Skip to main content
Log in

Facile Fabrication of Temperature Triggered Thermochromic Core-sheath Alginate Microfibers from Microfluidic Spinning

  • Published:
Fibers and Polymers Aims and scope Submit manuscript

Abstract

Dynamic tuning of color plays an important role in nature creatures. Color changing according to external stimuli lead to more advanced applications. Herein, we prepared thermochromic alginate microfibers which could dynamically change their color under different temperature through microfluidic spinning. The alginate microfibers had core-sheath structure and the thermochromic powder only distributed in the sheath layer. As the temperature increasing, the color of the fiber will disappeared at a certain temperature. Furthermore, when the temperature decreased, the color of the fiber will recover. So the color of the thermochromic alginate fibers could be reversely tuned by changing temperature. Moreover, the new thermochromic alginate fiber has good strength and could be woven into textiles which makes it hold great potential application in smart clothing industry.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. W. Weng, J. Yang, Y. Zhang, Y. Li, S. Yang, L. Zhu, and M. Zhu, Adv. Mater., 32, 1902301 (2020).

    Article  CAS  Google Scholar 

  2. Y. Zhao, M. Lei, S. Liu, and Q. Zao, Sendor. Actuat. B-Chem., 261, 226 (2018).

    Article  CAS  Google Scholar 

  3. Y. Jang, S. M. Kim, G. M. Spinks, and S. J. Kim, Adv. Mater., 32, 1902670 (2020).

    Article  CAS  Google Scholar 

  4. Q. Shi, J. Sun, C. Hou, Y. Li, Q. Zhang, and H. Wang, Adv. Fiber Mater., 1, 3 (2019).

    Article  Google Scholar 

  5. X. Lu, Z. Zhang, X. Sun, P. Chen, J. Zhang, H. Guo, Z. Shao, and H. Peng, Chem. Sci., 7, 5113 (2016).

    Article  CAS  Google Scholar 

  6. G. Huang, L. Liu, R. Wang, J. Zhang, X. Sun, and H. Peng, J. Mater. Chem. C, 4, 7589 (2016).

    Article  CAS  Google Scholar 

  7. X. Yuan, Z. Liu, S. Shang, H. Wang, Q. Zhang, Y. Lic, and W. Jin, RSC Adv., 6, 16319 (2016).

    Article  CAS  Google Scholar 

  8. M. Kolle, A. Lethbridge, M. Kreysing, J. J. Baumberg, J. Aizenberg, and P. Vukusic, Adv. Mater., 25, 2239 (2013).

    Article  CAS  Google Scholar 

  9. S. Shang, Z. Liu, Q. Zhang, H. Wang, and Y. Li, J. Mater. Chem. A, 3, 11093 (2015).

    Article  CAS  Google Scholar 

  10. S. Shang, Q. Zhang, H. Wang, and Y. Li, J. Colloid Interf. Sci., 483, 11 (2016).

    Article  CAS  Google Scholar 

  11. Q. Li, Kerui Li, H. Fan, C. Hou, Y. Li, Q. Zhang, and H. Wang, J. Mater. Chem. C, 5, 11448 (2017).

    Article  CAS  Google Scholar 

  12. Y. Zhao, Z. Xie, H. Gu, C. Zhua, and Z. Gu, Chem. Soc. Rev., 41, 3297 (2012).

    Article  CAS  Google Scholar 

  13. Z. Liu, Q. Zhang, H. Wang, and Y. Li, Chem. Commun., 47, 12801 (2011).

    Article  CAS  Google Scholar 

  14. Z. Liu, Q. Zhang, H. Wang, and Y. Li, J. Colloid Interf. Sci., 406, 18 (2013).

    Article  CAS  Google Scholar 

  15. C. E. Finlayson, C. Goddard, E. Papachristodoulou, D. R. E. Snoswell, A. Kontogeorgos, P. Spahn, G. P. Hellmann, O. Hess, and J. J. Baumberg, Opt. Express, 19, 3144 (2011).

