Arabian Journal of Geosciences

, Volume 8, Issue 5, pp 3171–3182 | Cite as

Spatial distribution of cadmium concentrations in street dust in an arid environment

  • Kholoud Mashal
  • Mohammed Salahat
  • Mohammed Al-Qinna
  • Yahya Al-Degs
Original Paper


Cadmium (Cd) concentration and its chemical speciation were studied in surface dust samples collected from 26 locations at Amman–Zarqa basin highways. The study area represents a heavily trafficked arid environment associated with highly calcareous soils with an average of 53 % CaCO3; such combination gives the investigation further speculations on abundant Cd bonded forms. Sequential extraction technique (SET) was used to assess the exchangeable, bound to carbonates, bound to iron oxide, bound to organic matter, and residual fractions in surface dust samples. Total and fractional Cd spatial distributions were spatially investigated and utilized to generate Cd contamination factor map. Total Cd concentrations ranged between 4.1 and 17.9 mg/kg where maximum contamination was allocated at the study area center. The exponential behavior of Cd distribution in space gave further distinction of the possible contamination sources. The main Cd speciation was in the following order: bound to iron oxide > residual > exchangeable > bound to carbonate > bound to organic matter. The degree of surface contamination was determined by individual contamination factor that delineated those areas located close to the wastewater treatment plant that had high potential risk to fauna and flora. Relationship between the total and fractional Cd concentrations with soil chemical properties showed that pH, CEC, and amorphous Fe were positively related to total extracted Cd, while carbonate content and OM are negatively correlated with Cd.


Cd Speciation Spatial analysis Contamination factor map Cd krig map 



This project was supported by the Deanship of Research and Graduate Studies at the Hashemite University. We would like to thank the Center of Environmental Studies at the Hashemite University for their help in analyzing the projects’ samples and Hana Al-Nounah for her assistance in the dust sampling and the analysis.


