Skip to main content
Log in

Towards the Development of One-Step Scalable Self-Cleaning and Stain-Resistant Coating on Cellulosic Wood

  • Regular Article
  • Published:
Fibers and Polymers Aims and scope Submit manuscript

Abstract

In this study, hydrophilic cellulosic wood (Tectona grandis) is modified into superhydrophobic wood with the aid of octadecyltrichlorosilane (OTS) and silica nanoparticles (SiO2) using one-step facile method. The prepared superhydrophobic wood possessed water contact angle (WCA) of 167 ± 2° and the sliding angle was less than 4°. The surface morphology was examined by scanning electron microscopy (SEM) and it showed agglomeration of nanostructures on the surface of superhydrophobic wood. Fourier transform infrared spectroscopy was used to analyse the functional groups present on the produced wood, and the results showed the existence of –\({{\text{CH}}}_{2}\) and –\({{\text{CH}}}_{3}\) groups. The exceptional self-cleaning and stain resistance of modified wood made it suitable for a variety of applications. Also, it is mechanically durable as it underwent and sustained tape peeling, sand abrasion and water jet impact. The modified wood demonstrated excellent durability in exposure to UV and on exposure to solutions of varying pH. This makes the fabricated wood suitable for various applications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

Data Availability

All relevant data are included in this article and its Supplementary Information files.

References

  1. E.E. Thybring, M. Kymäläinen, L. Rautkari, Moisture in modified wood and its relevance for fungal decay. IForest. 11(3), 418–422 (2018)

    Article  Google Scholar 

  2. M.R. Pelaez-Samaniego, V. Yadama, E. Lowell, R. Espinoza-Herrera, A review of wood thermal pretreatments to improve wood composite properties. Wood Sci. Technol. 47(6), 1285–1319 (2013)

    Article  CAS  Google Scholar 

  3. X. Han, Z. Wang, Q. Zhang, J. Pu, A simple and efficient method to fabricate superhydrophobic wood with enhanced mechanical durability. Forests 10(9), 750 (2019)

    Article  Google Scholar 

  4. B. Bhushan, Biomimetics: lessons from nature—an overview. Philos. Trans. R. Soc. A Math. Phys. Eng. Sci. 2009(367), 1445–1486 (1893)

    Google Scholar 

  5. M. Ma, R.M. Hill, Superhydrophobic surfaces. Curr. Opin. Colloid Interface Sci. 11(4), 193–202 (2006)

    Article  CAS  Google Scholar 

  6. B.K. Tudu, V. Gupta, A. Kumar, A. Sinhamahapatra, Freshwater production via efficient oil-water separation and solar-assisted water evaporation using black titanium oxide nanoparticles. J. Colloid Interface Sci. 566, 183–193 (2020)

    Article  CAS  PubMed  Google Scholar 

  7. B. K. Tudu, A. Kumar, B. Bhushan, Facile approach to develop anti-corrosive superhydrophobic aluminium with high mechanical, chemical and thermal durability. Philos. Trans. R. Soc. A Math. Phys. Eng. Sci. 377(2138), 20180272 (2019)

  8. P. Chauhan, A. Kumar, Development of a microbial coating for cellulosic surface using Aloe vera and Silane. Carbohydr. Polym. Technol. Appl. 1, 100015 (2020)

    Google Scholar 

  9. S.H. Kim, Fabrication of superhydrophobic surfaces. J. Adhes. Sci. Technol. 22(3–4), 235–250 (2008)

    Article  CAS  Google Scholar 

  10. J. Jeevahan, M. Chandrasekaran, G. Britto Joseph, R.B. Durairaj, G. Mageshwaran, Superhydrophobic surfaces: a review on fundamentals, applications, and challenges. J. Coatings Technol. Res. 15(2), 231–250 (2018)

    Article  CAS  Google Scholar 

  11. Z. Chen, X. Su, W. Wu, S. Chen, X. Zhang, Y. Wu, H. Xie, K. Li, Superhydrophobic PDMS@TiO2 wood for photocatalytic degradation and rapid oil-water separation. Surf. Coatings Technol. 434, 128182 (2022)

