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Preparation and Characterization of Fluorine-Containing Polybenzoxazole Composite Films including Graphene Oxide as a Reinforcing Material

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Abstract

The fluorine-containing polyhydroxyamide (F-75-PHA) was synthesized by using low-temperature solution polycondensation of 2,2-bis(3-amino-4-hydroxyphenyl) hexafluoropropane (BAHHFP, 75 mol%) and 3,3′-dihydroxybenzidine (DHB, 25 mol%) with terephthaloyl chloride (TPC) in N-methyl-2-pyrrolidinone (NMP) without metal salts. The F-75-PBO (polybenzoxazole)/GO (graphene oxide) composite films with different GO contents (0.01, 0.1, and 1.0 wt%, respectively) were prepared by heat-treatment of their precursors (F-75-PHA/GO composite films), and the effects of reinforcing material (GO) on the structural, thermal, and mechanical properties of them were studied systemically. FE-SEM images that the F-75-PBO matrix and GO sheets had a superior hydrogen bonding interaction and formed a three-dimensional (3D) network structure in composite films having a great bendability. FT-IR spectra indicated that the incorporation of GO in composite films could be reacting hydroxyl (−OH) groups on F-75-PHA matrix to carboxyl (−COOH) and/or −OH groups in GO sheets, and thus the O-H stretching peak (23.8 %) for F-75-PHA/GO-0.1 composite film mostly disappeared in comparison with that (100 %) of F-75-PHA film. DSC heating curves revealed that the thermal cyclization temperature (Tc) of the F-75-PHA/GO composite films decreased with an increment of GO content. Interestingly, for F-75-PHA/GO-0.1 composite film, the Tc decreased by up to 254 °C. However, despite the outstanding reinforcing effect of GO sheets, an interesting phenomenon was confirmed that 3D network structure including an excellent hydrogen bonding interaction did not largely influence the mechanical properties of F-75-PBO/GO composite films.

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References

  1. C. J. Zhou, Q. Zhuang, J. Qian, X. X. Li, and Z. W. Han, Chem. Lett., 37, 254 (2008).

    Article  CAS  Google Scholar 

  2. R. R. Hao, J. H. Jin, and S. L. Yang, Appl Mech. Mater., 577, 58 (2014).

    Article  Google Scholar 

  3. Y. Chen, S. Zhang, X. Y. Liu, Q. B. Pei, J. Qian, and Z. W. Han, Macromolecules, 48, 365 (2015).

    Article  CAS  Google Scholar 

  4. E. H. Lee, M. H. Jee, C. S. Kang, and D. H. Baik, Fiber. Polym., 20, 832 (2019).

    Article  CAS  Google Scholar 

  5. K. S. Choi, F. Liu, J. S. Choi, and T. S. Seo, Langmuir, 26, 12902 (2010).

    Article  CAS  Google Scholar 

  6. Z. Song, T. Xu, M. L. Gordin, Y. B. Jiang, I. T. Bae, Q. Xiao, H. Zhan, J. Liu, and D. Wang, Nano. Lett., 12, 2205 (2012).

    Article  CAS  Google Scholar 

  7. C. S. Kang, M. J. Paik, C. W. Park, and D. H. Baik, Fiber. Polym., 16, 239 (2015).

    Article  CAS  Google Scholar 

  8. C. S. Kang, M. J. Paik, C. W. Park, and D. H. Baik, Fiber. Polym., 17, 657 (2016).

    Article  CAS  Google Scholar 

  9. C. S. Kang, M. H. Jee, M. J. Yeo, and D. H. Baik, Fiber. Polym., 19, 1626 (2018).

    Article  CAS  Google Scholar 

  10. C. S. Kang and D. H. Baik, Fiber. Polym., 20, 2443 (2019).

    Article  CAS  Google Scholar 

  11. Y. C. Su and F. C. Chang, Polymer, 44, 7989 (2003).

    Article  CAS  Google Scholar 

  12. K. I. Fukukawa, Y. J. Shibasaki, and M. S. Ueda, Macromolecules, 37, 8256 (2004).

    Article  CAS  Google Scholar 

  13. J. Li, P. S. Wong, and J. K. Kim, Mater. Sci. Eng., 483–484, 66 (2008).

    Google Scholar 

  14. S. Kumar, L. L. Sun, S. Caceres, B. Li, W. Wood, A. Perugini, R. G. Maguire, and W. H. Zhong, Nanotechnology, 21, 105702 (2010).

