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A Study of the Thermal Properties of Main-Chain Polybenzoxazines Copolymerized with Nitrile-Benzoxazine

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Abstract

Main-chain benzoxazine has great potential for a number of fields, particularly fiber chemistry, due to its flexibility in molecular design and viscosity. It is expected that its thermal properties can be improved by blending with a low molecular weight benzoxazine possessing a functional group with excellent thermal properties. In this study, two types of bisphenol-A-based main-chain benzoxazine were synthesized, using aliphatic and aromatic diamine and o-aminobenzonitrile benzoxazine, then blended. Their thermal properties were investigated through FT-IR, DSC, and TGA. The copolybenzoxazine that comprised main-chain benzoxazine with aromatic diamine and o-aminobenzonitrile benzoxazine showed improved thermal stability over a low-temperature range and demonstrated a synergistic effect on char yield.

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References

  1. X. Ning, H. Ishida, J. Polym. Sci. Part A: Polym. Chem. 32, 1121 (1994)

    Article  CAS  Google Scholar 

  2. H. Ishida, T. Agag, “Handbook of benzoxazine resins”, 1st Ed., pp.3–14, Elsevier, Netherlands, 2011.

  3. Y. Yagci, B. Kiskan, N.N. Ghosh, J. Polym. Sci. Part A: Polym. Chem. 47, 5565 (2009)

    Article  CAS  Google Scholar 

  4. B. Kiskan, N.N. Ghosh, Y. Yagci, Polym. Int. 60, 167 (2011)

    Article  CAS  Google Scholar 

  5. M.M. Khan, K. Halder, S. Shishatskiy, V. Filiz, Polym. 10, 221 (2018)

    Article  CAS  Google Scholar 

  6. T. Agag, S. Geiger, S.M. Alhassan, S. Qutubuddin, H. Ishida, Macromol. 43, 7122 (2010)

    Article  CAS  Google Scholar 

  7. T. Takeichi, T. Kano, T. Agag, Polym. 46, 12172 (2005)

    Article  CAS  Google Scholar 

  8. Y. Murai, T. Uemura, Y. Chen, T. Kawauchi, T. Takeichi, Polym. J. 53, 439 (2021)

    Article  CAS  Google Scholar 

  9. H.D. Kim, I.W. Nam, Text. Sci. Eng. 45, 166 (2008)

    CAS  Google Scholar 

  10. L. Chen, D. Ren, S. Chen, K. Li, M. Xu, X. Liu, Polym. Test. 74, 127 (2019)

    Article  CAS  Google Scholar 

  11. A.Q. Dayo, M. Derradji, J. Wang, W.B. Liu, S. Song, T. Tang, React. Funct. Polym. 123, 97 (2018)

    Article  Google Scholar 

  12. X. Li, Y. Xia, W. Xu, Q. Ran, Y. Gu, Polym. Chem. 3, 1629 (2012)

    Article  CAS  Google Scholar 

  13. C.H. Lin, Y.C. Chou, M.W. Wang, R.J. Jeng, RSC Adv. 6, 17539 (2016)

    Article  CAS  Google Scholar 

  14. D. Wang, B. Li, Y. Zhang, Z. Lu, J. Appl. Polym. Sci. 127, 516 (2013)

    Article  CAS  Google Scholar 

  15. M. Xu, D. Ren, L. Chen, K. Li, X. Liu, Polym. 143, 28 (2018)

    Article  CAS  Google Scholar 

  16. H. D. Kim, K. I. Jang, Korean Patent, 10-2021-0000593 (2021).

  17. H.J. Kim, Z. Brunovska, H. Ishida, Polym. 40, 6565 (1999)

    Article  CAS  Google Scholar 

  18. M. Zeng, J. Chen, Q. Xu, Y. Huang, Z. Feng, Y. Gu, Polym. Chem. 9, 2913 (2018)

    Article  CAS  Google Scholar 

  19. Q. Ran, Y. Gu, and H. Ishida in “Advanced and Emerging Polybenzoxazine Science and Technology”, 1st ed. (H. Ishida and P. Froimowicz), pp.171–204, Elsevier, 2017.

  20. K.S. Park, H.D. Kim, Text. Sci. Eng. 56, 149 (2019)

    CAS  Google Scholar 

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Acknowledgements

The present research was supported by the research fund of Dankook University in 2023.

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Author notes

  1. Minju Jang and Jin Kyung Park have contributed equally to this work.

Authors and Affiliations

  1. Department of Fiber System Engineering, Dankook University, 152 Jukjeon-Ro, Suji-Gu, Yongin, 16890, Republic of Korea

    Minju Jang, Jin Kyung Park & HoDong Kim

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  1. Minju Jang
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  2. Jin Kyung Park
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  3. HoDong Kim
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Correspondence to HoDong Kim.

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Jang, M., Park, J.K. & Kim, H. A Study of the Thermal Properties of Main-Chain Polybenzoxazines Copolymerized with Nitrile-Benzoxazine. Fibers Polym 24, 4111–4119 (2023). https://doi.org/10.1007/s12221-023-00393-4

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