Abstract
Multifunctional cotton fabrics with antibacterial property and hydrophobicity were prepared using surface modification. Cotton fabrics were treated with the coating solution containing N-halamine compound poly[5,5-dimethyl-3-(3’-triethoxysilylpropyl) hydantoin] (PSPH) and TiO2 nanoparticles, followed by treated with polydimethylsiloxane (PDMS) to reduce the surface energy of cotton fabrics. The prepared cotton fabrics were characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM), Fourier transform infrared (FT-IR) spectra, X-ray photoelectron spectroscopy (XPS), and X-ray diffractometry (XRD). After chlorination, the prepared cotton fabrics exhibited excellent hydrophobicity with contact angle of 143°. The antibacterial results demonstrated that the prepared cotton fabrics had excellent antibacterial activity and could completely inactivate 4.54 cfu/sample of S.aureus and 4.92 cfu/sample of E. coli O157:H7 within 30 min of contact. The treated cotton fabrics also possessed robust stability under washing, UV light irradiation, and abrasion. Moreover, the breaking strength and air permeability of cotton fabric could maintain to the required values for practical application after treatment.
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J. Xu, Y. Zhi, L. Chen, S. Wei, Y. Wei, J. Mater. Sci. 57, 4104 (2022)
Z. Shi, I. Wyman, G. Liu, H. Hu, H. Zou, J. Hu, Polymer 54, 6406 (2013)
Q. Qiu, C. Yang, Y. Wang, C.A. Alexander, G. Yi, Y. Zhang, X. Qin, Y. Yang, Biomaterials 284, 121470 (2022)
S. Li, X. Lin, Y. Liu, R. Li, X. Ren, T.-S. Huang, Cellulose 26, 4213 (2019)
X. Zhang, L. Wang, E. Levanen, RSC Adv. 3, 12003 (2013)
H. Liu, J. Huang, Z. Chen, G. Chen, K. Zhang, S.S. Al-Deyab, Y. Lai, Chem. Eng. J. 330, 26 (2017)
S.J. Lm, D. Kim, Y. Kim, S. Jeong, C. Pang, S. Ryu, Langmuir 36, 689 (2020)
K.S. Min, R. Manivannan, Y.-A. Son, Dyes Pigm. 162, 8 (2019)
S. Peng, W. Meng, J. Guo, B. Wang, Z. Wang, N. Xu, X. Li, J. Wang, J. Xu, Langmuir 35, 2760 (2019)
Q. Gao, Q. Zhu, Y. Guo, Ind. Eng. Chem. Res. 48, 9797 (2009)
L. Shen, H. Hu, S. Wang, H. Fu, React. Funct. Polym. 143, 1381 (2019)
Y. Jin, P. Jiang, Q. Ke, F. Cheng, Y. Zhu, Y. Zhang, J. Hazard. Mater. 300, 175 (2015)
F. Liu, M. Ma, D. Zang, Z. Gao, C. Wang, Carbohydr. Polym. 103, 480 (2014)
K. Shen, M. Yu, Q. Li, W. Sun, X. Zhang, M. Quan, Z. Liu, S. Shi, Y. Gong, Appl. Surf. Sci. 426, 694 (2017)
C.-H. Xue, S.-T. Jia, J. Zhang, L.-Q. Tian, Thin Solid Films 517, 4593 (2009)
M. Przybylak, H. Maciejewski, A. Dudkiewicz, J. Walentowska, J. Foksowicz-Flaczyk, Cellulose 25, 1483 (2018)
M. Seth, H. Khan, R. Bhowmik, S. Karmakar, S. Jana, J. Sol-Gel Sci. Technol. 94, 127 (2019)
Y.-N. Gao, Y. Wang, T.-N. Yue, Y.-X. Weng, M. Wang, J. Colloid Interface Sci. 582, 112 (2021)
C. Dong, Z. Lu, F. Zhang, P. Zhu, L. Zhang, S. Sui, Mater. Lett. 152, 276 (2015)
T. Suryaprabha, M. Sethuraman, Cellulose 24, 395 (2017)
C.-H. Xue, J. Chen, W. Yin, S.-T. Jia, J.-Z. Ma, Appl. Surf. Sci. 258, 2468 (2012)