    Article  CAS  Google Scholar 

  15. E. Farjami, M. A. Rottmayer, and L. J. Deiner, J. Mater. Chem. A, 1, 15501 (2013).

    Article  CAS  Google Scholar 

  16. C. K. Chua and M. Pumera, J. Mater. Chem. A, 1, 1892 (2013).

    Article  CAS  Google Scholar 

  17. J. Liang, Y. Huang, L. Zhang, Y. Wang, Y. Ma, T. Y. Guo, and Y. S. Chen, Adv. Funct. Mater., 19, 2297 (2009).

    Article  CAS  Google Scholar 

  18. H. K. F. Cheng, N. G. Sahoo, Y. P. Tai, Y. Pan, H. Bao, L. Li, S. H. Chan, and J. Zhao, ACS Appl. Mater. Inter., 4, 2387 (2012).

    Article  CAS  Google Scholar 

  19. V. Pavlidis, M. Patila, U. T. Bornscheuer, D. Gournis, and H. Stamatis, Trends Biotechnol., 32, 312 (2014).

    Article  CAS  Google Scholar 

  20. Y. S. Ye, M. Y. Cheng, X. L. Xie, J. Rick, Y. J. Huang, F. C. Chang, and B. J. Hwang, J. Power Sources, 239, 424 (2013).

    Article  CAS  Google Scholar 

  21. A. Kundu, R. K. Layek, A. Kuila, and A. K. Nandi, ACS Appl. Mater. Inter., 4, 5576 (2012).

    Article  CAS  Google Scholar 

  22. X. Qi, X. Yao, S. Deng, T. Zhou, and Q. Fu, J. Mater. Chem. A, 2, 2240 (2014).

    Article  CAS  Google Scholar 

  23. G. S. Liou, P. H. Lin, H. J. Yen, Y. Y. Yu, T. W. Tsai, and W. C. Chen, J. Mater. Chem., 20, 531 (2010).

    Article  CAS  Google Scholar 

  24. J. Ishii, A. Takata, N. Sensui, Y. Oami, R. Yokota, L. Vladimirov, and M. Hasegawa, Eur. Polym. J., 46, 681 (2010).

    Article  CAS  Google Scholar 

  25. N. Sensui, J. Ishii, A. Takata, Y. Oami, and M. Hasegawa, High Perform. Polym., 21, 709 (2009).

    Article  CAS  Google Scholar 

  26. M. E. Uddin, R. K. Layek, N. H. Kim, D. Hui, and J. H. Lee, Comp. Part B: Eng., 80, 238 (2015).

    Article  CAS  Google Scholar 

  27. M. E. Uddin, R. K. Layek, N. H. Kim, H. Y. Kim, D. Hui, and J. H. Lee, Comp. Part B: Eng., 90, 223 (2016).

    Article  CAS  Google Scholar 

  28. S. Pilla, A. Kramschuster, J. J. Lee, C. Clemons, S. Gong, and L. S. Turng, J. Mater. Sci., 45, 2732 (2010).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Textile Materials Engineering, Shinhan University, Dongducheon, 11340, Korea

    Chan Sol Kang

  2. Department of Organic Materials Engineering, Chungnam National University, Daejeon, 34134, Korea

    Doo Hyun Baik

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  1. Chan Sol Kang
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  2. Doo Hyun Baik
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Correspondence to Doo Hyun Baik.

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Kang, C.S., Baik, D.H. Preparation and Characterization of Fluorine-Containing Polybenzoxazole Composite Films including Graphene Oxide as a Reinforcing Material. Fibers Polym 22, 2071–2078 (2021). https://doi.org/10.1007/s12221-021-1173-9

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  • DOI: https://doi.org/10.1007/s12221-021-1173-9

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