Skip to main content

Advertisement

Log in

Crude oil characterization, molecular affinity, and migration pathways of Halfaya oil field in Mesan Governorate, South Iraq

  • Original Paper
  • Published:
Arabian Journal of Geosciences Aims and scope Submit manuscript

Abstract

Nine oil samples of four production wells from Halfaya oil field are selected in this study from the reservoirs of Khasib, Mishrif, and Nahr Umr Formations. They are analyzed chemically for their crude oil characterization as well as isotopes and biomarkers to assess their source rock affinities. Oil biomarkers and isotope values of the analyzed samples from the Nahr Umr, Mishrif, and Khasib Formation reservoirs of Albian, Upper Cenomanian, and Lower Coniacian ages, respectively, from four selected production wells are plotted on sterane triangle, hopane diagram, tricyclic terpane diagram, pristane to phytane ratio with canonian variables, δ13C saturated and aromatic, and pristane/phytane diagrams. They have indicated source environment and lithology of marine algal type II that are nonbiodegraded and deposited in anoxic environments of carbonate and shale. Source maturation at the time of the oil generation are assessed by plots of oil analyzed values on the pristine/phytane diagram. Mature oil are also shown with T max equivalent of 435–440 C based on plots of methyldibenzothiophene ratio (MDR) and vitrinite reflectance of R o = 0.70–0.85 based on methylphenothrene ratio (MPI). Source age assessment are taken from δ13C (%) and the calculated C28/C29 sterane ratio which indicate Middle Jurassic age. Two structural contour maps and two seismic sections are used in this study for assessing source reservoir relations, oil migration paths from the Middle Jurassic Sargelu Formation and accumulation sites in mainly Cretaceous reservoirs. Accordingly, suggestion for risk assessments of drilling sites for hydrocarbon production could be given on the seismic section.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  • Al- A, Thamer K, Zumberge J, Markarian ZM (2011) Hydrocarbons in the Middle Miocene Jeribe Formation, Dyala Region, NE Iraq. J Petrol Geol, London 34(2):1–18

    Google Scholar 

  • Al-Ameri, Thamer K 2014: Oil Biomarkers, Isotopes and Palynofacies are used for Petroleum System types and migration pathways assessments of Iraqi Oil Fields. Arabian J. Geoscience, On line first DOI 10.1007/s12517-014-1606-5.

  • Al-Marsumi, Shahad W. 2014: Petroleum system and hydrocarbon potential of Halfaya oil field, Mesan Governorate, South Iraq. Unpublished MSc. Thesis, University of Baghdad, 130 pages.

  • Al-Sharhan, A. S. and Narin, A. E. M. (1997) Sedimentary basins and petroleum geology of the Middle East, Elsevier, the Netherlands, 843 pages.

  • Andrusevitch VE, Engel MH, Zumberge JE, Brothers LA (1998) Secular episodic changes in stable carbon isotope composition of crude oils. Chem Geol 152:59–72

    Article  Google Scholar 

  • Andrusevitch VE, Engel MH, Zumberge JE (2000) Effect of paleolatitude on the stable carbon isotope composition of crude oils. Geology 28:847–850

    Article  Google Scholar 

  • Aqrawi, A. A. M., Goff, Horbury, A. D. and Sadooni, F.N., (2010). The petroleum geology of Iraq, Scientific press, Beacons field UK, 242 pages.

  • Aquino Neto, F.R., Trendel, J.M.. Restle, A., Conan, J., Albrecht, P.A. 1983: Occurrence and formation of tricyclic and tetracyclic terpanes in sediments and petroleum. In: Advances in Organic Geochemistry 1981(M.Bjoroy, C.Albrecht, C.Cornford, et al., eds), Wiley, New York, pp. 659–676.

