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Enhanced efficiency of top-emission InP-based green quantum dot light-emitting diodes with optimized angular distribution

Abstract

High resolution and wide color gamut are two key requirements for novel display technologies. Owing to the distinguishing advantages over conventional displays, such as intrinsic wide color gamut and the possibility to achieve high resolution, quantum dot light-emitting diodes (QLED) have drawn considerable attention in recent years. On the other hand, indium phosphide quantum dots (InP QDs) have shown a great potential as a replacement for cadmium selenide (CdSe) QDs in display applications due to the inherent toxicity of cadmium-based QDs. In this study, we investigate a top-emission InP-based green QLED with optimized angular distribution. By adjusting the electrical and optical architecture, the device exhibits improved properties with a maximum current efficiency of 30.1 cd/A and a narrowed full width at half maxima (FWHM)of 31 nm, which are the best results ever reported to our knowledge.

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References

  1. Salehi, A.; Fu, X. Y.; Shin, D. H.; So, F. Recent advances in OLED optical design. Adv. Funct. Mater. 2019, 29, 1808803.

    Article  Google Scholar 

  2. Wei, Q.; Fei, N.; Islam, A.; Lei, T.; Hong, L.; Peng, R. X.; Fan, X.; Chen, L.; Gao, P. Q.; Ge, Z. Y. Small-molecule emitters with high quantum efficiency: Mechanisms, structures, and applications in OLED devices. Adv. Opt. Mater. 2018, 6, 1800512.

    Article  Google Scholar 

  3. Wu, J. B.; Agrawal, M.; Becerril, H. A.; Bao, Z. N.; Liu, Z. F.; Chen, Y. S.; Peumans, P. Organic light-emitting diodes on solution-processed graphene transparent electrodes. ACS Nano 2010, 4, 43–48.

    Article  CAS  Google Scholar 

  4. Wu, T. Z.; Sher, C. W.; Lin, Y.; Lee, C. F.; Liang, S. J.; Lu, Y. J.; Chen, S. W. H.; Guo, W. J; Kuo, H. C.; Chen, Z. Mini-LED and Micro-LED: Promising candidates for the next generation display technology. Appl. Sci. 2018, 8, 1557.

    Article  Google Scholar 

  5. Huang, Y. G.; Tan, G. J; Gou, F. W; Li, M. C.; Lee, S. L.; Wu, S. T. Prospects and challenges of mini-LED and micro-LED displays. J. Soc. Inf. Disp. 2019, 27, 387–401.

    Article  Google Scholar 

  6. Rogach, A. L.; Gaponik, N.; Lupton, J. M.; Bertoni, C.; Gallardo, D. E.; Dunn, S.; Pira, N. L.; Paderi, M.; Repetto, P.; Romanov, S. G. et al. Light-emitting diodes with semiconductor nanocrystals. Angew. Chem., Int. Ed. 2008, 47, 6538–6549.

    Article  CAS  Google Scholar 

  7. Pietryga, J. M.; Park, Y. S.; Lim, J.; Fidler, A. F.; Bae, W. K.; Brovelli, S.; Klimov, V. I. Spectroscopic and device aspects of nanocrystal quantum dots. Chem. Rev. 2016, 116, 10513–10622.

    Article  CAS  Google Scholar 

  8. Liu, Y.; Jiang, C. B.; Song, C.; Wang, J. H.; Mu, L.; He, Z. W.; Zhong, Z. J.; Cun, Y. K.; Mai, C. H.; Wang, J. et al. Highly efficient all-solution processed inverted quantum dots based light emitting diodes. ACS Nano 2018, 12, 1564–1570.

    Article  CAS  Google Scholar 

  9. Shirasaki, Y.; Supran, G. J.; Bawendi, M. G.; Bulovic, V. Emergence of colloidal quantum-dot light-emitting technologies. Nat. Photonics 2013, 7, 13–23.

    Article  CAS  Google Scholar 

  10. Yuan, Y.; Bi, Y.; Sun, M. Y.; Wang, D. Z.; Wang, D. D.; Gao, W. N.; Zhang, S. Speckle evaluation in laser display: From speckle contrast to speckle influence degree. Opt. Commun. 2020, 454, 124405.

    Article  CAS  Google Scholar 

  11. Yaras, F.; Kang, H.; Onural, L. Circular holographic video display system. Opt. Express 2011, 19, 9147–9156.

    Article  Google Scholar 

  12. Zhang, L. Q.; Yang, X. L.; Jiang, Q.; Wang, P. Y.; Yin, Z. G.; Zhang, X. W; Tan, H. R; Yang, Y. M.; Wei, M. Y.; Sutherland, B. R. et al. Ultra-bright and highly efficient inorganic based perovskite light-emitting diodes. Nat. Commun. 2017, 8, 15640.

