Abstract
The self-healing application in structural composites aims to recover component properties, control damage propagation, and increase component life. In this way, this study proposes to characterize and predict the inter-laminar shear behavior of polymer composites (5HS carbon/epoxy) with different fractions of self-healing agent. In addition, this work aims to measure the influence of self-healing content on the mechanical response. The ANOVA evidenced that the healing agent fraction influences on mechanical properties more than the internal dispersion for the same laminate before the healing cycle. Weibull distribution evidenced a linear decrease in shear stresses for higher EMAA (poly(ethylene-co-methacrylic acid)) content, regarding stiffness decrease as a response to ductile thermoplastic behavior. Ineffective healing effects were observed for the translaminar and intra-laminar damage, once most particles were concentrated in inter-laminar sections. However, the healing efficiency reached an average of 62% for shear stress and 106% for toughness behavior, provided by the closing shear cracks, i.e., up to 57% of reduced area related to the initial crack size. The predictive approach before and after healing action in the mechanical behavior provides the appropriate self-healing level to meet the specific project requirements, thus saving time and cost.
Similar content being viewed by others
Data availability
The datasets generated during the current study are available from the corresponding author upon request.
References
V. Mathes, The composites industry: plenty of opportunities in heterogeneous market. Reinf. Plast. 62, 44–51 (2018). https://doi.org/10.1016/j.repl.2017.05.002
A.H.S. dos Souza, G.A. Batista, L. Figueiredo, P.V.C.C.M. de Valvazori, Y. Mihara, M.S. Amarante, Composite materials in aeronautics: an analysis of trends in the fuselation of aircraft. Pesqui Em Ação 4, 240–246 (2018)
B. Lu, The boeing 787 dreamliner: designing an aircraft for the future. J. Young Investig. 1, 1–4 (2010)
S. Georgiadis, A.J. Gunnion, R.S. Thomson, B.K. Cartwright, Bird-strike simulation for certification of the Boeing 787 composite moveable trailing edge. Compos. Struct. 86, 258–268 (2008). https://doi.org/10.1016/j.compstruct.2008.03.025
Clarke M, Smart J, Botero E, Maier W, Alonso JJ. Strategies for posing a well-defined problem for urban air mobility vehicles. AIAA Scitech (2019). Pp. 1–14. https://doi.org/10.2514/6.2019-0818.
T. Donateo, A. Ficarella, A modeling approach for the effect of battery aging on the performance of a hybrid electric rotorcraft for urban air-mobility. Aerospace 7, 56 (2020). https://doi.org/10.3390/AEROSPACE7050056
V. Kostopoulos, A. Kotrotsos, A. Sousanis, G. Sotiriadis, Fatigue behaviour of open-hole carbon fibre/epoxy composites containing bis-maleimide based polymer blend interleaves as self-healing agent. Compos. Sci. Technol. 171, 86–93 (2019). https://doi.org/10.1016/j.compscitech.2018.12.013
K. Pingkarawat, C.H. Wang, R.J. Varley, A.P. Mouritz, Self-healing of delamination fatigue cracks in carbon fibre-epoxy laminate using mendable thermoplastic. J. Mater. Sci. 47, 4449–4456 (2012). https://doi.org/10.1007/s10853-012-6303-8
Q. Ma, hua, Dong F, Gan X hui, Zhou T., Effects of different interface conditions on energy absorption characteristics of Al/carbon fiber reinforced polymer hybrid structures for multiple loading conditions. Polym. Compos. 42, 2838–2863 (2021). https://doi.org/10.1002/pc.26019
