Arabian Journal of Geosciences

, Volume 6, Issue 9, pp 3257–3267 | Cite as

Hydrochemical characteristics of groundwater in the plains of Phalgu River in Gaya, Bihar, India

  • Rajesh Kumar Ranjan
  • AL. Ramanathan
  • Purushothaman Parthasarathy
  • Alok Kumar
Original Paper

Abstract

Assessment of groundwater quality is essential to ensure sustainable use of it for drinking, agricultural, and industrial purposes. The chemical quality of groundwater of Gaya region has been studied in detail in this work to delineate the potable groundwater zones. A total of 30 groundwater samples and 2 surface water samples were collected in and around Gaya district of Bihar. The major cations follow the trend: Ca2+ > Mg2+ > Na+ > K+. The domination of calcium ions in the groundwater is due to weathering of rocks. The K+ ranged between 0.2 and 47.95 ppm, suggesting its abundance the below desired limit; but some samples were found to be above permissible limit. K+ weathering of potash silicate and the use of potash fertilizer could be the source. The major anions abundance followed the order HCO3 > Cl > SO42− > NO3 > PO43−. Dissolution of carbonates and reaction of silicates with carbonic acid accounts for the addition of HCO3 to the groundwater and oxidation of sulphite may be the source of SO42−. Principal component analysis was utilized to reflect those chemical data with the greatest correlation and seven major principal components (PCs) representing >80 % of cumulative variance were able to interpret the most information contained in the data. PC1, PC2 and PC3 reflect the hydrogeochemical processes like mineral dissolution, weathering and anthropogenic sources. PC4, PC5, PC6 and PC7 show monotonic, random and independent relationships.