Z. Jiang, K. Ma, J. Du, R. Li, X. Ren, T.S. Huang, Appl. Surf. Sci. 288, 518 (2014)
R. Li, M. Sun, Z. Jiang, X. Ren, T.S. Huang, Fibers Polym. 15, 234 (2014)
X. Ren, H.B. Kocer, S.D. Worley, R.M. Broughton, T.S. Huang, Carbohydr. Polym. 75, 683 (2009)
W. Ma, J. Li, Y. Liu, X. Ren, Z.-G. Gu, Z. Xie and J. Liang, Colloids Surf., A, 506, 284 (2016).
Y. Wang, L. Li, Y. Liu, X. Ren and J. Liang, Mater. Sci. Eng., C, 69, 1075 (2016).
Y. Liu, K. Ma, R. Li, X. Ren, T.S. Huang, Cellulose 20, 3123 (2013)
C. Cao, M. Ge, J. Huang, S. Li, S. Deng, S. Zhang, Z. Chen, K. Zhang, S.S. Al-Deyab, Y. Lai, J. Mater. Chem. A 4, 12179 (2016)
X. Lin, M. Yin, Y. Liu, L. Li, X. Ren, Y. Sun, T.-S. Huang, J. Ind. Eng. Chem. 63, 303 (2018)
R. Li, P. Hu, X. Ren, S.D. Worley, T.S. Huang, Carbohydr. Polym. 92, 534 (2013)
K. Ma, Y. Liu, Z. Xie, R. Li, Z. Jiang, X. Ren, T.-S. Huang, Ind. Eng. Chem. Res. 52, 7413 (2013)
T. Mu, N. Pan, Y. Wang, X. Ren, T.-S. Huang, Fibers Polym. 19, 2284 (2018)
M. Zhang, C. Wang, S. Wang, J. Li, Carbohydr. Polym. 97, 59 (2013)
N. Pan, Y. Liu, X. Fan, Z. Jiang, X. Ren, J. Liang, J. Mater. Sci. 52, 1996 (2016)
L.J. Bastarrachea, J.M. Goddard, J. Appl. Polym. Sci. 127, 821 (2013)
Z. Jiang, X. Dai and H. Middleton, Mater. Sci. Eng., B, 176, 79 (2011).
J. Li, Y. Liu, Z. Jiang, K. Ma, X. Ren, T.-S. Huang, Ind. Eng. Chem. Res. 53, 13058 (2014)
Q. Qu, H. Geng, R. Peng, Q. Cui, X. Gu, F. Li, M. Wang, Langmuir 26, 9539 (2010)
Y. Wang, M. Yin, X. Lin, L. Li, Z. Li, X. Ren, Y. Sun, J. Colloid Interface Sci. 533, 604 (2019)
M. Qiao, Q. Liu, Y. Yong, Y. Pardo, R. Worobo, Z. Liu, S. Jiang, M. Ma, J. Agric. Food Chem. 66, 11441 (2018)
N. Ghasemi, J. Seyfi, M.J. Asadollahzadeh, Cellulose 25, 4211 (2018)
Z. He, B. Bao, J. Fan, W. Wang and D. Yu, Colloids Surf., A, 594, 124661 (2020).
A. Dong, Y.-J. Wang, Y. Gao, T. Gao, G. Gao, Chem. Rev. 117, 4806 (2017)
L. Kou, J. Liang, X. Ren, H. B. Kocer, S. D. Worley, R. M. Broughton and T. S. Huang, Colloids Surf., A, 345, 88 (2009).
L. Li, W. Ma, J. Ding, R. Li, X. Ren, Z. Gu, Y. Sun, Polym.-Plast. Technol. Mater. 59, 1585 (2020)
T. Zhu, S. Li, J. Huang, M. Mihailiasa, Y. Lai, Mater. Des. 134, 342 (2017)
C. Li, Z. Li and X. Ren, Colloids Surf., A, 577, 695 (2019).
Z. Jiang, Y. Liu, R. Li, X. Ren, T.S. Huang, Polym. Adv. Technol. 27, 460 (2016)
L. Zhou, H. Wang, J. Du, J. Fu, W. Wang, Fibers Polym. 19, 1228 (2018)
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This work is financially supported by the National Natural Science Foundation of China (21706093).
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Qian, F., Chen, M., Li, Z. et al. Fabrication of Stable Fluorine-Free Hydrophobic Cotton Fabrics with Prominent Antibacterial Property. Fibers Polym 24, 3869–3877 (2023). https://doi.org/10.1007/s12221-023-00362-x
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DOI: https://doi.org/10.1007/s12221-023-00362-x