Abstract
To meet increasingly stringent emission regulations, diesel engines must be equipped with DOC, DPF and SCR. Five performance parameters including system back pressure, HC conversion efficiency, conversion efficiency of NO to NO2, passive regeneration rate, and conversion efficiency of NO to N2 are very important for DOC+DPF+SCR system. Nine structural parameters including rDOC, rDPF, rSCR, σDOC, σDPF, σSCR, δDOC, δDPF, and δSCR directly affect the five performance parameters, this paper has carried out a detailed study on it. First, a simulation model of DOC+DPF+SCR system was established, and calibrated by experiment. Then, simulation was performed on the five performance parameters under different values of the nine structural parameters. Subsequently, a novel model using random forest algorithm was established to analyze the correlation between the performance parameters and the structural parameters. The results show that σDPF has the greatest influence on system backpressure, followed by rDPF. The rDOC has the greatest influence on HC conversion, followed by σDOC. The rDOC has the greatest influence on conversion of NO to NO2, followed by σDOC. The rDPF has the greatest influence on DPF passive regeneration rate, followed by rDOC. The rSCR has the greatest influence on conversion of NO to N2, followed by rDOC.
This is a preview of subscription content, access via your institution.
Abbreviations
- DOC:
-
diesel oxidation catalyst
- DPF:
-
diesel particulate filter
- SCR:
-
selective catalytic reduction
- HC:
-
hydrocarbon
- NO:
-
nitric oxide
- NO2 :
-
nitrogen dioxide
- N2 :
-
nitrogen
- r DOC :
-
length-to-diameter ratio of DOC
- r DPF :
-
length-to-diameter ratio of DPF
- r SCR :
-
length-to-diameter ratio of SCR
- σ DOC :
-
cell density of DOC
- σ DPF :
-
celldensity of DPF
- σ SCR :
-
cell density of SCR
- δ DOC :
-
wall thickness of DOC
- δ DPF :
-
wall thickness of DPF
- δ SCR :
-
wall thickness of SCR
References
Abu-Jrai, A. M., Al-Muhtaseb, A. a. H. and Hasan, A. O. (2017). Combustion, performance, and selective catalytic reduction of NOx for a diesel engine operated with combined tri fuel (H2, CH4, and conventional diesel). Energy, 119, 901–910.
Ayodhya, A. S. and Narayanappa, K. G. (2018). An overview of after-treatment systems for diesel engines. Environmental Science and Pollution Research 25, 35, 35034–35047.
Dadi, R. K., Daneshvar, K., Luss, D., Balakotaiah, V., Kalamaras, C. M. and Epling, W. (2018). Comparison of light-off performance of Pt-Pd/γ-Al2O3 dual layer and dual brick diesel oxidation catalysts. Chemical Engineering J., 335, 1004–1017.
Deng, Y., Zheng, W., E, J., Zhang, B., Zhao, X., Zuo, Q., Zhang, Z. and Han, D. (2017). Influence of geometric characteristics of a diesel particulate filter on its behavior in equilibrium state. Applied Thermal Engineering, 123, 61–73.
E, J., Liu, G., Zhang, Z., Han, D., Chen, J., Wei, K., Gong, J. and Yin, Z. (2019). Effect analysis on cold starting performance enhancement of a diesel engine fueled with biodiesel fuel based on an improved thermodynamic model. Applied Energy, 243, 321–335.
Haralampous, O. and Kontzias, T. (2014). Approximate pressure drop and filtration efficiency expressions for semi-open wall-flow channels. Canadian J. Chemical Engineering 92, 9, 1517–1525.
Herreros, J. M., Gill, S. S., Lefort, I., Tsolakis, A., Millington, P. and Moss, E. (2014). Enhancing the low temperature oxidation performance over a Pt and a Pt-Pd diesel oxidation catalyst. Applied Catalysis B: Environmental, 147, 835–841.
Hoang, S., Lu, X., Tang, W., Wang, S., Du, S., Nam, C. Y., Ding, Y., Vinluan, R. D., Zheng, J. and Gao, P. X. (2019). High performance diesel oxidation catalysts using ultra-low Pt loading on titania nanowire array integrated cordierite honeycombs. Catalysis Today, 320, 2–10.
Jung, Y., Pyo, Y. D., Jang, J., Kim, G. C., Cho, C. P. and Yang, C. (2019). NO, NO2 and N2O emissions over a SCR using DOC and DPF systems with Pt reduction. Chemical Engineering J., 369, 1059–1067.
Kapas, N., Shamim, T. and Laing, P. (2010). Effect of mass transfer on the performance of selective catalytic reduction (SCR) systems. J. Engineering for Gas Turbines and Power 133, 3, 032801.