  1. Allott RW, Hewitt CN, Kelly MR (1990) The environmental half-lives and mean residence times of contaminants in dust for an urban environment: Barrow-in-Furness. Sci Total Environ 93:403–410Google Scholar
  2. Alloway BJ (1995) Heavy metals in soils. Blackie Academic and Professional, GlasgowCrossRefGoogle Scholar
  3. Al-Qinna MI, Salahat MA, Shatnawi Z (2008) Effect of carbonates and gravel contents on hydraulic properties in gravely-calcareous soils. Dirasat, Agricultural sciences, 35:145–158Google Scholar
  4. Badri MA, Aston SR (1983) Observation on heavy metal geochemical associations in polluted and nonpolluted estuarine sediments. Environ Pollut 6B:181–193CrossRefGoogle Scholar
  5. Banat KM, Howari FM, Al-Hamad AA (2004) Heavy metals in urban soils of central Jordan: should we worry about their environmental risks? Environ Res 97:258–273CrossRefGoogle Scholar
  6. Baron J, Legret M, Astruc M (1990) Study of interactions between heavy metals and sewage sludge. Determination of stability constant and complexation capacities of complexes formed with Cu and Cd. Environ Technol 11:151–162CrossRefGoogle Scholar
  7. Bauer C, Kheboian C (1987) Accuracy of selective extraction procedures for metal speciation in model aquatic sediments. Anal Chem 59:1417–1423CrossRefGoogle Scholar
  8. Bocca B, Alimonti A, Petrucci F, Violante N, Sancesario G, Forte G (2004) Quantification of trace elements by sector field inductively coupled plasma spectrometry in urine, serum, blood and cerebrospinal fluid of patients with Parkinson’s disease. Spectrochim Acta 59 B:559–566CrossRefGoogle Scholar
  9. Boluda R, Andreu V, Pons V, Sanchez J (1988) Contenido en metals pesados (Cd, Co, Cr, Cu, Ni, Pb y Zn) en suelos de la comarca LaPlana de Requena - Utiel (Valencia). An Edafol Agrobiol 47:1485–1502Google Scholar
  10. Chen T, Liu X, Zhu M, Zhao K, Wu J, Xu J, Huang P (2008) Identification of trace element sources and associated risk assessment in vegetable soils of the urban–rural transitional area of Hangzhou, China. Environ Pollut 151:67–78CrossRefGoogle Scholar
  11. Chlopecka A, Bacon JR, Wilson MJ, Kay J (1996) Forms of cadmium, lead and zinc in contaminated soils from southwest Poland. J Environ Qual 25:69–79CrossRefGoogle Scholar
  12. Cuong DT, Obbard JP (2006) Metal speciation in coastal marine sediments from Singapore using a modified BCR-sequential extraction procedure. Appl Geochem 21:1335–1346CrossRefGoogle Scholar
  13. de la Villa VR, dela Flor M, Cala V (1997) Influence of carbonate on cadmium distribution in soils under semiarid environment. Agrochimica 41:270–278Google Scholar
  14. Errecalde MF, Boluda R, Lagarda MJ, Farre R (1991) Indices de contaminación por metals pesados en suelos de cultivo intensivo: aplicación en lacomarca de L’Horca (Valencia). Suelo y Planta 1:483–494Google Scholar
  15. ESRI (2006) ArcGIS Desktop Help 9.2. ESRI Inc, USAGoogle Scholar
  16. Gala V, Rodríguez J, Guerra A (1985) Contaminación por metales pesados en suelos de la Vega de Aranjuez. (I) Pb, Cd, Cu, Zn, Ni, Cr. Anal Edaf Agrobiol 14:1595–1608Google Scholar
  17. Goovaerts P (1997) Geostatistics for natural resources evaluation. Oxford University Press, New YorkGoogle Scholar
  18. Harrison RM, Laxen DP, Wilson SJ (1981) Chemical associations of lead, cadmium, copper, and zinc in street dusts and roadside soils. Environ Sci Technol 15:1378–1383CrossRefGoogle Scholar
  19. Hashisho Z, El-Fadel M (2004) Impacts of traffic-induced lead emissions on air, soil and blood lead levels in Beirut. Environ Monit Assess 93:185–202CrossRefGoogle Scholar
  20. Huang SJ, Chang CY, Muia DT, Chang FC, Lee MY, Wang CF (2007) Sequential extraction for evaluating the leaching behavior of selected elements in municipal solid waste incineration fly ash. J Hazard Mater 149:180–188CrossRefGoogle Scholar
  21. JMP (2009) Statistics and graphics guide. SAS Institute Incorporation, USA, NC, CaryGoogle Scholar
  22. Keefer RF, Codling EE, Singh RN (1984) Fractionation of metal organic complexes extracted from a sewage sludge-amended soil. Soil Sci Soc Am J 48:1054–1059CrossRefGoogle Scholar
