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Selective growth of ZnO nanorods on SiO2/Si substrates using a graphene buffer layer

Nano Research volume 4, pages 440–447 (2011)Cite this article

Abstract

A promising strategy for the selective growth of ZnO nanorods on SiO2/Si substrates using a graphene buffer layer in a low temperature solution process is described. High densities of ZnO nanorods were grown over a large area and most ZnO nanorods were vertically well-aligned on graphene. Furthermore, selective growth of ZnO nanorods on graphene was realized by applying a simple mechanical treatment, since ZnO nanorods formed on graphene are mechanically stable on an atomic level. These results were confirmed by first principles calculations which showed that the ZnO-graphene binding has a low destabilization energy. In addition, it was found that ZnO nanorods grown on SiO2/Si with a graphene buffer layer have better optical properties than ZnO nanorods grown on bare SiO2/Si. The nanostructured ZnO-graphene materials have promising applications in future flexible electronic and optical devices.

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References

  1. Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. V.; Grigorieva, I. V.; Firsov, A. A. Electric field effect in atomically thin carbon films. Science 2004, 306, 666–669.

    Article  CAS  Google Scholar 

  2. Stankovich, S.; Dikin, D. A.; Dommett, G. H. B.; Kohlhaas, K. M.; Zimney, E. J.; Stach, E. A.; Piner, R. D.; Nguyen, S. T.; Ruoff, R. S. Graphene-based composite materials. Nature 2006, 442, 282–286.

    Article  CAS  Google Scholar 

  3. Kim, K. S.; Zhao, Y.; Jang, H.; Lee, S. Y.; Kim, J. M.; Kim, K. S.; Ahn, J. H.; Kim, P.; Choi, J. Y.; Hong, B. H. Large-scale pattern growth of graphene films for stretchable transparent electrodes. Nature 2009, 457, 706–710.

    Article  CAS  Google Scholar 

  4. Reina, A.; Thiele, S.; Jia, X.; Bhaviripudi, S.; Dresselhaus, M. S.; Schaefer, J. A.; Kong, J. Growth of large-area single- and bi-layer graphene by controlled carbon precipitation on polycrystalline Ni surfaces. Nano Res. 2009, 2, 509–516.

    Article  CAS  Google Scholar 

  5. Xu, Y.; Liu, Z.; Zhang, X.; Wang, Y.; Tian, J.; Huang, Y.; Ma, Y.; Zhang, X.; Chen, Y. A graphene hybrid material covalently functionalized with porphyrin: Synthesis and optical limiting property. Adv. Mater. 2009, 21, 1275–1279.

    Article  CAS  Google Scholar 

  6. Kamat, P. V. Graphene-based nanoarchitectures. Anchoring semiconductor and metal nanoparticles on a two-dimensional carbon support. J. Phys. Chem. Lett. 2009, 1, 520–527.

    Article  Google Scholar 

  7. Lightcap, I. V.; Kosel, T. H.; Kamat, P. V. Anchoring semiconductor and metal nanoparticles on a two-dimensional catalyst Mat. storing and shuttling electrons with reduced graphene oxide. Nano Lett. 2010, 10, 577–583.

    Article  CAS  Google Scholar 

  8. Wang, X.; Tabakman, S. M.; Dai, H. Atomic layer deposition of metal oxides on pristine and functionalized graphene. J. Am. Chem. Soc. 2008, 130, 8152–8153.

    Article  CAS  Google Scholar 

  9. Kim, Y. T.; Han, J. H.; Hong, B. H.; Kwon, Y. U. Electrochemical deposition of CdSe quantum dot arrays on large-scale graphene electrodes using mesoporous silica thin film templates. Adv. Mater. 2010, 22, 515–518.

