST, Holtz F (2007) The formation of SiO2-rich melts within the deep oceanic crust by hydrous partial melting of gabbro. Contrib Mineral Petrol. 153:67–84
Koh JS, Yun SH (1999) The compositions of biotite and muscovite in the Yuksipryeong two-mica granite and its petrological meaning. Geosciences Journal. 3:77–86
Lalonde AE, Bernard P (1993) Composition and color of biotite from granites: two useful properties in the characterization of plutonic suites from the Hepburn Internal Zone of Wopmay Orogen, Northwest Territories. Can Mineral. 31:203–217
Lattard D, Engelmann R, Kontny A, Sauerzapf U (2006) Curie temperatures of synthetic titanomagnetites in the Fe–Ti–O system: effects of compositions, crystal chemistry, and thermomagnetic methods. J Geophys Res 111:B12S28. doi:10.1029/2006JB004591
Lepage LD (2003) ILMAT: an Excel worksheet for ilmenite–magnetite geothermometry and geobarometry. Comput Geosci. 29:673–678
London D (1999) Stability of tourmaline in peraluminous granite systems: the boron cycle from anatexis to hydrothermal aureoles. Eur J Mineral. 11:253–262
London D (2008) Pegmatites. Can Mineral Special Publication 10, p 368
Ludwig KR (2003) Isoplot/EX version 3.0, A geochronological toolkit for Microsoft Excel: Berkeley Geochronology Center Special Publication
Martin RF, De Vito C (2005) The patterns of enrichment in felsic pegmatites ultimately depend on tectonic setting. Can Mineral. 43:2027–2048
Mohammad YO, Cornell DH, Qaradaghi JH, Mohammad FO (2014) Geochemistry and Ar–Ar muscovite ages of the Daraban Leucogranite, Mawat Ophiolite, Northeastern Iraq: implications for Arabia–Eurasia continental collision. J Asian Earth Sci. 86:151–165
Morgan GB, London D (1999) Crystallization of the little three layered pegmatite-aplite dike, Ramona District, California. Contrib Mineral Petr. 136:310–330
Mukasa S, Ludden J (1987) Uranium-lead isotopic ages of plagiogranites from the Troodos ophiolite, Cyprus, and their tectonic significance. Geol. 15:825–828
Nachit H, Ibhi A, Abia EH, Ohoud MB (2005) Discrimination between primary magmatic biotites, re-equilibrated biotites and neoformed biotites. C R Geosci. 337:1415–1420
Payne JL, Hand M, Barovich KM, Wade BP (2008) Temporal constraints on the timing of high-grade metamorphism in the northern Gawler Craton: implications for assembly of the Australian Proterozoic. Aust J Earth Sci. 55:623–640
Rollinson H (2009) New models for the genesis of plagiogranites in the Oman Ophiolite. Lithos. 112:603–614
Sauerzapf U, Lattard D, Burchard M, Engelmann R (2008) The titanomagnetite–ilmenite equilibrium: new experimental data and thermo-oxybarometric application to the crystallization of basic to intermediate rocks. J Petrol. 49:1161–1185
Scaillet B, Pichavant M, Roux J (1995) Experimental crystallization of leucogranite magmas. J Petrol. 36:663–705
Shabani AA, Lalonde AE, Whalen JB (2003) Composition of biotite from granitic rocks of the Canadian Appalachian: a potential tectonomagmatic indicator? Can Mineral. 41:1381–1396
Shafaii Moghadam H, Stern RJ (2015) Ophiolites of Iran: keys to understanding the tectonic evolution of SW Asia: (II) Mesozoic ophiolites. J Asian Earth Sci. 100:31–59
Slama J, Kosler J, et al. (2008) Plesovice zircon—a new natural reference material for U-Pb and Hf isotopic microanalysis. Chem Geol. 249:1–35
Speer JA (1984) Mica in igneous rocks. In: Bailey SW (ed) Micas. Rev Mineral Soc Am, vol 13, pp. 299–356
Stern RA, Amelin Y (2003) Assessment of errors in SIMS zircon U-Pb geochronology using a natural zircon standard and NIST SRM 610 glass. Chem Geol. 197:111–146
