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Fabrication of Stable Fluorine-Free Hydrophobic Cotton Fabrics with Prominent Antibacterial Property

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Abstract

Multifunctional cotton fabrics with antibacterial property and hydrophobicity were prepared using surface modification. Cotton fabrics were treated with the coating solution containing N-halamine compound poly[5,5-dimethyl-3-(3’-triethoxysilylpropyl) hydantoin] (PSPH) and TiO2 nanoparticles, followed by treated with polydimethylsiloxane (PDMS) to reduce the surface energy of cotton fabrics. The prepared cotton fabrics were characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM), Fourier transform infrared (FT-IR) spectra, X-ray photoelectron spectroscopy (XPS), and X-ray diffractometry (XRD). After chlorination, the prepared cotton fabrics exhibited excellent hydrophobicity with contact angle of 143°. The antibacterial results demonstrated that the prepared cotton fabrics had excellent antibacterial activity and could completely inactivate 4.54 cfu/sample of S.aureus and 4.92 cfu/sample of E. coli O157:H7 within 30 min of contact. The treated cotton fabrics also possessed robust stability under washing, UV light irradiation, and abrasion. Moreover, the breaking strength and air permeability of cotton fabric could maintain to the required values for practical application after treatment.

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References

  1. J. Xu, Y. Zhi, L. Chen, S. Wei, Y. Wei, J. Mater. Sci. 57, 4104 (2022)

    Article  CAS  Google Scholar 

  2. Z. Shi, I. Wyman, G. Liu, H. Hu, H. Zou, J. Hu, Polymer 54, 6406 (2013)

    Article  CAS  Google Scholar 

  3. Q. Qiu, C. Yang, Y. Wang, C.A. Alexander, G. Yi, Y. Zhang, X. Qin, Y. Yang, Biomaterials 284, 121470 (2022)

    Article  CAS  PubMed  Google Scholar 

  4. S. Li, X. Lin, Y. Liu, R. Li, X. Ren, T.-S. Huang, Cellulose 26, 4213 (2019)

    Article  CAS  Google Scholar 

  5. X. Zhang, L. Wang, E. Levanen, RSC Adv. 3, 12003 (2013)

    Article  CAS  Google Scholar 

  6. H. Liu, J. Huang, Z. Chen, G. Chen, K. Zhang, S.S. Al-Deyab, Y. Lai, Chem. Eng. J. 330, 26 (2017)

    Article  CAS  Google Scholar 

  7. S.J. Lm, D. Kim, Y. Kim, S. Jeong, C. Pang, S. Ryu, Langmuir 36, 689 (2020)

    Article  CAS  PubMed  Google Scholar 

  8. K.S. Min, R. Manivannan, Y.-A. Son, Dyes Pigm. 162, 8 (2019)

    Article  CAS  Google Scholar 

  9. S. Peng, W. Meng, J. Guo, B. Wang, Z. Wang, N. Xu, X. Li, J. Wang, J. Xu, Langmuir 35, 2760 (2019)

    Article  CAS  PubMed  Google Scholar 

  10. Q. Gao, Q. Zhu, Y. Guo, Ind. Eng. Chem. Res. 48, 9797 (2009)

    Article  CAS  Google Scholar 

  11. L. Shen, H. Hu, S. Wang, H. Fu, React. Funct. Polym. 143, 1381 (2019)

    Article  Google Scholar 

  12. Y. Jin, P. Jiang, Q. Ke, F. Cheng, Y. Zhu, Y. Zhang, J. Hazard. Mater. 300, 175 (2015)

    Article  CAS  PubMed  Google Scholar 

  13. F. Liu, M. Ma, D. Zang, Z. Gao, C. Wang, Carbohydr. Polym. 103, 480 (2014)

    Article  CAS  PubMed  Google Scholar 

  14. K. Shen, M. Yu, Q. Li, W. Sun, X. Zhang, M. Quan, Z. Liu, S. Shi, Y. Gong, Appl. Surf. Sci. 426, 694 (2017)

    Article  CAS  Google Scholar 

  15. C.-H. Xue, S.-T. Jia, J. Zhang, L.-Q. Tian, Thin Solid Films 517, 4593 (2009)

    Article  CAS  Google Scholar 

  16. M. Przybylak, H. Maciejewski, A. Dudkiewicz, J. Walentowska, J. Foksowicz-Flaczyk, Cellulose 25, 1483 (2018)

    Article  CAS  Google Scholar 

  17. M. Seth, H. Khan, R. Bhowmik, S. Karmakar, S. Jana, J. Sol-Gel Sci. Technol. 94, 127 (2019)

    Article  Google Scholar 

  18. Y.-N. Gao, Y. Wang, T.-N. Yue, Y.-X. Weng, M. Wang, J. Colloid Interface Sci. 582, 112 (2021)

    Article  CAS  PubMed  Google Scholar 

  19. C. Dong, Z. Lu, F. Zhang, P. Zhu, L. Zhang, S. Sui, Mater. Lett. 152, 276 (2015)

    Article  CAS  Google Scholar 

  20. T. Suryaprabha, M. Sethuraman, Cellulose 24, 395 (2017)

    Article  CAS  Google Scholar 

  21. C.-H. Xue, J. Chen, W. Yin, S.-T. Jia, J.-Z. Ma, Appl. Surf. Sci. 258, 2468 (2012)

