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Eco-Friendly, Thermal Resistant Cotton Fabric Enhanced with Nano Zinc Borate Powder

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Abstract

The easy burning of cotton fabrics, which have the widest usage area among natural fibers, is a serious problem. Thus, treatment with an environmental friend flame retardant material is essential for cotton fabrics. Zinc borates are multifunctional fire retardants. They can act as smoke suppressor, flame retardant and spark suppressor. Since they are non-toxic and environmental friend materials, they are ideal flame retardants for fabric treatment. In this study, nano-sized zinc borate (ZnO·3B2O3·7H2O) was synthesized and cotton fabric was treated with zinc borate powder with a novel method. Zinc borates are slightly soluble in water. They were dissolved with aid of ammonia as zinc ammonia borate complexes and were recrystalised on the cotton fabric fibers through the evaporation of ammonia. The burning resistance of treated cotton fabric was investigated. The hardness, hydrophobicity, smoke suppression and burning resistance of untreated and treated cotton fabrics were compared. Since zinc borates have smoke suppression feature, a more slight smoke was observed and a higher rate of carbonization occurred during combustion test of treated cotton fabric compared to the untreated cotton fabric. In addition, the burning rate was reduced from 2.26 cm/s to 1.26 cm/s.

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References

  1. D. Ahmed, AUTEX 2009 World Textile Conference, Izmir, Turkey, Hybridization of Smart Textiles in Medical and Healthcare Management, https://danishchandna.files.wordpress.com/2009/12/paper-link.pdf (Accessed September 21, 2021).

  2. N. Mao and M. Du in “Waterproof and Water Repellent Textiles and Clothing” (J. Williams Ed.), pp.233–265, Woodhead Publishing, Sawston, 2018.

  3. J. Zhang, P. France, A. Radomyselskiy, S. Datta, J. Zhao, and W. V. Ooij, J. Appl. Polym. Sci., 88, 1473 (2003).

    Article  CAS  Google Scholar 

  4. H. J. Lee, S. Y. Yeo, and S. H. Jeong, J. Mater. Sci., 38, 2199 (2003).

    Article  CAS  Google Scholar 

  5. F. Fang, B. Tong, T. Du, X. Zhang, Y. Meng, X. Liu, and X. Tian, Cellulose, 23, 3341 (2016).

    Article  CAS  Google Scholar 

  6. A. Bashari, M. Shakeri, and A. R. Shirvan, “UV-protective textiles, The Impact and Prospects of Green Chemistry for Textile Technology”, pp.327–365, Woodhead Publishing, Sawston, 2019.

    Google Scholar 

  7. C. Jiang, W. Liu, M. Yang, C. Liu, S. He, Y. Xie, and Z. Wang, Colloids Surf. A: Physicochem. Eng. Asp., 559, 235 (2018).

    Article  CAS  Google Scholar 

  8. Z. Mai, Z. Xiong, X. Shu, X. Liu, H. Zhang, X. Yin, Y. Zhou, M. Liu, M. Zhang, W. Xu, and D. Chen, Carbohydr. Polym., 199, 516 (2018).

    Article  CAS  Google Scholar 

  9. Z. Omerogullari Basyigit and D. Kut, Text. Apparel, 28, 287 (2018).

    Google Scholar 

  10. Q. Zhang, W. Zhang, J. Huang, Y. Lai, T. Xing, G. Chen, W. Jin, H. Liu, and B. Sun, Mater. Des., 85, 796 (2015).

    Article  CAS  Google Scholar 

  11. N. Yaman, Fiber. Polym., 10, 413 (2009).

    Article  CAS  Google Scholar 

  12. M. Forouharshad, M. Montazer, M. B. Moghadam, and O. Saligheh, Thermochim. Acta, 516, 29 (2011).

    Article  CAS  Google Scholar 

  13. Ş. Celep, MS Thesis, Çukurova University, Adana, 2007.

    Google Scholar 

  14. H. Dayioğlu and H. Canbaz Karakas, “Elyaf Bilgisi”, Teknik Fuarcilik, İstanbul, 2007.

    Google Scholar 

  15. N. Seventekin, “Tekstil Kimyasi”, 1st ed., Ege University Textile and Apparel Research Application Center, İzmir, 2004.

    Google Scholar 

  16. F. R. Abe, A. Á. S. De Oliveira R. V. Marino, T. C. R. Rialto, D. P. Oliveira, and D. J. Dorta, Ecotoxicol. Environ. Saf., 208, 111745 (2021).