Keywords

Hydrogeochemistry Anthropogenic Contamination Alluvial Aquifers 

References

  1. APHA (2005) Standard methods of analysis of water, waste water, 14th edn. American Public Health Association, USA, p 1457Google Scholar
  2. Bergström LF, Johansson R (1991) Leaching of nitrate from monolith lysimeter of different types of agricultural soils. J Environ Qual 20:801–807CrossRefGoogle Scholar
  3. Bhattacharya P, Chatterjee D, Jacks G (1997) Occurrence of arsenic contamination of groundwater in alluvial aquifers from Delta Plain, Eastern India: option for safe drinking supply. Intern J Water Res Dev 13:79–92CrossRefGoogle Scholar
  4. Bhattacharya P, Claesson M, Bundschu J, Srace O, Fagerberg J, Jacks G (2006) Distribution and mobility of arsenic in the Río Dulce alluvial aquifers in Santiago del Estero province, Argentina. Sci Tot Environ 358:97–120CrossRefGoogle Scholar
  5. Boruvka L, Vecek O, Jehlicka J (2005) Principal component analysis as a tool to indicate the origin of potentially toxic elements in soil. Geoderma 128:289–300CrossRefGoogle Scholar
  6. Carlon C, Critto A, Marcomini A, Nathanail P (2001) Risk based characterization of contaminated industrial site using multivariate and geostatistical tools. Environ Pollut 111:417–427CrossRefGoogle Scholar
  7. Cey EE, Rudolph DL, Aravena R, Parkin G (1999) Role of the riparian zone in controlling the distribution and fate of agricultural nitrogen near a small stream in southern Ontario. J Contam Hydrol 37:45–67CrossRefGoogle Scholar
  8. Chadha DK (1999) A proposed new diagram for geochemical classification of natural waters and interpretation of chemical data. J Hydrogeol 7:431–439Google Scholar
  9. Chauhan VS, Yunus M, Sankararamakrishnan N (2011) Geochemistry and mobilization of arsenic in Shuklaganj area of Kanpur–Unnao district, Uttar Pradesh, India. Environ Monit Assess. doi:10.1007/s10661-011-2310-5
  10. Chen YSR, Butler JN, Stumm W (1973) Kinetic study of phosphate reaction with aluminium oxide and kaolinite. Environ Sci Tech 7:327–332CrossRefGoogle Scholar
  11. Costa JL, Massone H, Martínez D, Suero EE, Vidal CM, Bedmarm F (2002) Nitrate contamination of a rural aquifer and accumulation in the unsaturated zone. Agr Water Manag 541:33–47CrossRefGoogle Scholar
  12. Cullen WR, Reimer KJ (1989) Arsenic speciation in environment. Chem Rev 89:713–764CrossRefGoogle Scholar
  13. Eaton FM (1950) Significance of carbonates in irrigation water. Soil Sci 69:123–133Google Scholar
  14. Feast NA, Hiscock KM, Dennis PF (1998) Nitrogen isotope hydrochemistry and denitrification within the chalk aquifer system of north Norfolk. UK J Hydrol 211:233–252Google Scholar
  15. Feng LH (2003) Principal component analysis of environmental quality. Math Pract Theor 33:32–35Google Scholar
  16. Fournier RO, Potter II (1982) An equation correlating the solubility of quartz in water from 25° to 900° at pressure up to 1000 bars. Geochim Cosmochim Acta 46:1969–1973CrossRefGoogle Scholar
  17. Fung T, Le DE (1987) Application of principal components analysis to change detection. Photogramm Eng Remote Sens 53:1649–1658Google Scholar
  18. Handa BK (1986) Trace elements content of groundwater in the basaltic rocks in some parts of Indian Peninsula. In: Power KB, Thigale SS (eds) Hydrogeology of volcanic terranes. University of Poona, Pune, pp 83–104Google Scholar
  19. He B, Meng Q (2002) Some notes on the principal component analysis method. J Yunnan Normal University 22:6–8Google Scholar
  20. Kelly WR (1997) Heterogeneities in ground-water geochemistry in a sand aquifer beneath an irrigated field. J Hydrol 19:154–176CrossRefGoogle Scholar
  21. Kraft GJ, Stites W, Mechenich DJ (1999) Impacts of irrigated vegetable agriculture on a humid north-central US sand plain aquifer. Groundwater 37:572–580CrossRefGoogle Scholar
  22. Kuppusamy MR, Grirdhar VV (2006) Factor analysis of water quality characteristics including trace metal speciation in the coastal environmental system of Chennai Ennore. Environ Int 32:174–179CrossRefGoogle Scholar
  23. Maeda M, Zhao B, Ozaki Y, Yoneyama T (2003) Nitrate leaching in an Andisol treated with different types of fertilizers. Environ Pollut 121:477–487Google Scholar
  24. Manly BFJ (1997) Multivariate statistical methods: a primer, 2nd edn. Chapman and Hall, LondonGoogle Scholar
  25. McArthur JM, Banerjee DM, Hudson-Edwards KA, Mishra R, Purohit R, Ravenscroft P et al (2004) Natural organic matter in sedimentary basins and its relation to arsenic in anoxic groundwater: the example of West Bengal and its worldwide implications. Appl Geochem 19:1255–1293CrossRefGoogle Scholar
  26. Meglin RR (1991) Examining large databases: a chemometric approach using principal component analysis. J Chemomet 5:163–179CrossRefGoogle Scholar