    Article  CAS  Google Scholar 

  16. N. Zhou, A. Zhang, L. Shi, and K. Zhang, ACS Macro Lett., 2, 116 (2013).

    Article  CAS  Google Scholar 

  17. X. Sun, J. Zhang, X. Lu, X. Fang, and H. Peng, Angew. Chem. Int. Ed., 54, 3630 (2015).

    Article  CAS  Google Scholar 

  18. J. Zhang, S. He, L. Liu, G. Guan, X. Lu, X. Sun, and H. Peng, J. Mater. Chem. C, 4, 2127 (2016).

    Article  CAS  Google Scholar 

  19. T. M. A. Elmaaty, S. A. Abdeldayem, and N. Elshafai, Cloth. Text. Res. J., 38, 182 (2020).

    Article  Google Scholar 

  20. T. A. Elmaaty, S. M. Ramadan, S. M. N. Eldin, and G. Elgamal, Fiber. Polym., 19, 2317 (2018).

    Article  CAS  Google Scholar 

  21. K. Katayama, K. Nakamura, and T. Amano, Colloid Polym. Sci., 226, 125 (1968).

    CAS  Google Scholar 

  22. L. Fambri, A. Pegoretti, R. Fenner, S. D. Ineardona, and C. Migliaresi, Polymer, 38, 79 (1997).

    Article  CAS  Google Scholar 

  23. A. Koeppel and C. Holland, ACS Biomater. Sci. Eng., 3, 226 (2017).

    Article  CAS  Google Scholar 

  24. J. Liu, R. Zhang, M. Ci, S. Sui, and P. Zhu, J. Eng. Fiber. Fabr., 14, 1 (2019).

    Google Scholar 

  25. W. E. Teo and S. Ramakrishna, Nanotechnology, 17, R89 (2006).

    Article  CAS  Google Scholar 

  26. Z. M. Huang, Y. Z. Zhang, M. Kotaki, and S. Ramakrishna, Compos. Sci. Technol., 63, 2223 (2003).

    Article  CAS  Google Scholar 

  27. E. Kang, Y. Y. Choi, S. K. Chae, J. H. Moon, J. Y. Chang, and S. H. Lee, Adv. Mater., 24, 4271 (2012).

    Article  CAS  Google Scholar 

  28. X. Shi, S. Ostrovidov, Y. Zhao, X. Liang, M. Kasuya, K. Kurihara, K. Nakajima, H. Bae, H. Wu, and A. Khademhosseini, Adv. Funct. Mater., 25, 2500 (2015).

    Google Scholar 

  29. J. Cheng, Y. Jun, J. Qin, and S. H. Lee, Biomaterials, 114, 121 (2017).

    Article  CAS  Google Scholar 

  30. C. M. Hwang, A. Khademhosseini, Y. Park, K. Sun, and S. H. Lee, Langmuir, 24, 6845 (2008).

    Article  CAS  Google Scholar 

  31. Z. Bai, J. M. M. Reyes, R. Montazami, and N. Hashemi, J. Mater. Chem. A, 2, 4878 (2014).

    Article  CAS  Google Scholar 

  32. Y. S. Lin, K. S. Huang, C. H. Yang, C. Y. Wang, Y. S. Yang, H. C. Hsu, Y. J. Liao, and C. W. Tsai, PLoS One, 7, e33184 (2012).

    Article  CAS  Google Scholar 

  33. H. Yang and M. Guo, Macromol. Rapid Commun., 40, 1900111 (2019).

    Article  Google Scholar 

  34. J. Guo, Y. Yu, H. Wang, H. Zhang, X. Zhang, and Y. Zhao, Small, 15, 1805162 (2019).

    Article  Google Scholar 

  35. A. S. Chaurasia and S. Sajjadi, Lab Chip, 19, 851 (2019).

    Article  CAS  Google Scholar 

  36. J. Liu, Y. Liu, D. Miao, S. Sui, C. Zhang, and P. Zhu, Fiber. Polym., 19, 1650 (2018).

    Google Scholar 

Download references

Acknowledgments

The project was funded by State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University (KF2014).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Shenglong Shang or Ping Zhu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zou, X., Shang, S., Liu, J. et al. Facile Fabrication of Temperature Triggered Thermochromic Core-sheath Alginate Microfibers from Microfluidic Spinning. Fibers Polym 22, 1535–1542 (2021). https://doi.org/10.1007/s12221-021-0778-3

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12221-021-0778-3

Keywords

Navigation