    Article  CAS  Google Scholar 

  22. Z. Jiang, K. Ma, J. Du, R. Li, X. Ren, T.S. Huang, Appl. Surf. Sci. 288, 518 (2014)

    Article  CAS  Google Scholar 

  23. R. Li, M. Sun, Z. Jiang, X. Ren, T.S. Huang, Fibers Polym. 15, 234 (2014)

    Article  CAS  Google Scholar 

  24. X. Ren, H.B. Kocer, S.D. Worley, R.M. Broughton, T.S. Huang, Carbohydr. Polym. 75, 683 (2009)

    Article  CAS  Google Scholar 

  25. W. Ma, J. Li, Y. Liu, X. Ren, Z.-G. Gu, Z. Xie and J. Liang, Colloids Surf., A, 506, 284 (2016).

  26. Y. Wang, L. Li, Y. Liu, X. Ren and J. Liang, Mater. Sci. Eng., C, 69, 1075 (2016).

  27. Y. Liu, K. Ma, R. Li, X. Ren, T.S. Huang, Cellulose 20, 3123 (2013)

    Article  CAS  Google Scholar 

  28. C. Cao, M. Ge, J. Huang, S. Li, S. Deng, S. Zhang, Z. Chen, K. Zhang, S.S. Al-Deyab, Y. Lai, J. Mater. Chem. A 4, 12179 (2016)

    Article  CAS  Google Scholar 

  29. X. Lin, M. Yin, Y. Liu, L. Li, X. Ren, Y. Sun, T.-S. Huang, J. Ind. Eng. Chem. 63, 303 (2018)

    Article  CAS  Google Scholar 

  30. R. Li, P. Hu, X. Ren, S.D. Worley, T.S. Huang, Carbohydr. Polym. 92, 534 (2013)

    Article  CAS  PubMed  Google Scholar 

  31. K. Ma, Y. Liu, Z. Xie, R. Li, Z. Jiang, X. Ren, T.-S. Huang, Ind. Eng. Chem. Res. 52, 7413 (2013)

    Article  CAS  Google Scholar 

  32. T. Mu, N. Pan, Y. Wang, X. Ren, T.-S. Huang, Fibers Polym. 19, 2284 (2018)

    Article  CAS  Google Scholar 

  33. M. Zhang, C. Wang, S. Wang, J. Li, Carbohydr. Polym. 97, 59 (2013)

    Article  CAS  PubMed  Google Scholar 

  34. N. Pan, Y. Liu, X. Fan, Z. Jiang, X. Ren, J. Liang, J. Mater. Sci. 52, 1996 (2016)

    Article  Google Scholar 

  35. L.J. Bastarrachea, J.M. Goddard, J. Appl. Polym. Sci. 127, 821 (2013)

    Article  CAS  Google Scholar 

  36. Z. Jiang, X. Dai and H. Middleton, Mater. Sci. Eng., B, 176, 79 (2011).

  37. J. Li, Y. Liu, Z. Jiang, K. Ma, X. Ren, T.-S. Huang, Ind. Eng. Chem. Res. 53, 13058 (2014)

    Article  CAS  Google Scholar 

  38. Q. Qu, H. Geng, R. Peng, Q. Cui, X. Gu, F. Li, M. Wang, Langmuir 26, 9539 (2010)

    Article  CAS  PubMed  Google Scholar 

  39. Y. Wang, M. Yin, X. Lin, L. Li, Z. Li, X. Ren, Y. Sun, J. Colloid Interface Sci. 533, 604 (2019)

    Article  CAS  PubMed  Google Scholar 

  40. M. Qiao, Q. Liu, Y. Yong, Y. Pardo, R. Worobo, Z. Liu, S. Jiang, M. Ma, J. Agric. Food Chem. 66, 11441 (2018)

    Article  CAS  PubMed  Google Scholar 

  41. N. Ghasemi, J. Seyfi, M.J. Asadollahzadeh, Cellulose 25, 4211 (2018)

    Article  CAS  Google Scholar 

  42. Z. He, B. Bao, J. Fan, W. Wang and D. Yu, Colloids Surf., A, 594, 124661 (2020).

  43. A. Dong, Y.-J. Wang, Y. Gao, T. Gao, G. Gao, Chem. Rev. 117, 4806 (2017)

    Article  CAS  PubMed  Google Scholar 

  44. L. Kou, J. Liang, X. Ren, H. B. Kocer, S. D. Worley, R. M. Broughton and T. S. Huang, Colloids Surf., A, 345, 88 (2009).

  45. L. Li, W. Ma, J. Ding, R. Li, X. Ren, Z. Gu, Y. Sun, Polym.-Plast. Technol. Mater. 59, 1585 (2020)

    CAS  Google Scholar 

  46. T. Zhu, S. Li, J. Huang, M. Mihailiasa, Y. Lai, Mater. Des. 134, 342 (2017)

    Article  CAS  Google Scholar 

  47. C. Li, Z. Li and X. Ren, Colloids Surf., A, 577, 695 (2019).

  48. Z. Jiang, Y. Liu, R. Li, X. Ren, T.S. Huang, Polym. Adv. Technol. 27, 460 (2016)

    Article  Google Scholar 

  49. L. Zhou, H. Wang, J. Du, J. Fu, W. Wang, Fibers Polym. 19, 1228 (2018)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work is financially supported by the National Natural Science Foundation of China (21706093).

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Correspondence to Rong Li.

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Qian, F., Chen, M., Li, Z. et al. Fabrication of Stable Fluorine-Free Hydrophobic Cotton Fabrics with Prominent Antibacterial Property. Fibers Polym 24, 3869–3877 (2023). https://doi.org/10.1007/s12221-023-00362-x

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  • DOI: https://doi.org/10.1007/s12221-023-00362-x

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