    Article  CAS  Google Scholar 

  12. J. Ou, G. Zhao, F. Wang, W. Li, S. Lei, X. Fang, A.R. Siddiqui, Y. Xia, A. Amirfazli, Durable superhydrophobic wood via one-step immersion in composite silane solution. ACS Omega 6(11), 7266–7274 (2021)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  13. Q. Lu, R. Cheng, H. Jiang, S. Xia, K. Zhan, T. Yi, J.J. Morrell, L. Yang, H. Wan, G. Du, W. Gao, Superhydrophobic wood fabricated by epoxy/Cu2(OH)3Cl NPs/stearic acid with performance of desirable self-cleaning, anti-mold, dimensional stability, mechanical and chemical durability. Colloids Surf A Physicochem Eng Asp 647(May), 129162 (2022)

    Article  CAS  Google Scholar 

  14. F.G. Adamopoulos, E.C. Vouvoudi, D.S. Achilias, I. Karapanagiotis, Fluorosilane water-repellent coating for the protection of marble, wood and other materials. Heritage 4(4), 2668–2675 (2021)

    Article  Google Scholar 

  15. S.K. Pandit, B.K. Tudu, I.M. Mishra, A. Kumar, Development of stain resistant, superhydrophobic and self-cleaning coating on wood surface. Prog. Org. Coatings 139, 105453 (2020)

    Article  CAS  Google Scholar 

  16. S. Jia, M. Liu, Y. Wu, S. Luo, Y. Qing, H. Chen, Facile and scalable preparation of highly wear-resistance superhydrophobic surface on wood substrates using silica nanoparticles modified by VTES. Appl. Surf. Sci. 386, 115–124 (2016)

    Article  CAS  Google Scholar 

  17. S. M. Shah, U. Zulfiqar, S. Z. Hussain, I. Ahmad, Habib-ur-Rehman, I. Hussain, T. Subhani, A durable superhydrophobic coating for the protection of wood materials. Mater Lett. 203, 17–20 (2017)

  18. M. Xia, T. Yang, S. Chen, G. Yuan, Fabrication of superhydrophobic Eucalyptus wood surface with self-cleaning performance in air and oil environment and high durability. Colloids Interface Sci. Commun. 36, 100264 (2020)

    Article  CAS  Google Scholar 

  19. A. Kumar, B.K. Tudu, S.K. Pandit, Development of novel anti-wetting coating on cellulosic surface using low carbon butyric acid. Cellulose 28, 4825–4834 (2021)

    Article  CAS  Google Scholar 

  20. S.A. Kulkarni, S.B. Ogale, K.P. Vijayamohanan, Tuning the hydrophobic properties of silica particles by surface silanization using mixed self-assembled monolayers. J. Colloid Interface Sci. 318(2), 372–379 (2008)

    Article  CAS  PubMed  Google Scholar 

  21. J. Sagiv, Organized monolayers by adsorption. 1. Formation and structure of oleophobic mixed monolayers on solid surfaces. J. Am. Chem. Soc. 102(1), 92–98 (1980)

    Article  CAS  Google Scholar 

  22. X. Yang, H. Wang, P. Wang, X. Yang, H. Mao, Thermal stability of octadecyltrichlorosilane and perfluorooctyltriethoxysilane monolayers on SiO2. Nanomaterials 10(2), 210 (2020)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  23. S. Sinha, C.H. Wang, M. Mukherjee, Rubrene on differently treated SiO2/Si substrates: a comparative study by atomic force microscopy, x-ray absorption and photoemission spectroscopies techniques. Thin Solid Films 638, 167–172 (2017)

    Article  CAS  Google Scholar 

  24. Z.G. Bai, Y.Y. Bai, G.P. Zhang, S.Q. Wang, B. Zhang, A hydrogen bond based self-healing superhydrophobic octadecyltriethoxysilane−lignocellulose/silica coating. Prog. Org. Coatings 2021(151), 106104 (2020)

    Google Scholar 

  25. T. Oh, W. K. Jong, Study on the interfacial properties at the OTS treated SiO2 film. Proceedings of the 2008 International Conference on Condition Monitoring and Diagnosis, C, vol. 2007 (2008), pp 276–279

  26. L.A. Beneditt-Jimenez, N.A. Ulloa-Castillo, J. Iturbe-Ek, O. Martínez-Romero, A. Elías-Zúñiga, A.O. Sustaita, A hybrid superhydrophobic/hydrophilic surface based on SiO2 nanoparticles over a clay substrate for enhanced dew yield potential. Appl. Sci. 12(3), 1526 (2022)