  23. Khoshgoftar AH, Shariatmadari H, Karimian N, Kalbasi M, van derZee S, Parker DR (2004) Salinity and zinc application effects on phytoavailability of cadmium and zinc. Soil Sci Soc Am J 68:1885–1889Google Scholar
  24. Lair GJ, Graf M, Zehetner F, Gerzabek MH (2008) Distribution of cadmium among geochemical fractions in floodplain soils of progressing development. Environ Pollut 156:207–214CrossRefGoogle Scholar
  25. Lalonde SV, Amskold LA, Warren LA, Konhauser KO (2007) Surface chemical reactivity and metal adsorptive properties of natural cyanobacterial mats from an alkaline hydrothermal spring, Yellowstone National Park. Chem Geol 243:36–52CrossRefGoogle Scholar
  26. Lee K, Yu H, Yun T, Mayer B (2005) Metal contamination and solid phase partitioning of metals in urban roadside sediments. Chemosphere 60:672–689CrossRefGoogle Scholar
  27. Liao M, Huang C, Xie Z (1999) Effect of pH on transport and transformation of cadmium in soil–water system. Huanjing Kexue Xuebao 19:81–86Google Scholar
  28. Li XD, Lee SL, Wong SC, Shi WZ, Thornton I (2004) The study of metal contamination in urban soils of Hong Kong using a GIS-based approach. Environ Pollut 129:113–124Google Scholar
  29. Li Xi, Poon C, Liu PS (2001) Heavy metal contamination of urban soils and street dusts in Hong Kong. Appl Geochem 16:1361–1368Google Scholar
  30. Lin YP (2002) Multivariate geostatistical methods to identify and map spatial variations of soil heavy metals. Environ Geol 42:1–10Google Scholar
  31. Loppert RH, Inskeep WP (2001) Method of soils analysis. Part 3: chemical methods, 3rd edn. American Society of Agronomy, MadisonGoogle Scholar
  32. Manno E, Varrica D, Dongarra G (2006) Metal distribution in road dust samples collected in an urban area close to a petrochemical plant at Gela, Sicily. Atmos Environ 40:5929–5941CrossRefGoogle Scholar
  33. Manta DS, Angelone M, Bellanca A, Neri R, Sproveri M (2002) Heavy metals in urban soils: a case study from the city of Palermo (Sicily), Italy. Sci Total Environ 300:229–243CrossRefGoogle Scholar
  34. Martin HW, Kaplan DI (1998) Temporal changes in cadmium, thallium, and vanadium mobility in soil and phytoavailability under field conditions. Water Air Soil Pollut 101:399–410CrossRefGoogle Scholar
  35. Mashal K, Al-Qinna M, Ali Y (2009) Spatial distribution and environmental implications of lead and zinc in urban soils and street dusts samples in Al-Hashimeyeh Municipality. Jordan J Mech Ind Eng 3(2):141–150Google Scholar
  36. Mielke HW, Gonzales CR, Smith MK, Mielke PW (1999) The urban environment and children’s health: soils as an integrator of lead, zinc, and cadmium in New Orleans, Louisiana, USA. Environ Res Sect A 81:117–129CrossRefGoogle Scholar
  37. Mireles A, Solıś C, Andrade E, Lagunas-Solar M, Pinã C, Flocchini RG (2004) Heavy metal accumulation in plants and soil irrigated with wastewater from Mexico City. Nucl Instrum Methods Phys Res B Beam Interact Mater Atoms 219–220:187–190CrossRefGoogle Scholar
  38. Nemati K, Abu Bakar NK, Abas MR, Sobhanzadeh E (2011) Speciation of heavy metals by modified BCR sequential extraction procedure in different depths of sediments from Sungai Buloh, Selangor, Malaysia. J Hazard Mater 192:402–410Google Scholar
  39. Nriagu JO (1988) A silent epidemic of environmental metal poisoning? Environ Pollut 50:139–161CrossRefGoogle Scholar
  40. Page AL, Miller RSH, Keeney DR (1982) Method of soils analysis. Part 2. Chemical and microbiological properties, 2nd edn. American Society of Agronomy, MadisonGoogle Scholar
  41. Qiao XL, Luo YM, Christie P, Wong MH (2003) Chemical speciation and extractability of Zn, Cu and Cd in two contrasting biosolids-amended clay soils. Chemosphere 50:823–829CrossRefGoogle Scholar
  42. Quenea K, Lamy I, Winterton P, Bermond A, Dumat C (2009) Interactions between metals and soil organic matter in various particle size fractions of soil contaminated with waste water. Geoderma 149:217–223CrossRefGoogle Scholar