    Article  CAS  Google Scholar 

  17. W. Liu, R. Shi, X. Ge, H. Huang, X. Chen, and M. Mu, Prog. Org. Coat., 156, 106271 (2021).

    Article  CAS  Google Scholar 

  18. W. Rao, J. Shi, C. Yu, H.-B. Zhao, and Y.-Z. Wang, Chem. Eng. J., 424, 130556 (2021).

    Article  CAS  Google Scholar 

  19. A. Cayla, F. Rault, S. Giraud, F. Salaün, V. Fierro, and A. Celzard, Polymers, 8, 331 (2016).

    Article  Google Scholar 

  20. M. Nakpathom and P. Phromphen, NU. Int. J. Sci., 4, 26 (2007).

    Google Scholar 

  21. P. Li, B. Wang, Y. J. Xu, Z. Jiang, C. Dong, Y. Liu, and P. Zhu, ACS Sust. Chem. Eng., 7, 19246 (2019).

    Article  CAS  Google Scholar 

  22. J. Liu and C. Xiao, Int. J. Biol. Macromol., 119, 1083 (2018).

    Article  CAS  Google Scholar 

  23. Ö. Akgül, MS Thesis, Yildiz Technical University, Istanbul, 2010.

    Google Scholar 

  24. Y. Ipek, Turk. J. Chem., 44, 214 (2020).

    Article  CAS  Google Scholar 

  25. A. S. Kipcak, F. T. Senberber, M. Yildirim, S. A. Yuksel, E. Moroydor Derun, and N. Tugrul, Chem., Main Group Met., 39, 59 (2016).

    Article  CAS  Google Scholar 

  26. G. Ö. Çakal, B. Baltaci, G. Bayram, S. Özkar, and İ. Eroğlu, J. Cryst. Growth, 533, 125461 (2020).

    Article  Google Scholar 

  27. Y. Fang, Q. Wang, C. Guo, Y. Song, and P. A. Cooper, J. Anal. Appl. Pyrolysis, 100, 230 (2013).

    Article  CAS  Google Scholar 

  28. H. Durrani, V. Sharma, D. Bamboria, A. Shukla, S. Basak, and W. Ali, Cellulose, 27, 9061 (2020).

    Article  CAS  Google Scholar 

  29. S. Gordon and Y. L. Hsie, “Cotton: Science and Technology”, Woodhead Publishing Limited and CRC Press, Boca Raton, 2007.

    Book  Google Scholar 

  30. Y. İpek and Ö. Ertekin, Fiber. Polym., 22, 2826 (2021).

    Article  Google Scholar 

  31. M. Gönen, Ph.D. Dissertation, Izmir Institute of Technology, İzmir, 2009.

    Google Scholar 

  32. Q. Qin, R. H. Guo, E. H. Ren, X. X. Lai, C. Cui, H. Y. Xiao, M. Zhou, G. Yao, S. X. Jiang, and J. W. Lan, ACS Sustain. Chem. Eng., 8, 10335 (2020).

    Article  CAS  Google Scholar 

  33. W. D. Schindler and P. J. Hauser, “Chemical Finishing of Textiles”, Elsevier, Woodhead Publishing, UK, 2004.

    Book  Google Scholar 

  34. N. Tugrul, M. Bardakci, and E. Ozturk, Res. Chem. Intermed., 41, 4395 (2015).

    Article  CAS  Google Scholar 

  35. N. Çakici, M. I. Aksu, and E. Erdemir, CYTA-J. Food, 13, 196 (2015).

    Article  Google Scholar 

  36. R. Schubring, Arch. Lebensmittelhyg, 53, 34 (2002).

    Google Scholar 

  37. P. A. V. Freitas, R. R. A. Silva, T. V. de Oliveira, R. R. A. Soares, N. S. Junior, A. R. F. Moraes, A. C. dos S. Pires, and N. F. F. Soares, LWT, 132, 109780 (2020).

    Article  CAS  Google Scholar 

Download references

Acknowledgement

This study was financially supported by Munzur University (Project no: MFMUB017-05).

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Correspondence to Yeliz İpek.

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İpek, Y. Eco-Friendly, Thermal Resistant Cotton Fabric Enhanced with Nano Zinc Borate Powder. Fibers Polym 23, 3435–3441 (2022). https://doi.org/10.1007/s12221-022-4988-0

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  • DOI: https://doi.org/10.1007/s12221-022-4988-0

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