Y. Zhan, Q. Ma, X. Gan, M. Cai, T. Zhou, Deformation and energy absorption characters of Al-CFRP hybrid tubes under quasi-static. Polym. Compos. 41, 4602–4618 (2020)
M. Qi-hua, D. Fan, G. Xue-hui, Z. Tianjun, Crashworthiness design of gradient bionic Al/CFRP hybrid tubes under multiple loading conditions. Mech. Adv. Mater. Struct. 1, 1–18 (2022)
A. Azevedo do Nascimento, F. Fernandez, S. da Silva, P.C.E. Ferreira, J.D. José, A.P. Cysne Barbosa, Addition of poly (ethylene-co-methacrylic acid) (EMAA) as self-healing agent to carbon-epoxy composites. Compos. Part A Appl. Sci. Manuf. 137, 106016 (2020). https://doi.org/10.1016/j.compositesa.2020.106016
D.G. Bekas, K. Tsirka, D. Baltzis, A.S. Paipetis, Self-healing materials : A review of advances in materials, evaluation, characterization and monitoring techniques. Compos. Part B 87, 92–119 (2016). https://doi.org/10.1016/j.compositesb.2015.09.057
B.M.D. Hager, P. Greil, C. Leyens, Z.S. Van Der, U.S. Schubert, Self-healing materials. Adv. Mater. 22, 5424–5430 (2010)
R.P. Wool, Self-healing materials : a review. Soft Matter 4, 400 (2008). https://doi.org/10.1039/b711716g
M.R. Kessler, S.R. White, Self-activated healing of delamination damage in woven composites. Compos. Part A Appl. Sci. Manuf. 32, 683–699 (2001). https://doi.org/10.1016/S1359-835X(00)00149-4
R.B. Ladani, C.H. Wang, A.P. Mouritz, Delamination fatigue resistant three-dimensional textile self-healing composites. Compos. Part A Appl. Sci. Manuf. 127, 105626 (2019). https://doi.org/10.1016/j.compositesa.2019.105626
G. de Souza, J.R. Tarpani, Interleaving CFRP and GFRP with a thermoplastic ionomer: the effect on bending properties. Appl. Compos. Mater. 28, 559–572 (2021). https://doi.org/10.1007/s10443-021-09874-2
Q. OuYang, X. Wang, L. Liu, High crack self-healing efficiency and enhanced free-edge delamination resistance of carbon fibrous composites with hierarchical interleaves. Compos. Sci. Technol. 217, 109115 (2022). https://doi.org/10.1016/j.compscitech.2021.109115
A.I. Selmy, N.A. Azab, M.A. Abd El-Baky, Flexural fatigue characteristics of two different types of glass fiber/epoxy polymeric composite laminates with statistical analysis. Compos. Part B Eng. 45, 518–527 (2013). https://doi.org/10.1016/j.compositesb.2012.08.017
A.I. Selmy, M.A. El-Baky, N.A. Azab, Experimental study on flexural fatigue behavior of glass fibers/epoxy hybrid composites with statistical analysis. J. Reinf. Plast. Compos. 32, 1821–1834 (2013). https://doi.org/10.1177/0731684413496879
A.I. Selmy, N.A. Azab, M.A. El-Baky, Statistical analysis of monotonic mechanical properties for unidirectional glass fiber (U)/random glass fiber (R)/epoxy hybrid and non-hybrid polymeric composites. J Compos. Mater. 48, 455–469 (2014). https://doi.org/10.1177/0021998312474046
M.A. Abd El-baky, M.A. Attia, M. Kamel, Flexural fatigue and failure probability analysis of polypropylene-glass hybrid fibres reinforced epoxy composite laminates. Plast. Rubber Compos. 47, 47–64 (2018). https://doi.org/10.1080/14658011.2017.1397252
M.A. Abd El-baky, Evaluation of mechanical properties of jute/glass/carbon fibers reinforced hybrid composites. Fibers Polym. 18, 2417–2432 (2017). https://doi.org/10.1007/s12221-017-7682-x
M.A. Attia, M.A. Abd El-Baky, A.E. Alshorbagy, Mechanical performance of intraply and inter-intraply hybrid composites based on e-glass and polypropylene unidirectional fibers. J. Compos. Mater. 51, 381–394 (2017). https://doi.org/10.1177/0021998316644972
