Abstract
Chinese Ni-Mo sulfide ores. Chondrite-normalized PGE pattern for the coaly slates displays a strong positive Ru anomaly and slightly negative Pt anomaly. The Zn-rich shale of Czech and the black shale of South China show similar patterns to the coaly slates except its slightly enriched Au and positive Pt anomaly, respectively. Positive correlations of organic carbon and the redox-sensitive trace elements such as U, V and Mo with PGEs concentrations in the coaly slates suggest that the PGEs were most likely introduced by submarine hydrothermal activity and precipitated with organic matters under anoxic environment. In general, the metalliferous black slates in the OMB seem to be metamorphosed analogue of the Early Cambrian black shales of the South China Block in the former continental back-arc basin setting, which host metalliferous Ni-Mo-PGE sulfide ores.
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Barnes, S.J., Boyd, R., Korneliussen, A., Nillson, L.P., Often, M., Pedersen, R.B., and Robins, B., 1987, The use of mantle normalization and metal ratios in discriminating between the effects of partial melting, crystal fractionation and sulphide segregation on platinum-group elements, gold, nickel and copper: examples from Norway. In: Prichard, H.M., Potts, P.J., Bowles, J.F.W., and Cribb, S.J. (eds.), Geo-Platinum. Elsevier, Amsterdam, p. 113–143.
Barnes, S.J., Naldrett, A.J., and Gorton, M.P., 1985, The origin of the fractionation of platinum-group elements in terrestrial magmas. Chemical Geology, 53, 307–323.
Bechtel, A., Ghazia, A.M., Elliott, W.C., and Oszczepalskib, S., 2001, The occurrences of the rare earth elements and the platinum group elements in relation to base metal zoning in the vicinity of Rote Faule in the Kupferschiefer of Poland. Applied Geochemistry, 16, 375–386.
Borg, G., Tredoux, M., Maiden, K.J., Sellschop, J.P.F., and Wayward, O.F.D., 1987, PGE- and Au-distribution in rift-related volcanics, sediments and stratabound Cu/Ag ores of Middle Proterozoic age in Central SWA/Namibia. In: Prichard, H.M., Potts, P.J., Bowles, J.F.W., and Cribb, S.J. (eds.), Geo-Platinum. Elsevier, Amsterdam, p. 303–317.
Brugmann, G.B., Naldrett, A.J., and MacDonald, A.J., 1989, Magma mixing and constitutional zone refining in the Lac des Iles Complex, Ontario: genesis of platinum-group element mineralization. Economic Geology, 84, 1557–1573.
Canet, C., Alfonso, P., Melgarejo, J.C., and Belyatsky, B.V., 2004, Geochemical evidences of sedimentary-exhalative origin of the shale-hosted PGE-Ag-Au-Zn-Cu occurrences of the Prades Mountains (Catalonia, Spain): trace-element abundances and Sm-Nd isotopes. Journal of Geochemical Exploration, 82, 17–33.
Cheong, C.S., Jeong, G.Y., Kim, H., Choi, M.S., Lee, S.H., and Cho, M., 2003, Early Permian peak metamorphism recorded in U-Pb system of black slates from the Ogcheon metamorphic belt, South Korea, and its tectonic implication. Chemical Geology, 193, 81–92.
Choi, D.K., Woo, J., and Park, T.Y., 2012, The Okcheon Supergroup in Lake Chungju area, Korea: Neoproterozoic volcanic and glaciogenic sedimentary successions in a rift basin. Geosciences Journal, 12, 207–227.
Cho, M. and Kim, H., 2002, Metamorphic evolution of the Ogcheon metamorphic belt: review of recent studies and remaining problems. Journal of the Petrological Society of Korea, 11, 121–137.
Cho, M. and Kim, H., 2005, Metamorphic evolution of the Ogcheon belt, Korea: a review and new age constraint. International Geology Review, 47, 41–57.
Chough, S.K., 1981, Submarine debris flow deposits in the Ogcheon Basin, Korean Peninsula. UN ESCAP, CCOP Technology Bulletin, 14, 17–29.
Chough, S.K., 2013, Geology and sedimentology of the Korean Peninsula. Elsevier, Amsterdam, 363 p.
Cluzel, D., Cadet, J.P., and Lapierre, H., 1990, Geodynamics of the Ogcheon Belt (South Korea). Tectonophysics, 183, 41–56.
Coveney, R.M., Murowchick, J.B., Grauch, R.I., Nansheng, C., and Glascock, M.D., 1992, Field relations, origins, and resource implications for platiniferous molybdenum-nickel ores in black shales of South China. Exploration and Mining Geology, 1, 21–28.
Green, A. and Peck, D., 2005, Platinum group elements exploration: Economic considerations and geological criteria. In: Mungall, J.E. (ed.), Exploration for deposits of platinum group elements. Short Course Series v. 35, Mineralogical Association of Canada, Ottawa, p.247–274.
Hughes, H.S.R., McDonald, I., and Kerr, A.C., 2015, Platinum-group element signatures in the North Atlantic Igneous Province: Implications for mantle controls on metal budgets during continental breakup. Lithos, 233, 89–110.
Hulbert, L.J., Gregoire, C.D., and Paktunc, D., 1992, Sedimentary nickel, zinc, and platinum-group-element mineralization in Devonian black shales at the Nick property, Yukon, Canada: a new deposit type. Exploration and Mining Geology, 1, 39–62.
Jeong, G.Y., 2006, Mineralogy and geochemistry of metalliferous black slates in the Okcheon metamorphic belt, Korea: a metamorphic analogue of black shales in the South China block. Mineralium Deposita, 41, 469–481.
