Abstract
Chitosan oligosaccharide (COS) was utilized to simultaneously dye and functionally modify wool fabrics with antibacterial activity via Maillard reaction in this work. Sodium dodecyl sulfate polyacrylamide gel electrophoresis (SDS-PAGE) and infrared spectrometer (IR) were used to demonstrate the reaction between COS and wool keratin. The results verified the formation of new keratin–COS conjugates with higher molecular weight. Time, pH and temperature of the reaction had a great effect on the color strength (K/S) of the dyed wool fabrics caused by maillard browning. The affinity of COS to the wool could be improved significantly and the color depth of the dyed fabric increased accordingly when the fabrics were pretreated with different agents (H2O2, mercaptoethanol or protease). In the meantime, the dyed fabrics showed promising antibacterial capacity against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) in addition to good color fastness.
Similar content being viewed by others
Data availability
The data that support the findings of this study are available from the corresponding author upon reasonable request.
References
S. Shahidi, M. Ghoranneviss, S. Dalalsharifi, J. Text. Inst. 106, 1127 (2015)
M. Montazer, A. Mozaffari, F. Alimohammadi, Fiber Text. East Eur. 232, 100 (2015)
D.K. Ravindra, A. Arunabh, S.J. Priyanka, Adv. Appl. Sci. Res. 7, 116 (2016)
Z. Mohammadkhodaei, J. Mokhtari, M. Nouri, Color. Technol. 126, 81 (2010)
R. Farouk, H.E. Gaffer, Carbohyd. Polym. 97, 138 (2013)
S. Safapour, M. Sadeghi-Kiakhani, S. Eshaghloo-Galugahi, Fiber. Polym. 19, 1428 (2018)
L. Chakraborty, P. Pandit, S.R. Maulik, J. Clean Prod. 245, 1 (2020)
M.D. Teli, P. Pandit, A.C.S. Sustain, Chem. Eng. 5, 323 (2017)
F.S. Ghaheh, S.M. Mortazavi, F. Alihosseini, A. Fassihi, A.S. Nateri, D. Abedi, J. Clean Prod. 72, 139 (2014)
T. Ohe, K. Moriyoshi, T. Ohmoto, Y. Yoshimura, J. Fiber Sci. Technol. 73, 34 (2017)
T. Ohe, Y. Yoshimura, J. Fiber Sci. Technol. 74, 229 (2018)
T. Ohe, Y. Yoshimura, J. Fiber Sci. Technol. 76, 127 (2020)
L. Cui, J. Yuan, P. Wang, X.P. Wang, X. Fan, Q. Wang, J. Clean Prod. 178, 611 (2018)
T. Ohe, T. Nakai, Y. Yoshimura, Text. Res. J. 20, 2216 (2016)
T. Ohe, Y. Yoshimura, Text. Res. J. 84, 539 (2014)
J.H. Li, X. Tian, T. Hua, J.M. Fu, M.K. Koo, W. Chan, T. Poon, ACS Appl. Bio. Mater. 4, 4014 (2021)
K.M. Mostafa, H.A. Ameen, J. Nat. Fibers 19, 13167 (2022)
K. Mostafa, A. El-Sanabary, Pigm. Resin Technol. 49, 11 (2020)
B. Miralles, A. Martínez-Rodríguez, A. Santiago, J. Van de Lagemaat, A. Heras, Food Chem. 100, 1071 (2007)
Y. Song, E.E. Babiker, M. Usui, A. Saito, A. Kato, Food Res. Int. 35, 459 (2002)
Z.Z. Xu, G.Q. Huang, T.C. Xu, L.N. Liu, J.X. Xiao, Int. J. Biol. Macromol. 131, 601 (2019)
M. Mengíbar, B. Miralles, Á. Heras, LWT Food Sci. Technol. 75, 440 (2017)
G.L. Miller, Anal. Chem. 31, 426 (1959)
P. Kubelka, Part I. JOSA 38, 448 (1948)
J.S. Kim, Y.S. Lee, Food Chem. 116, 227 (2009)
Y. Yu, Q. Wang, J. Yuan, X. Fan, P. Wang, Carbohyd. Polym. 153, 463 (2016)
X. Wang, G.Y. Cao, W.L. Xu, J. Appl. Polym. Sci. 112, 1959 (2009)
P. Wang, Q. Wang, L. Cui, M. Gao, X. Fan, Fiber. Polym. 12, 760 (2011)
V. Dev, J. Venugopal, S. Sudha, G. Deepika, S. Ramakrishna, Carbohydr. Polym. 75, 646 (2009)
M. Hosseinnezhad, K. Gharanjig, N. Razani, H. Imani, Fiber. Polym. 21, 2036 (2020)
Acknowledgements
This project was financially supported by the National Natural Science Foundation of China (Grant No. 22178145).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of Interest
The authors report no conflicts of interest. The authors alone are responsible for the content and writing of the paper.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Cui, L., Guan, R., Meng, Y. et al. Simultaneous Coloration and Antibacterial Modification of Wool Fabric with Chitosan Oligosaccharide via Maillard Reaction. Fibers Polym 24, 1941–1949 (2023). https://doi.org/10.1007/s12221-023-00233-5
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12221-023-00233-5