    Article  CAS  Google Scholar 

  13. Xiao, Z. G; Kerner, R. A.; Zhao, L. F; Tran, N. L.; Lee, K. M.; Koh, T. W.; Scholes, G. D.; Rand, B. P. Efficient perovskite light-emitting diodes featuring nanometre-sized crystallites. Nat. Photonics 2017, 11, 108–115.

    Article  CAS  Google Scholar 

  14. Mei, W. H; Zhang, Z. Q.; Zhang, A. D.; Li, D.; Zhang, X. Y.; Wang, H. W.; Chen, Z.; Li, Y. Z.; Li, X. G.; Xu, X. G. High-resolution, full-color quantum dot light-emitting diode display fabricated via photolithography approach. Nano Res. 2020, 13, 2485–2491.

    Article  CAS  Google Scholar 

  15. Colvin, V. L.; Schlamp, M. C.; Alivisatos, A. P. Light-emitting diodes made from cadmium selenide nanocrystals and a semiconducting polymer. Nature 1994, 370, 354–357.

    Article  CAS  Google Scholar 

  16. Dai, X. L.; Zhang, Z. X.; Jin, Y. Z.; Niu, Y.; Cao, H. J.; Liang, X. Y.; Chen, L. W.; Wang, J. P.; Peng, X. G. Solution-processed, highperformance light-emitting diodes based on quantum dots. Nature 2014, 515, 96–99.

    Article  CAS  Google Scholar 

  17. Mashford, B. S.; Stevenson, M.; Popovic, Z.; Hamilton, C.; Zhou, Z. Q.; Breen, C.; Steckel, J.; Bulovic, V.; Bawendi, M.; Coe-Sullivan, S. et al. High-efficiency quantum-dot light-emitting devices with enhanced charge injection. Nat. Photonics 2013, 7, 407–412.

    Article  CAS  Google Scholar 

  18. Coe, S.; Woo, W. K.; Bawendi, M.; Bulović, V. Electroluminescence from single monolayers of nanocrystals in molecular organic devices. Nature 2002, 420, 800–803.

    Article  CAS  Google Scholar 

  19. Lim, J.; Park, M.; Bae, W. K.; Lee, D.; Lee, S.; Lee, C.; Char, K. Highly efficient cadmium-free quantum dot light-emitting diodes enabled by the direct formation of excitons within InP@ZnSeS quantum dots. ACS Nano 2013, 7, 9019–9026.

    Article  CAS  Google Scholar 

  20. Li, L.; Reiss, P. One-pot synthesis of highly luminescent InP/ZnS nanocrystals without precursor injection. J. Am. Chem. Soc. 2008, 130, 11588–11589.

    Article  CAS  Google Scholar 

  21. Xie, R. G.; Battaglia, D.; Peng, X. G. Colloidal InP nanocrystals as efficient emitters covering blue to near-infrared. J. Am. Chem. Soc. 2007, 129, 15432–15433.

    Article  CAS  Google Scholar 

  22. Li, D.; Kristal, B.; Wang, Y. J.; Feng, J. W.; Lu, Z. G.; Yu, G.; Chen, Z.; Li, Y. Z.; Li, X. G.; Xu, X. G. Enhanced efficiency of InP-based red quantum dot light-emitting diodes. ACS Appl. Mater. Inter. 2019, 11, 34067–34075.

    Article  CAS  Google Scholar 

  23. Li, Y.; Hou, X. Q.; Dai, X. L.; Yao, Z. L.; Lv, L. L.; Jin, Y. Z.; Peng, X. G. Stoichiometry-controlled InP-based quantum dots: Synthesis, photoluminescence, and electroluminescence. J. Am. Chem. Soc. 2019, 141, 6448–6452.

    Article  CAS  Google Scholar 

  24. Won, Y. H.; Cho, O.; Kim, T.; Chung, D. Y.; Kim, T.; Chung, H.; Jang, H.; Lee, J.; Kim, D.; Jang, E. Highly efficient and stable InP/ZnSe/ZnS quantum dot light-emitting diodes. Nature 2019, 575, 634–638.

    Article  CAS  Google Scholar 

  25. Cao, F.; Wang, S.; Wang, F. J.; Wu, Q. Q.; Zhao, D. W.; Yang, X. Y. A layer-by-layer growth strategy for large-size InP/ZnSe/ZnS core-shell quantum dots enabling high-efficiency light-emitting diodes. Chem. Mater. 2018, 30, 8002–8007.

    Article  CAS  Google Scholar 

  26. Lim, J.; Park, M.; Bae, W. K.; Lee, D.; Lee, S.; Lee, C.; Char, K. Highly efficient cadmium-free quantum dot light-emitting diodes enabled by the direct formation of excitons within InP@ZnSeS quantum dots. ACS Nano 2013, 7, 9019–9026.