Stern RJ (2002) Subduction zones. Rev. Geophys. 40. doi:10.1029/2001RG000108
Tareen JAK, Keshava Prasad AV, Basavalingu B, Ganesha AV (1995) The effect of fluorine and titanium on the vapour-absent melting of phlogopite and quartz. Mineral Mag. 59:566–570
Tauxe L (2010) Essentials of Paleomagnetism. University of California Press, USA
Tilton GR, Hopson CA, Wright JE (1981) Uranium–lead isotopic ages of the Samail ophiolite, Oman, with applications to Tethyan Ocean. J Geophy Res. 86:2763–2775
Torres-Ruiz J, Pesquera A, Gil-Crespo PP, Velilla N (2003) Origin and petrogenetic implications of tourmaline-rich rocks in the Sierra Nevada (Betic Cordillera, Southeastern Spain). Chem Geol. 197:55–86
Villaseca C, Barbero L (1994) Chemical variability of Al-Ti-Fe-Mg minerals in peraluminous granitoid rocks from central Spain. Eur J Mineral. 6:691–710
Whalen JB, Chappell BW (1988) Opaque mineralogy and mafic mineral chemistry of 1- and S-type granites of the Lachlan Fold belt, southeast Australia. Am Mineral. 73:281–296
Wiedenbeck M, Allé P, Corfu F, Griffin WL, Meier M, Oberli F, von Quadt A, Roddick JC, Spiegel W (1995) Three natural zircon standards for U-Th-Pb, Lu-Hf, trace element and REE analyses. Geostandards Newsletter. 19:1–23
Williams IS, Buick IS, Cartwright I (1996) An extended episode of early Mesoproterozoic metamorphic fluid flow in the Reynolds Range, central Australia. J Metamorph Geol. 14:29–48
Wolf M, London D (1997) Boron in granitic magmas: stability of tourmaline in equilibrium with biotite and cordierite. Contrib Mineral Petrol. 130:12–30
Wones DR, Eugster HP (1965) Stability of biotite: experiment, theory and application. Am Mineral. 50:1228–1272
Wyllie PJ, Sekine T (1982) The formation of mantle phlogopite in subduction zone hybridization. Contrib Mineral Petrol. 79:375–380
Yavuz F (2003) Evaluating micas in petrologic and metallogenic aspect: part II—applications using the computer program Mica+. Comput Geosci. 29:1215–1228
Yavuz F, Karakaya N, Yildirim DK, Karakaya MC (2014) A Windows program for calculation and classification of touramline-supergroup (IMA-2011). Comput Geosci. 63:70–87
Yoder JR, Kushiro I (1969) Melting of a hydrous phase; phlogopite. Am J Sci. 257-A:558–582
Zirkler A, Johnson TE, White RW, Zack T (2012) Polymetamorphism in the mainland Lewisian complex, NW Scotland — phase equilibria and geochronological constraints from the Cnoc an t'Sidhean suite. J Metamorph Geol. 30:865–885
Acknowledgements
YO Mohammad is grateful to the Ministry of Higher Education and Scientific Research of Kurdistan Regional Government for providing a scholarship award which helped in producing this work. Thanks to the Department of Earth Sciences, University of Gothenburg, Sweden, for inviting and hosting the first author to prepare his post-doctorate research. DH Cornell is highly appreciated for isotope analysis and comments on the early draft. The reviews of two anonymous reviewers enhanced the quality of the paper.
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a and b Concordia age results for several zircon and monazite standards analysed in the same run as our analyses. (DOCX 19 kb)
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Mohammad, Y.O., Qaradaghi, J.H. Geochronological and mineral chemical constraints on the age and formation conditions of the leucogranite in the Mawat ophiolite, Northeastern of Iraq: insight to sync-subduction zone granite. Arab J Geosci 9, 608 (2016). https://doi.org/10.1007/s12517-016-2630-4
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DOI: https://doi.org/10.1007/s12517-016-2630-4