Khalife, E., Tabatabaei, M., Demirbas, A. and Aghbashlo, M. (2017). Impacts of additives on performance and emission characteristics of diesel engines during steady state operation. Progress in Energy and Combustion Science, 59, 32–78.
Kozina, A., Radica, G. and Nižetić, S. (2020). Analysis of methods towards reduction of harmful pollutants from diesel engines. J. Cleaner Production, 262, 121105.
Lao, C. T., Akroyd, J., Eaves, N., Smith, A., Morgan, N., Nurkowski, D., Bhave, A. and Kraft, M. (2020). Investigation of the impact of the configuration of exhaust after-treatment system for diesel engines. Applied Energy, 267, 114844.
Leskovjan, M., Kočí, P. and Maunula, T. (2018). Simulation of diesel exhaust aftertreatment system DOC—pipe—SCR: The effects of Pt loading, PtOx formation and pipe configuration on the deNOx performance. Chemical Engineering Science, 189, 179–190.
Li, Z. J., Cai, D., He, L., Cao, L. J., Li, Z. Y. and Meng, Y. (2019). NO2-assisted regeneration performance enhancement of catalyzed diesel particulate filters. Environmental Engineering Science 36, 8, 922–936.
Liang, Y., Ding, X., Dai, J., Zhao, M., Zhong, L., Wang, J. and Chen, Y. (2019). Active oxygen-promoted NO catalytic on monolithic Pt-based diesel oxidation catalyst modified with Ce. Catalysis Today, 327, 64–72.
Liang, Y., Zhao, M., Wang, J., Sun, M., Li, S., Huang, Y., Zhong, L., Gong, M. and Chen, Y. (2017). Enhanced activity and stability of the monolithic Pt/SiO2-Al2O3 diesel oxidation catalyst promoted by suitable tungsten additive amount. J. Industrial and Engineering Chemistry, 54, 359–368.
Liu, J., Sun, P., Huang, H., Meng, J. and Yao, X. (2017). Experimental investigation on performance, combustion and emission characteristics of a common-rail diesel engine fueled with polyoxymethylene dimethyl ethers-diesel blends. Applied Energy, 202, 527–536.
Lupše, J., Campolo, M. and Soldati, A. (2016). Modelling soot deposition and monolith regeneration for optimal design of automotive DPFs. Chemical Engineering Science, 151, 36–50.
Mallamo, F., Longhi, S., Millo, F. and Rolando, L. (2014). Modeling of diesel oxidation catalysts for calibration and control purpose. Int. J. Engine Research 15, 8, 965–979.
Meng, D., Xu, Q., Jiao, Y., Guo, Y., Guo, Y., Wang, L., Lu, G. and Zhan, W. (2018). Spinel structured CoaMnbOx mixed oxide catalyst for the selective catalytic reduction of NOx with NH3. Applied Catalysis B: Environmental, 221, 652–663.
Nazarpoor, Z., Golden, S. and Liu, R. F. (2017). Development of advanced ultra-low PGM DOC for BS VI DOC+CDPF+SCR system. SAE Int. J. Materials and Manufacturing 10, 1, 72–77.
Park, S. and Oh, J. (2018). Uniformity index measurement technology using thermocouples to improve performance in urea-selective catalytic reduction systems. Heat and Mass Transfer 54, 11, 3253–3264.
Sampara, C. S., Bissett, E. J. and Assanis, D. (2008). Hydrocarbon storage modeling for diesel oxidation catalysts. Chemical Engineering Science 63, 21, 5179–5192.
Serrano, J. R., Climent, H., Piqueras, P. and Angiolini, E. (2016). Filtration modelling in wall-flow particulate filters of low soot penetration thickness. Energy, 112, 883–898.
Shan, Y. L., Shi, X. Y., Du, J. P., Yan, Z. D., Yu, Y. B. and He, H. (2019). SSZ-13 synthesized by solvent-free method: A potential candidate for NH3-SCR catalyst with high activity and hydrothermal stability. Industrial & Engineering Chemistry Research 58, 14, 5397–5403.
Shi, X., Liu, F., Xie, L., Shan, W. and He, H. (2013). NH3-SCR performance of fresh and hydrothermally aged Fe-ZSM-5 in standard and fast selective catalytic reduction reactions. Environmental Science & Technology 47, 7, 3293–3298.
Shi, Y. X., Cai, Y. X., Li, X. H., Pu, X. Y., Zhao, N. and Wang, W. K. (2020). Effect of the amount of trapped particulate matter on diesel particulate filter regeneration performance using non-thermal plasma assisted by exhaust waste heat. Plasma Science & Technology 22, 1, 015504.
Shin, Y., Jung, Y., Cho, C. P., Pyo, Y. D., Jang, J., Kim, G. and Kim, T. M. (2020). NOx abatement and N2O formation over urea-SCR systems with zeolite supported Fe and Cu catalysts in a nonroad diesel engine. Chemical Engineering J., 381, 122751.