  • Boreham CL, Crick IH, Powell TG (1988) Alternative calibration of the Methylphenanthrene Index against vitrinite reflectance: application to maturity measurements on oil and sediments. Org Geochem 12:289–294

    Article  Google Scholar 

  • Clark JP, Philp RP (1989) Geochemical characterization of evaporates and carbonate depositional environments and correlation of associated crude oil in the Black Greek Basin, Alberta. Canadian Geol Bull 37:401–416

    Google Scholar 

  • Connan, J. 1984: Biodegradation of crude oil in reservoirs. In: Advances in Petroleum Geochemistry, vol. 1(J. Brook and D.H. Welte, eds.), Academic Press, London, pp. 299–335.

  • Didyk BM, Simoneit BRT, Brassell SC, Eglinton G (1978) Organic geochemical indicators of palaeoenvironmental condition of sedimentation. Nature 272:216–222

    Article  Google Scholar 

  • Grantham PJ, Wakefield LL (1988) Variations in the sterane carbon number distribution of marine source rock derived crude oils through geological time. Org Geochem 12:293–304

    Article  Google Scholar 

  • Huang WY, Meinshein WG (1979) Steroles as ecological indicators. Geochemica et Cosmochemica, Acta 43:739–745

    Article  Google Scholar 

  • Hunt,J.M. 1996; petroleum geochemistary .2ndedn . Freeman,NewYork,743 P.

  • Isaksen GH (2004) Central North Sea hydrocarbon systems generation, migration, entrapment and thermal degradation of oil and gas. AAPG Bull 8(11):1545–1572

    Article  Google Scholar 

  • Jassim,S.Z., and Goff,J.C. 2005; Geology of Iraq .published by Dolin, Prague and Moravian Museum Brno,341P.

  • Junbong C, Summons RE (2001) Complex pattern of steroidal biomarkers in Tertiary lacustrine sediments of the Biyang Basin, China. Org Geochem 32:115–126

    Article  Google Scholar 

  • Levorsen AI (1967) The geology of petroleum. Freeman, Oxford, 350 p

    Google Scholar 

  • Lewan MD (1984) Factors controlling the proportionality of vanadium to nickel in crude oil. Geochemica et Cosmochemica, Acta 48:123–124

    Article  Google Scholar 

  • Mackenzie AS, Partience RL, Maxwell JR, Vandenbroucke M, Durand B (1980) Molecular parameters for maturation in the Toarchian shale, Paris Basin, France-1, Changes in the configuration of a cyclic isoprenoid alkanes, steranes and triterpanes. Geochemica et Cosmochemica, Acta 44:1709–1921

    Article  Google Scholar 

  • Moldowan,J.M., Sundaraman, P. and Scholl,M. 1986; Sensitivity of biomarker properties to depositional environment and /or source input in the lower Toarcian of S.W. Germany.OrganicGeochemistary,Vol.10,PP.915-26.

  • Moldowan JM, Fago FJ, Carlson RMK et al (1991) Rearranged hopanes in sediments and petroleum. Geochemica et Cosmochemica, Acta 55:3333–3353

    Article  Google Scholar 

  • Peters, K.E., 1986, Guidelines for evaluating petroleum source rocks using programmed pyrolysis, American Association of Petroleum Geologist Bulletin., vol. 70, pp 318–329.

  • Peters, K,E. and Moldowan, J.M. 1991: Effect of source, thermal maturity, and biodegradation on the distribution and isomeration of homohopane in petroleum. Organic Geochemistry,17, pp. 47–61.

  • Peters, K.E., C.C. Walters and J.M.Moldowan 2005a; The biomarker guide, VI: Biomarker and isotopes in the environment and human history Cambridge University Press, Uk,471P

  • Peters,K.,C.C.Walters and J.M. Moldwan 2005b; The Biomarker guide, VII: Biomarkers and isotopes in petroleum system and earth history . Cambridge University Press, UK,674.