    Article  CAS  Google Scholar 

  27. J.X.H. Wong, H.Z. Yu, Preparation of transparent superhydrophobic glass slides: demonstration of surface chemistry characteristics. J. Chem. Educ. 90(9), 1203–1206 (2013)

    Article  CAS  Google Scholar 

  28. I.M. Hauner, A. Deblais, J.K. Beattie, H. Kellay, D. Bonn, The dynamic surface tension of water. J. Phys. Chem. 8, 1599–1603 (2017)

    CAS  Google Scholar 

  29. C.H. Whitnah, The surface tension of milk. A review. J. Dairy Sci. 42, 1437–1449 (1959)

    Article  CAS  Google Scholar 

  30. S.S. Yadav, B.S. Sikarwar, P. Ranjan, R. Janardhanan, A. Goyal, Surface tension measurement of normal human blood samples by pendant drop method. J. Med. Eng. Technol. 44, 227–236 (2020)

    Article  PubMed  Google Scholar 

  31. E.A. Thomas, D.H. Poritz, D.L. Muirhead, Urine advancing contact angle on several surfaces. J. Adhes. Sci. Technol. 23, 1917–1923 (2009)

    Article  CAS  Google Scholar 

  32. S. Gittings, N. Turnbull, B. Henry, C.J. Roberts, P. Gershkovich, Characterisation of human saliva as a platform for oral dissolution medium development. Eur. J. Pharm. Biopharm. 91, 16–24 (2015)

    Article  CAS  PubMed  Google Scholar 

  33. K. Takamura, H. Fischer, N.R. Morrow, Physical properties of aqueous glycerol solutions. J. Petrol. Sci. Eng. 98–99, 56–60 (2012)

    Google Scholar 

  34. C. Qi, H. Chen, Y. Sun, Q. Fu, L. Shen, X. Li, Y. Liu, Facile synthesis and anti-icing performance of superhydrophobic flower-like OTS-SiO2 with tunable size. Adv. Powder Technol. 31(11), 4533–4540 (2020)

    Article  CAS  Google Scholar 

  35. D. Nanda, P. Varshney, M. Satapathy, S.S. Mohapatra, A. Kumar, Self-assembled monolayer of functionalized silica microparticles for self-cleaning applications. Colloids Surf A Physicochem Eng Asp 529, 231–238 (2017)

    Article  CAS  Google Scholar 

  36. T.V. Duncan, Release of engineered nanomaterials from polymer nanocomposites: the effect of matrix degradation. ACS Appl. Mater. Interfaces 7(1), 20–39 (2015)

    Article  CAS  PubMed  Google Scholar 

  37. I.S. Bayer, A.J. Davis, E. Loth, A. Steele, Water jet resistant superhydrophobic carbonaceous films by flame synthesis and tribocharging. Mater. Today Commun. 3, 57–68 (2015)

    Article  CAS  Google Scholar 

  38. V.A. Ganesh, H.K. Raut, A.S. Nair, S. Ramakrishna, A review on self-cleaning coatings. J. Mater. Chem. 21(41), 16304–16322 (2011)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work made use of the Indian Institute of Technology (ISM), Dhanbad facilities.

Funding

The authors receive no financial support for the research, authorship, and/or publication of this article.

Author information

Authors and Affiliations

Authors

Contributions

All authors have equal contribution.

Corresponding author

Correspondence to Aditya Kumar.

Ethics declarations

Conflict of interest

The authors declare no conflict of interest.

Ethical approval

Not applicable.

Consent to participate

Not applicable.

Consent for publication

The authors give their consent for the publication of identifiable details, which include photographs and details within the text to be published in the “Cellulose” Journal and Article.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (DOCX 105 KB)

Supplementary file2 (MP4 21309 KB)

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gururani, R., Pandit, S.K., Kumari, P. et al. Towards the Development of One-Step Scalable Self-Cleaning and Stain-Resistant Coating on Cellulosic Wood. Fibers Polym 25, 1779–1788 (2024). https://doi.org/10.1007/s12221-024-00556-x

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12221-024-00556-x

Keywords

Navigation