Spiteri, A., Dimopoulos Eggenschwiler, P., Liao, Y., Wigley, G., Michalow-Mauke, K. A., Elsener, M., Kröcher, O. and Boulouchos, K. (2015). Comparative analysis on the performance of pressure and air-assisted urea injection for selective catalytic reduction of NOx. Fuel, 161, 269–277.
Tan, P. Q., Wang, D. Y., Yao, C. J., Zhu, L., Wang, Y. H., Wang, M. H., Hu, Z. Y. and Lou, D. M. (2020a). Extended filtration model for diesel particulate filter based on diesel particulate matter morphology characteristics. Fuel, 277, 118150.
Tan, P. Q., Zhang, S. C., Wang, S. Y., Hu, Z. Y. and Lou, D. M. (2020b). Simulation on catalytic performance of fresh and aged SCR catalysts for diesel engines. J. Energy Institute 93, 6, 2280–2292.
Torregrosa, A. J., Serrano, J. R., Arnau, F. J. and Piqueras, P. (2011). A fluid dynamic model for unsteady compressible flow in wall-flow diesel particulate filters. Energy 36, 1, 671–684.
Tsuneyoshi, K. and Yamamoto, K. (2012). A study on the cell structure and the performances of wall-flow diesel particulate filter. Energy 48, 1, 492–499.
Walke, N. H., Nandgaonkar, M. R. and Marathe, N. V. (2016). NOx, soot, and fuel consumption predictions under transient operating cycle for common rail high power density diesel engines. J. Combustion, 2016, 1374768.
Wang, P., Luo, P., Yin, J. and Lei, L. (2016). Evaluation of NO oxidation properties over a Mn-Ce/γ-Al2O3 catalyst. J. Nanomaterials, 2016, 2103647.
Wang, Y., Xie, L., Liu, F. and Ruan, W. (2019). Effect of preparation methods on the performance of CuFe-SSZ-13 catalysts for selective catalytic reduction of NOx with NH3. J. Environmental Sciences, 81, 195–204.
Wardana, M. K. A., Hyun, J. and Lim, O. (2019). A study of urea injection timing to predict the NOx conversion in SCR systems. Energy Procedia, 158, 1942–1948.
Xiao, G., Li, B., Tian, H., Leng, X. and Long, W. (2020). Numerical study on flow and pressure drop characteristics of a novel type asymmetric wall-flow diesel particulate filter. Fuel, 267, 117148.
Yanagihara, H., Brandstatter, W., Ohashi, N., Gschaider, B., Leixnering, J. and Stankovic, I. (2009). Evaluation of performance of diesel particulate filters through integrated multi-scale computer calculations. Topics in Catalysis 52, 13, 1842–1846.
Yu, M., Luss, D. and Balakotaiah, V. (2013). Analysis of flow distribution and heat transfer in a diesel particulate filter. Chemical Engineering J., 226, 68–78.
Zhang, B., E, J., Gong, J., Yuan, W., Zhao, X. and Hu, W. (2017). Influence of structural and operating factors on performance degradation of the diesel particulate filter based on composite regeneration. Applied Thermal Engineering, 121, 838–852.
Zhang, J., Li, Y., Wong, V. W., Shuai, S., Qi, J., Wang, G., Liu, F. and Hua, L. (2019). Experimental study of lubricant-derived ash effects on diesel particulate filter performance. Int. J. Engine Research 22, 3, 921–934.
Zhang, Z., Ye, J., Tan, D., Feng, Z., Luo, J., Tan, Y. and Huang, Y. (2021). The effects of Fe2O3 based DOC and SCR catalyst on the combustion and emission characteristics of a diesel engine fueled with biodiesel. Fuel, 290, 120039.
Zhong, F. L., Zhong, Y. J., Xiao, Y. H., Cai, G. H. and Wei, K. M. (2011). Effect of Si-doping on thermal stability and diesel oxidation activity of Pt supported porous γ-Al2O3 monolithic catalyst. Catalysis Letters 141, 12, 1828–1837.
Acknowledgement
This work was supported by the National Natural Science Foundation of China [52076154]; the National Key R&D Program of China [2017YFC0211202]; and the Prospective study funding of Nanchang Automotive Innovation Institute [QZKT 2020–07]. The authors would like to thank the editors and anonymous reviewers for their suggestions to improve the paper.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Qiang, T.P., Peng, L.Y., De Yuan, W. et al. Effects of Catalyst Structural Parameters on the Performance of Exhaust Gas Aftertreatment System of Diesel Engines. Int.J Automot. Technol. 23, 1085–1097 (2022). https://doi.org/10.1007/s12239-022-0095-x
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12239-022-0095-x