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Electrochemical conversion of CO2 to syngas with a wide range of CO/H2 ratio over Ni/Fe binary single-atom catalysts

Abstract

A series of carbon-based binary single-atom catalysts of Fe and Ni coordinated by nitrogen are fabricated using a glucose-chelating method. Depending on the Ni/Fe content, they exhibit a wide-range of controllable CO/H2 ratio from 0.14 to 10.86, which is meaningful to specific chemical processes. The durability of the catalyst is evaluated over an 8-hour period with no significant degradation of activity. The variation of the faradaic efficiency with Ni/Fe content is justified by density-functional-theory based calculation of the reaction barrier in both hydrogen evolution and CO2 reduction reactions.

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Acknowledgements

This work was financially supported by the Natural Science Foundation of Tianjin, China (No. 18JCYBJC20600) and Institute of Energy, Hefei Comprehensive National Science Center (No. 19KZS207).

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Correspondence to Shi Hu.

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Zhang, M., Hu, Z., Gu, L. et al. Electrochemical conversion of CO2 to syngas with a wide range of CO/H2 ratio over Ni/Fe binary single-atom catalysts. Nano Res. 13, 3206–3211 (2020). https://doi.org/10.1007/s12274-020-2988-1

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Keywords

  • CO2 reduction
  • syngas
  • binary single-atom catalyst
  • electrocatalysis