Jiang, S.Y., Yang, J.H., Ling, H.F., Chen, Y.Q., Feng, H.Z., Zhao, K.D., and Ni, P., 2007, Extreme enrichment of polymetallic Ni-Mo-PGE-Au in lower Cambrian black shales of South China: An Os isotope and PGE geochemical investigation. Palaeogeography, Palaeoclimatology, Palaeoecology, 254, 217–228.
Jiang, S.Y., Yang, J.H., Ling, H.F., Feng, H.Z., Chen, Y.Q., and Chen, J.H., 2003, Re-Os isotopes and PGE geochemistry of black shales and intercalated Ni-Mo polymetallic sulfide bed from the Lower Cambrian Niutitang Formation, South China. Progress in Natural Sciences, 13, 788–794.
Jo, N.H., Shin, D.B., Kim, C.R., and Yi, M.J., 2013, Geology and geochemical characteristics of uranium mineralized zone in Suyoung area, Geumsan. Journal of the Geological Society of Korea, 49, 231–244. (in Korean with English abstract)
Kang, J.H., Hayasaka, Y., and Ryoo, C.R., 2012, Tectonic evolution of the central Ogcheon Belt, Korea. Journal of the Petrological Society of Korea, 21, 129–150. (in Korean with English abstract)
Kim, J.H., 1989, Geochemistry and genesis of Guryongsan (Ogcheon) uraniferous black slate. Journal of the Korean Institute of Mining Geology, 22, 35–63.
Koh, H.J. and Kim, J.H., 1995, Deformation sequence and characteristics of the Ogcheon Supergroup in the Goesan area, central Ogcheon belt, Korea. Journal of the Geological Society of Korea, 31, 271–298. (in Korean with English abstract)
Kucha, H., 1982, Platinum-group metals in the Zechstein copper deposit, Poland. Economic Geology, 77, 1578–1591.
Lee, K.S., Chang, H.W., and Park, K.H., 1998, Neoproterozoic bimodal volcanism in the central Ogcheon belt, Korea: age and tectonic implication. Precambrian Research, 89, 47–57.
Lee, M.S., 1978, Geochemical study of granite intrusions in the area of uranium bearing formation of the Ogcheon System. Journal of the Geological Society of Korea, 14, 113–119. (in Korean with English abstract)
Lee, M.S. and Chon, H.T., 1980, Geochemical correlations between uranium and other components in U-bearing formations of Ogcheon Belt. Journal of the Korean Institute of Mining Geology, 13, 241–246. (in Korean with English abstract)
Lee, S.M., Park, H.I., Kim, S.J., Park, B.S., and Lee, S.H., 1981, Genesis of the uranium deposits in the metasediments of Deogpyeong area, Goesan-gun. Journal of the Geological Society of Korea, 17, 53–68. (in Korean with English abstract)
Lehmann, B., Mao, J., Li, S., Zhang, G., and Zeng, M., 2003, Re-Os dating of polymetallic Ni-Mo-PGE-Au mineralization in Lower Cambrian black shales of South China and its geological significance–a reply. Economic Geology, 98, 663–664.
Li, Z.X., Li, X.H., Kinny, P.D., Wang, J., Zhang, S., and Zhou, H., 2003, Geochronology of Neoproterozoic syn-rift magmatism in the Yangtze Craton, South China and correlations with other continents: evidence for a mantle superplume that broke up Rodinia. Precambrian Research, 122, 85–109.
Lott, D.A., Coveney, R.M., Murowchick, J.B., and Grauch, R.I., 1999, Sedimentary exhalative nickel–molybdenum ores in South China. Economic Geology, 94, 1051–1066.
Min, K. and Cho, M., 1998, Metamorphic evolution of the northwestern Ogcheon metamorphic belt, South Korea. Lithos, 43, 31–51. (in Korean with English abstract)
Oh, C.H., Kim, S.T., and Lee, J.H., 1995, The PT condition and timing of the main metamorphism in the southwestern part of the Okcheon metamorphic belt. Journal of the Geological Society of Korea, 31, 343–361. (in Korean with English abstract)
Pasava, J., Barnes, S.J., and Vymazalova, A., 2003, The use of mantle normalization and metal ratios in the identification of the sources of platinum-group elements in various metal-rich black shales. Mineralium Deposita, 38, 775–783.
Pasava, J., Hladikova, J., and Dobes, P., 1996, Origin of Proterozoic metal-rich black shales from the Bohemian Massif, Czech Republic. Economic Geology, 91, 63–79.
Piper, D.Z., 1994, Seawater as the source of minor elements in black shales, phosphorites and other sedimentary rocks. Chemical Geology, 114, 95–114.
Shin, D.B. and Kim, S.J., 2011, Geochemical characteristics of black slate and coaly slate from the uranium deposit in Deokpyeong area. Economic and Environmental Geology, 44, 373–386. (in Korean with English abstract)
Shin, I.K., Kim, S.H., and Shin, D.B., 2016, Mineralogy and sulfur isotope compositions of the uraniferous black slates in the Ogcheon Metamorphic Belt, South Korea. Journal of Geochemical Exploration, 169, 1–12.
Steiner, M., Wallis, E., Erdtmann, B.D., Zhao, Y.L., and Yang, R.D., 2001, Submarine-hydrothermal exhalative ore layers in black shales from South China and associated fossils: insights into a Lower Cambrian facies and bio-evolution. Palaeogeography, Palaeoclimatology, Palaeoecology, 169, 165–191.
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Shin, D., Kim, S. PGE distribution in the metalliferous black slates of the Okcheon Metamorphic Belt, South Korea. Geosci J 20, 827–835 (2016). https://doi.org/10.1007/s12303-016-0029-6
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DOI: https://doi.org/10.1007/s12303-016-0029-6