  27. Min JH, Yun ST, Kim K, Kim HS, Kim DJ (2003) Geologic controls on the chemical behavior of nitrate in riverside alluvial aquifers. Korea Hydrol Process 17:1197–1211CrossRefGoogle Scholar
  28. Mrklas O, Bentley LR, Lunn SRD (2006) Principal component analyses of groundwater chemistry data during enhanced bioremediation. Water Air Soil Pollut 169:395–411CrossRefGoogle Scholar
  29. Mudge SM, Duce CE (2005) Identifying the source, transport path and sinks of sewage derived organic matter. Environ Pollut 136:209–220CrossRefGoogle Scholar
  30. Nolan BT (2001) Relating nitrogen sources and aquifer susceptibility of nitrate in shallow ground waters of the United States. Groundwater 39:290–299Google Scholar
  31. Owens LB, Van Keure RW, Edwards WM (1998) Budgets of non-nitrogen nutrients in a high fertility pasture system. Agricul Ecosyst Environ 70:7–18Google Scholar
  32. Panno SV, Hackley KC, Hwang HH, Kelly WR (2001) Determination of the sources of nitrate contamination in karst springs using isotopic and chemical indicators. Chem Geol 179:113–128Google Scholar
  33. Pauwels H, Foucher JC, Kloppman W (2000) Denitrification and mixing in a schist aquifer: influence on water chemistry and isotopes. Chem Geol 168:307–324Google Scholar
  34. Peterson EW, Davis RK, Brahana JV, Orndorff HA (2002) Movement of nitrate through regolith covered karst terrane, northwest Arkansas. J Hydrol 256:35–47CrossRefGoogle Scholar
  35. Piper AM (1944) A graphic procedure in the geochemical interpretation of water analysis. Trans Am Geophys Union 25:914–923Google Scholar
  36. Postma D, Boesen C, Kristiansen H, Larsen F (1991) Nitrate reduction in an unconfined sandy aquifer: water chemistry, reduction processes, and geochemical modeling. Water Resour Res 27:2027–2045CrossRefGoogle Scholar
  37. Reghunath R, Murthy TRS, Raghavan BR (2002) The utility of multivariate statistical techniques in hydrogeochemical studies: an example from Karnataka, India. Water Research 36:2437–2442Google Scholar
  38. Richard LA (1954) Diagnosis and improvement of saline and alkali soils. Agricultural handbook (Vol. 60, pp 160). Washington, DC: USDAGoogle Scholar
  39. Richter BC, Kreitler CW, Bledsoe BE (1993) Geochemical Techniques for Identifying Sources of Groundwater Salinization. CRC Press, New YorkGoogle Scholar
  40. Robertson WD, Russell BM, Cherry JA (1996) Attenuation of nitrate in aquitard sediments of southern Ontario. J Hydrol 180:267–281Google Scholar
  41. Singh KP, Malik A, Mohan D, Sinha S (2004) Multivariate statistical techniques for the evaluation of spatial and temporal variations in water quality of Gomti River (India) – a case study. Water Research 38:3980–3992Google Scholar
  42. Singh KP, Malik A, Singh VK, Mohan D, Sinha S (2005) Chemometric analysis of groundwater quality data of alluvial aquifer of Gangetic plain, North India. Anal Chim Acta 550:82–91CrossRefGoogle Scholar
  43. Singh CK, Shashtri S, Mukherjee S (2010) Integrating multivariate statistical analysis with GIS for geochemical assessment of groundwater quality in Shiwaliks of Punjab, India. Environ Earth Sci. doi:10.1007/s12665-010-0625-0
  44. Smith RL, Howes BL, Duff JH (1991) Denitrification in nitrate-contaminated groundwater: occurrence in steep vertical geochemical gradients. Geochim Cosmochim Acta 55:1815–1825Google Scholar
  45. Starr R, Gillham RW (1993) Denitrification and organic carbon availability in two aquifers. Groundwater 31:934–947Google Scholar
  46. Stigter TY, Van Ooijen SPJ, Post VEA, Appello CAJ, Carvalho Dill AMM (1998) A hydrogeological and hydrochemical explanation of the groundwater composition under irrigated land in a Mediterranean environment, Algarve, Portugal. J Hydrol 208:262–279CrossRefGoogle Scholar
  47. Wilcox LV (1955) Classification and use of irrigation water (pp 19). U.S. Department of Agriculture circular 969, Washington DC, U.S. Department of AgricultureGoogle Scholar
  48. Yawei W, Lina L, Jianbo S, Guibin J (2005) Chemometrics methods for the investigation of methylmercury and total mercury contamination in mollusks samples collected from coastal sites along the Chinese Bohai Sea. Environ Pollut 135:457–467CrossRefGoogle Scholar
  49. Zhang C (2006) Using multivariate analyses and GIS to identify pollutants and their spatial patterns in urban soils in Galway, Ireland. Environ Pollut 142:501–511CrossRefGoogle Scholar

Copyright information

© Saudi Society for Geosciences 2012

Authors and Affiliations

  • Rajesh Kumar Ranjan
    • 1
    • 2
  • AL. Ramanathan
    • 2
  • Purushothaman Parthasarathy
    • 3
  • Alok Kumar
    • 2
  1. 1.School of Earth Biological and Environmental SciencesCentral University of BiharPatnaIndia
  2. 2.School of Environmental SciencesJawaharlal Nehru UniversityNew DelhiIndia
  3. 3.National Institute of HydrologyRoorkeeIndia

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