  43. Raghunath R, Tripathi RM, Kumar AV, Sathe AP, Khandekar RN, Nambi KSV (1999) Assessment of Pb, Cd, Cu, and Zn exposures of 6- to 10-year-old children in Mumbai. Environ Res 80:215–221CrossRefGoogle Scholar
  44. Raven PH, Berg LR, Johnson GB (1998) Environment, 2nd edn. Saunders College Publishing, New YorkGoogle Scholar
  45. Salminen R (2005) Geochemical Atlas of Europe. Part I, Background Information, Methodology and Maps. Geological Survey of Finland. Electronic version
  46. Satarug S, Baker JR, Urbenjapol S, Haswell-Elkins M, Reilly PEB, Williams DJ, Moore MR (2003) A global perspective on cadmium pollution and toxicity in non-occupationally exposed population. Toxicol Lett 137:65–83CrossRefGoogle Scholar
  47. Schuhmacher M, Meneses M, Granero S, Llobet JM, Domingo JL (1997) Trace element pollution of soils collected near a municipal solid waste incinerator: human health risk. Bull Environ Contam Toxicol 59:861–867CrossRefGoogle Scholar
  48. Scott HD (2000) Soil physics: agricultural and environmental applications. Iowa State University Press, AmesGoogle Scholar
  49. Selker JS, Keller CK, McCord JT (1999) Vadose zone processes. Lewis Publishers/CRC Press LLC, FloridaGoogle Scholar
  50. Shetye S, Shudhakar M, Mohan R, Tyagi A (2009) Implications of organic carbon, trace elemental and CaCO3 variations in a sediment core from the Arabian Sea. Indian J Mar Sci 384(4):432–438Google Scholar
  51. Smolders E, Lambergts RM, McLaughlin MJ, Tiller KG (1998) Effect of soil solution chloride on cadmium availability to Swiss chard. J Environ Qual 27:426–431Google Scholar
  52. Sposito G (1989) The surface chemistry of soils. Oxford University Press, OxfordGoogle Scholar
  53. Sposito G, Lund LJ, Chang AC (1982) Trace metal chemistry in arid zone field soils amended with sewage sludge: I. Fractionation of Ni, Cu, Zn, Cd, and Pb in soil phases. Soil Sci Soc Am J 46:260–264CrossRefGoogle Scholar
  54. Steel RGD, Torrie JH (1980) Principles and procedures of statistics: a biometrical approach. McGraw-Hill Inc, USAGoogle Scholar
  55. Tessier A, Campbell PGC, Bisson M (1979) Sequential extraction procedure for the speciation of particulate trace metals. Anal Chem 51:844–851CrossRefGoogle Scholar
  56. Thompson CM, Markesbery WR, Ehmann WD, Mao YX, Vance DE (1988) Regional brain trace-element studies in Alzheimer’s disease. Neurotoxicity 9:1–7Google Scholar
  57. USEPA (1996) Recent developments for in situ treatment of metals contaminated soils. U.S. Environmental Protection Agency, Office of Solid Waste and Emergency Response, USAGoogle Scholar
  58. Usero J, Gamero M, Morillo J, Gracia I (1998) Comparative study of three sequential extraction procedures for metals in marine sediments. Environ Int 24:487–497CrossRefGoogle Scholar
  59. Waisberg M, Joseph P, Hale B, Beyersmann D (2003) Molecular and cellular mechanisms of cadmium carcinogenesis. Toxicology 192:95–117CrossRefGoogle Scholar
  60. WHO (2006) Guidelines for drinking-water quality. First addendum to third edition, vol. 1. World Health Organization, GenevaGoogle Scholar
  61. Wong DWS, Lee J (2005) Statistical analysis of geographic information with ArcView GIS and ArcGIS. Wiley, USAGoogle Scholar
  62. Xiangdong L, Zhenguo S, Onyx WHW, Yok-sheung L (2000) Chemical partitioning of heavy metal contaminants in sediments of the Pearl River Estuary. Chem Speciat Bioavailab 12:17–25Google Scholar
  63. Yin Y, Impellitteri CA, You SJ, Allen HE (2002) The importance of organic matter distribution and extract soil:solution ratio on the desorption of heavy metals from soils. Sci Total Environ 287:107–119CrossRefGoogle Scholar

Copyright information

© Saudi Society for Geosciences 2014

Authors and Affiliations

  • Kholoud Mashal
    • 1
  • Mohammed Salahat
    • 1
  • Mohammed Al-Qinna
    • 1
  • Yahya Al-Degs
    • 2
  1. 1.Department of Land Management and Environment, Faculty of Natural Resources and EnvironmentHashemite UniversityZarqaJordan
  2. 2.Chemistry DepartmentThe Hashemite UniversityZarqaJordan

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