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An Investigation on Thermal Decomposition Behavior of Water-Soluble Azo Dyes

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Abstract

In order to investigate the thermal decomposition behavior of water-soluble azo dyes, a series of structurally isomeric water-soluble hydroxyl azo dyes were synthesized and their thermal decomposition phenomena were examined using TGA and DSC. Their thermal decomposition mechanism was also studied by measuring UV–Vis absorbance of the prepared dyes at various heating temperatures. From thermal analysis and spectroscopy, we found that the dyes decomposed gradually without a melting process, and those with strong inter-molecular interactions had high decomposition temperatures. Moreover, we suggested a new thermal decomposition mechanism different from that of the water-insoluble dye, in which dye molecules rapidly decomposed within a narrow temperature range following a melting process. We also found that dyes with stronger inter-molecular interactions had higher degradation temperatures using density analysis, X-ray diffraction (XRD), dynamic light scattering (DLS), and density functional theory (DFT) calculation.

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The datasets generated during the current study can be requested from the corresponding author upon reasonable request.

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Authors and Affiliations

  1. Samsung Display Co., Ltd., Cheonan, 31086, Republic of Korea

    Young Do Kim

  2. Department of Fiber System Engineering, Dankook University, Yongin, 16890, Republic of Korea

    Jung Jin Lee

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  1. Young Do Kim
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  2. Jung Jin Lee
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Correspondence to Jung Jin Lee.

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Kim, Y.D., Lee, J.J. An Investigation on Thermal Decomposition Behavior of Water-Soluble Azo Dyes. Fibers Polym 24, 2799–2806 (2023). https://doi.org/10.1007/s12221-023-00275-9

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