I.F. Ituarte, S. Panicker, H.P.N. Nagarajan, E. Coatanea, D.W. Rosen, Optimisation-driven design to explore and exploit the process–structure–property–performance linkages in digital manufacturing. J. Intell. Manuf. 1, 1–23 (2022). https://doi.org/10.1007/s10845-022-02010-2
M. Azizian, J.H.S. Almeida, Stochastic, probabilistic and reliability analyses of internally-pressurised filament wound composite tubes using artificial neural network metamodels. Mater. Today Commun. 31, 103627 (2022). https://doi.org/10.1016/j.mtcomm.2022.103627
F.M. Monticeli, H.L. Ornaghi, H.J.C. Woorwald, M.O.H. Cioffi, Three-dimensional porosity characterization in carbon / glass fiber epoxy hybrid composites. Compos. Part A Appl. Sci. Manuf. 125, 105555 (2019). https://doi.org/10.1016/j.compositesa.2019.105555
American Society for Testing and Materials, ASTM D2344 D2344M-16, Standard test method for short-beam strength of polymer matrix composite materials and their laminates. ASTM Int. (2016). https://doi.org/10.1520/D2344
F.M. Beremin, A. Pineau, F. Mudry, J.C. Devaux, Y. D’Escatha, P. Ledermann, A local criterion for cleavage fracture of a nuclear pressure vessel steel. Metall Trans. A 14, 2277–2287 (1983). https://doi.org/10.1007/BF02663302
X. Gao, R.H. Dodds, R.L. Tregoning, J.A. Joyce, R.E. Link, A Weibull stress model to predict cleavage fracture in plates containing surface cracks. Fatigue Fract. Eng. Mater. Struct. 22, 481–493 (1999). https://doi.org/10.1046/j.1460-2695.1999.00202.x
S.Y. Kim, N.R. Sottos, S.R. White, Self-healing of fatigue damage in cross-ply glass/epoxy laminates. Compos. Sci. Technol. 175, 122–127 (2019). https://doi.org/10.1016/j.compscitech.2019.03.016
G.P. McCombe, J. Rouse, R.S. Trask, P.J. Withers, I.P. Bond, X-ray damage characterisation in self-healing fibre reinforced polymers. Compos. Part A Appl. Sci. Manuf. 43, 613–620 (2012). https://doi.org/10.1016/j.compositesa.2011.12.020
G. Williams, R. Trask, I. Bond, A self-healing carbon fibre reinforced polymer for aerospace applications. Compos. Part A Appl. Sci. Manuf. 38, 1525–1532 (2007). https://doi.org/10.1016/j.compositesa.2007.01.013
I.S. Vintila, S. Draghici, H.A. Petrescu, A. Paraschiv, M.R. Condruz, L.R. Maier, A. Bara, M. Necolau, Evaluation of dispersion methods and mechanical behaviour of glass fibre composites with embedded self-healing systems. Polymers (Basel) 13(1), 1642 (2021). https://doi.org/10.3390/polym13101642
B. Ashrafi, J. Guan, V. Mirjalili, Y. Zhang, L. Chun, P. Hubert, B. Simard, C.T. Kingston, O. Bourne, A. Johnston, Enhancement of mechanical performance of epoxy/carbon fiber laminate composites using single-walled carbon nanotubes. Compos. Sci. Technol. 71, 1569–1578 (2011). https://doi.org/10.1016/j.compscitech.2011.06.015
N.N.F.N.M.N. Kahar, A.F. Osman, E. Alosime, N. Arsat, N.A.M. Azman, A. Syamsir, Z. Itam, Z.A.A. Hamid, The versatility of polymeric materials as self-healing agents for various types of applications: A review. Polymers (Basel) 13, 1–34 (2021). https://doi.org/10.3390/polym13081194
R.J. Varley, G.P. Parn, Thermally activated healing in a mendable resin using a non woven EMAA fabric. Compos. Sci. Technol. 72, 453–460 (2012). https://doi.org/10.1016/j.compscitech.2011.12.007
K. Pingkarawat, T. Bhat, D.A. Craze, C.H. Wang, R.J. Varley, A.P. Mouritz, Healing of carbon fibre-epoxy composites using thermoplastic additives. Polym. Chem. 4, 5007–5015 (2013). https://doi.org/10.1039/c3py00459g