  • Radke M (1988) Application of aromatic compounds as maturity indicators in source rocks and crude oils, marine and petroleum geology. Marine and Petroleum geol 5(3):224–236

    Article  Google Scholar 

  • Radke, M. and Welte, D.H. 1983: The methylphenanthrene index (MPI). A maturity parameter based on Aromatic hydrocarbons. In: Advances in Organic Geochemistry 1981(M.Bjoroy, C.Albrecht, C.Cornford, et al., eds), Wiley, New York, pp. 504–512.

  • Repsol, 2006: Organic geochemistry for exploration. A practical guide to the application of analytical techniques in petroleum exploration projects. Santiago Quesada, Upstream Technology Group

  • Robert, P 1988:Organic metamorphism and geothermal history, Microscopic study of organic matter and thermal evolution of sedimentary basins. D. Reidel, Holland, 311 pages.

  • Rohrback, B.G. 1983: Crude oil geochemistry of the Gulf of Suez. Advances in Organic Geochemistry 1981 (M.Bjoroy, C.Albrecht, C.Cornford, et al., eds), Wiley, New York, pp.39-48.

  • Sadooni,F.N. 1993; Stratigraphic sequence microfiches and petroleum prospects of the Yamama formation, Lower Cretaceous, Southern Iraq. AAPG bull.,77,PP.1971-1988.

  • Seifert WK, Moldowan JM (1981) Paleoreconstruction by biological markers. Geochemica et Cosmochemica, Acta 45:783–794

    Article  Google Scholar 

  • Seifert, W.K. and Moldowan, J.M. 1986: Use of biological markers in petroleum exploration. In: Methods in Geochemistry and Geophysics, vol. 24(R.B. Johns, ed), Elsevier, Amsterdam, pp. 261–290.

  • Selley RC (1998) Elements of petroleum geology. Academic, London, UK, p 470

    Google Scholar 

  • Sharland,P.R.,Archer,R.,Casey,D.M. ., Hall, S.H., Heward,A.P., Horbury, A.D. and Simmons,M.D. 2001; Arabian Plate Sequence Stratigraphy .Geo Arabia Special Publication 2. Gulf Petrolink Bahrain,371P.

  • Sofer Z (1984) Stable carbon isotope compositions of crude oil: application to source depositional environments and petroleum alteration. AAPG Bull 68:31–49

    Google Scholar 

  • Ten Haven HL, de Leeuw JW, Rullkutter J, Sinninghe Damste JS (1987) Restricted utility of the pristine/phytane ratio as palaeoenvironmental indicator. Nature 330:641–643

    Article  Google Scholar 

  • Tissot,B.P. and Welte, D.H. 1984; Petroleum formation occurrence Springer, New York, 699P.

  • Volkman, J.K., 1986; A review of sterol markers for marine and terrigenous organic matter .Organic Geochemistry, Vol,. P.83–99.

  • Waples DW, Machihara T (1991) Biomarker in petroleum exploration. International Human Resources Development Corporation, Boston, 232P

    Google Scholar 

  • Wenger LM, Davis CL, Isaksen GL (2002) Multiple control on petroleum biodegradation and impact on oil quality. SPE Reserv Eval Eng 3:375–383

    Article  Google Scholar 

  • Zumberge, J. 1987: Prediction of source rocks characteristics based on terpane biomarkers in crude oils: a multivariate statistical approach. Geochemica et Cosmochemica, Acta, 51 pp. 1625–1637.

Download references

Acknowledgments

The oil analyses were done in Geomark Research Institute while oil samples, seismic sections, and wells final reports are supplied from the Oil Ministry and the Mesan Oil Company. Accordingly, we acknowledge and thank them all.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Thamer K Al-Ameri.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Al-Ameri, T.K., Al-Marsoumi, S.W. & Al-Musawi, F.A. Crude oil characterization, molecular affinity, and migration pathways of Halfaya oil field in Mesan Governorate, South Iraq. Arab J Geosci 8, 7041–7058 (2015). https://doi.org/10.1007/s12517-014-1733-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12517-014-1733-z

Keywords

Navigation