    Article  CAS  Google Scholar 

  27. Zhang, H.; Hu, N.; Zeng, Z. P.; Lin, Q. L.; Zhang, F. J.; Tang, A. W.; Jia, Y.; Li, L. S.; Shen, H. B.; Teng, F. et al. High-efficiency green InP quantum dot-based electroluminescent device comprising thick-shell quantum dots. Adv. Opt. Mater. 2019, 7, 1801602.

    Article  Google Scholar 

  28. Moon, H.; Lee, W.; Kim, J.; Lee, D.; Cha, S.; Shin, S.; Chae, H. Composition-tailored ZnMgO nanoparticles for electron transport layers of highly efficient and bright InP-based quantum dot light emitting diodes. Chem. Commun. 2019, 55, 13299–13302.

    Article  CAS  Google Scholar 

  29. Li, Y.; Li, D.; Kristal, B.; Feng, J.; Lu, Z.; Chen, Z.; Li, X. Enhanced efficiency of InP-based red and green quantum dot light-emitting diodes. SID Symp. Dig. Tech. Pap. 2020, 51, 960–963.

    Article  CAS  Google Scholar 

  30. Lee, T.; Hahm, D.; Kim, K.; Bae, W. K.; Lee, C.; Kwak, J. Highly efficient and bright inverted top-emitting InP quantum dot light-emitting diodes introducing a hole-suppressing interlayer. Small 2019, 15, e1905162.

    Article  Google Scholar 

  31. Hofmann, S.; Thomschke, M.; Lüessem, B.; Leo, K. Top-emitting organic light-emitting diodes. Opt. Express 2011, 19, A1250–A1264.

    Article  CAS  Google Scholar 

  32. Wang, H. C.; Zhang, H.; Chen, H. Y.; Yeh, H. C.; Tseng, M. R.; Chung, R. J.; Chen, S.; Liu, R. S. Cadmium-free InP/ZnSeS/ZnS heterostructure-based quantum dot light-emitting diodes with a ZnMgO electron transport layer and a brightness of over 10,000 cd·m−2. Small 2017, 13, 1603962.

    Article  Google Scholar 

  33. Ghosh, S.; Ghosh, M.; Kumar, P.; Sarkar, A. S.; Pal, S. K. Quenching of the excitonic emission of ZnO quantum dots due to Auger-assisted hole transfer to CdS quantum dots. J. Phys. Chem. C 2016, 120, 27717–27723.

    Article  CAS  Google Scholar 

  34. Shi, A. M.; Sun, J. H.; Zeng, Q. H.; Shao, C.; Sun, Z. C.; Li, H. B.; Kong, X. G.; Zhao, J. L. Photoluminescence quenching of CdTe/CdS core-shell quantum dots in aqueous solution by ZnO nanocrystals. J. Lumin. 2011, 131, 1536–1540.

    Article  CAS  Google Scholar 

  35. Zhang, Q.; Gu, X. B.; Zhang, Q. S.; Jiang, J.; Jin, X.; Li, F.; Chen, Z. P.; Zhao, F.; Li, Q. H. ZnMgO: ZnO composite films for fast electron transport and high charge balance in quantum dot light emitting diodes. Opt. Mater. Express 2018, 8, 909–918.

    Article  CAS  Google Scholar 

  36. Kim, H. M.; Cho, S.; Kim, J.; Shin, H.; Jang, J. Li and Mg Co-doped zinc oxide electron transporting layer for highly efficient quantum dot light-emitting diodes. ACS Appl. Mater. Inter. 2018, 10, 24028–24036.

    Article  CAS  Google Scholar 

  37. Liu, G. H.; Zhou, X.; Chen, S. M. Very bright and efficient microcavity top-emitting quantum dot light-emitting diodes with Ag electrodes. ACS Appl. Mater. Inter. 2016, 8, 16768–16775.

    Article  CAS  Google Scholar 

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Acknowledgements

This work was supported by the National Key R&D Program of China under Grant No. 2016YFB0401700.

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Correspondence to Zhuo Chen, Yanzhao Li, Xinguo Li or Xiaoguang Xu.

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Li, D., Feng, J., Zhu, Y. et al. Enhanced efficiency of top-emission InP-based green quantum dot light-emitting diodes with optimized angular distribution. Nano Res. 14, 4243–4249 (2021). https://doi.org/10.1007/s12274-021-3596-4

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  • DOI: https://doi.org/10.1007/s12274-021-3596-4

Keywords

  • Cd-free quantum dots
  • quantum dot light-emitting diode (QLED)
  • top-emission
  • angular distribution
  • current efficiency