    Article  CAS  Google Scholar 

  10. Lee, B.; Park, S. Y.; Kim, H. C.; Cho, H.; Vogel, E. M.; Kim, M. J.; Wallace, R. M.; Kim, J. Conformal Al2O3 dielectric layer deposited by atomic layer deposition for graphene-based nanoelectronics. Appl. Phys. Lett. 2008, 92, 203102.

    Article  Google Scholar 

  11. Tong, L. M.; Li, Z. P.; Zhu, T.; Xu, H. X.; Liu, Z. F. Single gold-nanoparticle-enhanced raman scattering of individual single-walled carbon nanotubes via atomic force microscope manipulation. J. Phys. Chem. C 2008, 112, 7119–7123.

    Article  CAS  Google Scholar 

  12. Saito, N.; Haneda, H.; Sekiguchi, T.; Ohashi, N.; Sakaguchi, I.; Koumoto, K. Low-temperature fabrication of light-emitting zinc oxide micropatterns using self-assembled monolayers. Adv. Mater. 2002, 14, 418–421.

    Article  CAS  Google Scholar 

  13. Choi, D.; Choi, M. Y.; Choi, W. M.; Shin, H. J.; Seo, J. S.; Park, J.; Yoon, S. M.; Chae, S. J.; Lee, Y. H.; Kim, S. W.; Choi, J. Y.; Lee, S. Y.; Kim, J. M. Fully rollable transparent nanogenerators based on graphene electrodes. Adv. Mater. 2010, 22, 2187–2192.

    Article  CAS  Google Scholar 

  14. Wang, X.; Gao, Y.; Wei, Y.; Wang, Z. L. Output of an ultrasonic wave-driven nanogenerator in a confined tube. Nano Res. 2009, 2, 177–182.

    Article  CAS  Google Scholar 

  15. Kim, Y. J.; Lee, J. H.; Yi, G. C. Vertically aligned ZnO nanostructures grown on graphene layers. Appl. Phys. Lett. 2009, 95, 213101.

    Article  Google Scholar 

  16. Lee, J. M.; Pyun, Y. B.; Yi, J.; Choung, W.; Park, W. I. ZnO nanorod-graphene hybrid architectures for multifunctional conductors. J. Phys. Chem. C 2009, 113, 19134–19138.

    Article  CAS  Google Scholar 

  17. Vanderbilt, D. Soft self-consistent pseudopotentials in a generalized eigenvalue formalism. Phys. Rev. B 1990, 41, 7892–7895.

    Article  Google Scholar 

  18. Choi, M. Y.; Choi, D.; Jin, M. J.; Kim, I.; Kim, S. H.; Choi, J. Y.; Lee, S. Y.; Kim, J. M.; Kim, S W. Mechanically powered transparent flexible charge-generating nanodevices with piezoelectric ZnO nanorods Adv. Mater. 2009, 21, 2185–2189.

    Article  CAS  Google Scholar 

  19. Choi, D.; Choi, M. Y.; Shin, H. J.; Yoon, S. M.; Seo, J. S.; Choi, J. Y.; Lee, S. Y.; Kim, J. M.; Kim, S. W. Nanoscale networked single-walled carbon-nanotube electrodes for transparent flexible nanogenerators. J. Phys. Chem. C 2010, 114, 1379–1384.

    Article  CAS  Google Scholar 

  20. Kim, K. K.; Lee, S. D.; Kim, H.; Park, J. C.; Lee, S. N.; Park, Y.; Park, S. J.; Kim, S. W. Enhanced light extraction efficiency of GaN-based light-emitting diodes with ZnO nanorod arrays grown using aqueous solution. Appl. Phys. Lett. 2009, 94, 071118.

    Article  Google Scholar 

  21. Blake, P.; Hill, E. W.; Castro Neto, A. H.; Novoselov, K. S.; Jiang, D.; Yang, R.; Booth, T. J.; Geim, A. K. Making graphene visible. Appl. Phys. Lett. 2007, 91, 063124.