B. Jony, S. Roy, S.B. Mulani, Fracture resistance of in-situ healed CFRP composite using thermoplastic healants. Mater. Today Commun. 24, 101067 (2020). https://doi.org/10.1016/j.mtcomm.2020.101067
D.Y. Wu, S. Meure, D. Solomon, Self-healing polymeric materials: A review of recent developments. Prog. Polym. Sci. 33, 479–522 (2008). https://doi.org/10.1016/j.progpolymsci.2008.02.001
P. Michael, D. Döhler, W.H. Binder, Improving autonomous self healing via combined chemical/physical principles. Polymer (Guildf) 69, 216–227 (2015). https://doi.org/10.1016/j.polymer.2015.01.041
J. Champagne, S.S. Pang, G. Li, Effect of confinement level and local heating on healing efficiency of self-healing particulate composites. Compos. Part B Eng. 97, 344–352 (2016). https://doi.org/10.1016/j.compositesb.2016.05.002
A.J. Patel, N.R. Sottos, E.D. Wetzel, S.R. White, Autonomic healing of low-velocity impact damage in fiber-reinforced composites. Compos. Part A Appl. Sci. Manuf. 41, 360–368 (2010). https://doi.org/10.1016/j.compositesa.2009.11.002
P.S. Tan, A.A. Somashekar, P. Casari, D. Bhattacharyya, Healing efficiency characterization of self-repairing polymer composites based on damage continuum mechanics. Compos. Struct. 208, 367–376 (2019). https://doi.org/10.1016/j.compstruct.2018.09.091
F.M. Monticeli, R.M. Neves, H.L.J. Ornaghi, J.H.S. Almeida, A systematic review on high-performance fiber-reinforced 3D printed thermoset composites. Polym. Compos. 42, 3702–3715 (2021). https://doi.org/10.1002/pc.26133
C.H. Wang, K. Sidhu, T. Yang, J. Zhang, R. Shanks, Interlayer self-healing and toughening of carbon fibre/epoxy composites using copolymer films. Compos. Part A Appl. Sci. Manuf. 43, 512–518 (2012). https://doi.org/10.1016/j.compositesa.2011.11.020
Y.P. Chuves, M. Pitanga, I. Grether, M.O. Cioffi, F. Monticeli, The influence of several carbon fiber architecture on the drapability effect. Textile 2, 486–498 (2022). https://doi.org/10.3390/textiles2030027
C. Bai, Q. Ma, X. Gan, T. Zhou, Theoretical prediction model of mean crushing force of CFRP-Al hybrid circular tubes. Polym. Compos. 42, 5035–5050 (2021)
R. Khan, R. Alderliesten, R. Benedictus, Two-parameter model for delamination growth under mode i fatigue loading (Part A: Experimental study). Compos. Part A Appl. Sci. Manuf. 65, 192–200 (2014). https://doi.org/10.1016/j.compositesa.2014.06.007
F.M. Monticeli, M.O.H. Cioffi, H.J.C. Voorwald, Mode II delamination of carbon-glass fiber/epoxy hybrid composite under fatigue loading. Int. J. Fatigue 154, 106574 (2022). https://doi.org/10.1016/j.ijfatigue.2021.106574
Acknowledgements
The authors acknowledge the financial support from São Paulo Research Foundation (FAPESP Grant no: 2017/10606-4; 2020/09422-9), Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES finance code 001), and National Council for Scientific and Technological Development (CNPq).
Funding
FAPESP,2017/10606-4, Francisco Monticeli, 2021/05706-5,Francisco Monticeli,2019/04412-8, Maria Odila Hilário Cioffi, 2020/09422-9, Yuri Pereira Chuves, CAPES, 001.
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Chuves, Y.P., Monticeli, F.M., do Nascimento, A.A. et al. The Effect of Self-Healing Agent Fraction on CFRP Mechanical Behavior: Statistical Analysis Approach. Fibers Polym 24, 729–740 (2023). https://doi.org/10.1007/s12221-023-00103-0
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12221-023-00103-0