    Article  Google Scholar 

  22. Ni, Z. H.; Wang, H. M.; Kasmin, J.; Fan, H. M.; Yu, T.; Wu, Y. H.; Feng, Y. P.; Shen, Z. X. Graphene thickness determination using reflection and contrast spectroscopy. Nano Lett. 2007, 7, 2758–2763.

    Article  CAS  Google Scholar 

  23. Chae, S. J.; Gunes, F.; Kim, K. K.; Kim, E. S.; Han, G. H.; Kim, S. M.; Shin, H. J.; Yoon, S. M.; Choi, J. Y.; Park, M. H.; Yang, C. W.; Pribat, D.; Lee, Y. H. Synthesis of large-area graphene layers on poly-nickel substrate by chemical vapor deposition: Wrinkle formation. Adv. Mater. 2009, 21, 2328–2333.

    Article  CAS  Google Scholar 

  24. Lee, S. D.; Kim, Y. S.; Yi, M. S.; Choi, J. Y.; Kim, S. W. Morphology control and electroluminescence of ZnO nanorod/GaN heterojunctions prepared using aqueous solution. J. Phys. Chem. C 2009, 113, 8954–8958.

    Article  CAS  Google Scholar 

  25. Xuan, Y.; Lin, H. C.; Ye, P. D.; Wilk, G. D. Capacitance-voltage studies on enhancement-mode InGaAs metal-oxidesemiconductor field-effect transistor using atomic-layerdeposited Al2O3 gate dielectric. Appl. Phys. Lett. 2006, 88, 263518.

    Article  Google Scholar 

  26. Kresse, G.; Furthmüller, J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B 1996, 54, 11169–11186.

    Article  CAS  Google Scholar 

  27. Kresse, G.; Furthmüller, J. Efficiency of ab-initio total energy calculations for metals and semiconductors using a planewave basis set. Comput. Mater. Sci. 1996, 6, 15–19.

    Article  CAS  Google Scholar 

  28. Kresse, G.; Joubert, D. From ultrasoft pseudopotentials to the projector augmented-wave method. Phys. Rev. B 1999, 59, 1758–1775.

    Article  CAS  Google Scholar 

  29. Nobis, T.; Kaidashev, E. M.; Rahm, A.; Lorenz, M.; Lenzner, J.; Grundmann, M. Spatially inhomogeneous impurity distribution in ZnO micropillars. Nano Lett. 2004, 4, 797–800.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Samsung Advanced Institute of Technology, Giheung, Yongin, Gyeonggi, 446-712, Republic of Korea

    Won Mook Choi, Hyo Sug Lee, Kihong Kim, Hyeon-Jin Shin, Seon-Mi Yoon & Jae-Young Choi

  2. School of Advanced Materials Science and Engineering, Sungkyunkwan (SKKU) Advanced Institute of Nanotechnology (SAINT), Center for Human Interface Nanotechnology (HINT), Sungkyunkwan University, Suwon, 440-746, Republic of Korea

    Kyung-Sik Shin & Sang-Woo Kim

  3. Department of Mechanical Engineering, Kyung Hee University, Yongin, Gyeonggi, 446-701, Republic of Korea

    Dukhyun Choi

Authors
  1. Won Mook Choi
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  2. Kyung-Sik Shin
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  3. Hyo Sug Lee
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  4. Dukhyun Choi
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  5. Kihong Kim
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  6. Hyeon-Jin Shin
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  7. Seon-Mi Yoon
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  8. Jae-Young Choi
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  9. Sang-Woo Kim
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Correspondence to Jae-Young Choi or Sang-Woo Kim.

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These authors contributed equally to this work

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Choi, W.M., Shin, KS., Lee, H.S. et al. Selective growth of ZnO nanorods on SiO2/Si substrates using a graphene buffer layer. Nano Res. 4, 440–447 (2011). https://doi.org/10.1007/s12274-011-0100-6

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  • DOI: https://doi.org/10.1007/s12274-011-0100-6

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