Abstract
The effect of hydrophilic bentonite incorporation on the curing performance of pigmented ultra violet (UV) curable polyurethane acrylate (PUA) coating was investigated. To the best of our knowledge, crock fastness and gloss properties of pigmented bentonite incorporated UV curable PUA coating have been examined for the first time. Fourier Transform Infrared (FTIR) spectroscopy analysis of the cured films showed that addition of both bentonite and pigment decreased the conversion of C=C. However a more significant drop was observed with the addition of pigment into the formulation. The drop of conversion with the incorporation of bentonite did not adversely affect the hardness and crock fastness values and hence the UV curing performance of the films. Bentonite particles were efficiently distributed in the film and intercalation was achieved owing to the ball milling process. Hardness of the cured films increased with the increase in energy levels. On the other hand, hardness decreased at higher pigment concentrations however, was not affected adversely by bentonite incorporation. Gloss was found to be enhanced with the addition of bentonite in both pigmented and unpigmented films. Significant improvement in crock fastness could not achieved with the addition of bentonite.
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V. Landry, B. Riedl, and P. Blanchet, Prog. Org. Coat., 62, 400 (2008).
K. Dietliker, R. Hüsler, J.-L. Birbaum, S. Ilg, S. Villeneuve, K. Studer, T. Jung, J. Benkhoff, H. Kura, A. Matsumoto, and H. Oka, Prog. Org. Coat., 58, 146 (2007).
L. Macarie and G. Ilia, J. Appl. Polym. Sci., 104, 247 (2007).
C. Lubbers and J. Erbeck, Radtech Rep., 2, 35 (2014).
G. Baysal, B. Kalav, and B. K. Kayaoǧlu, Color. Technol., 135, 111 (2019).
H. Bahria and Y. Erbil, Dyes Pigment., 134, 442 (2016).
V. Jančovičová, M. Mikula, B. Havlínová, and Z. Jakubíková, Prog. Org. Coat., 76, 432 (2013).
A. Gürses, M. Açıkyıldız, K. Güneş, and M. S. Gürses, “Dyes and Pigments” in “Springer Briefs in Molecular Science Green Chemistry for Sustainability”, 1st ed. (S. K. Sharma Ed.), pp.13–28, Springer, Cham, 2016.
O. A. Hakeim, H. A. Diab, and J. Adams, Prog. Org. Coat., 84, 70 (2015).
S. Sinha Ray and M. Okamoto, Prog. Polym. Sci., 28, 1539 (2003).
E. T. Thostenson, C. Li, and T.-W. Chou, Compos. Sci. Technol., 65, 491 (2005).
S. Pavlidou and C. D. Papaspyrides, Prog. Polym. Sci., 33, 1119 (2008).
T. T. Zhu, C. H. Zhou, F. B. Kabwe, Q. Q. Wu, C. S. Li, and J. R. Zhang, Appl. Clay Sci., 169, 48 (2019).
P. Chittavanich, K. Miller, and M. D. Soucek, Prog. Org. Coat., 73, 392 (2012).
M. Soltani, R. Veisi, A. A. Rohani, O. Ramzani, H. R. Naji, and E. S. Bakar, BioResources, 9, 86 (2014).
P. Gloeckner, T. Jung, S. Struck, and K. Studer, “Radiation Curing: Coatings and Printing Inks”, Technical Basics, Applications and Trouble Shooting, Vincentz, Hannover, 2009.
W. N. Nkeuwa, B. Riedl, and V. Landry, Prog. Org. Coat., 77, 1 (2014).
W. N. Nkeuwa, B. Riedl, and V. Landry, J. Coat. Technol. Res., 11, 283 (2014).
W. N. Nkeuwa, B. Riedl, and V. Landry, J. Coat. Technol. Res., 14, 555 (2017).
F. M. Uhl, S. P. Davuluri, S.-C. Wong, and D. C. Webster, Polymer, 45, 6175 (2004).
M. J. Kim, H. G. Kim, and S. S. Kim, Macromol. Res., 20, 739 (2012).
X. Y. Sun, J. L. Kang, J. Z. Hang, L. J. Jin, F. Xu, and L. Y. Shi, Adv. Mater. Res., 750–752, 2057 (2013).
G. Baysal, B. Kalav, and B. K. Kayaoǧlu, Color. Technol., 135, 283 (2019).
Certificate of Analysis, https://www.sigmaaldrich.com/Graphics/COfAInfo/SigmaSAPQM/COFA/68/682659/682659-BULK_________MKCK4658_________.pdf (Accessed June 7, 2020).
C. M. Koo, H. T. Ham, M. H. Choi, S. O. Kim, and I. J. Chung, Polymer, 44, 681 (2003).
E. M. S. Azzam, S. M. Sayyah, and A. S. Taha, Egypt. J. Pet., 22, 493 (2013).
S. N. A. Muttalib and N. Othman, Procedia Chem., 19, 381 (2016).
M. Gao and P. Zhu, Starch/Stärke, 64, 97 (2012).
E. A. S. Gonzalez, D. Olmos, G. Gonzalez-Gaitano, B. Orgaz, and J. Gonzalez-Benito, J. Appl. Polym. Sci., 132, 42676 (2015).
T. Liu, Y. Li, Y. Su, H. Yu, N. Zhao, Y. Yang, and Z. Jiang, Polym. Compos., 37, 3003 (2016).
ASTM D4366-16, “Standard Test Methods for Hardness of Organic Coatings by Pendulum Damping Tests”, ASTM International, 2016.
ASTM D523-14, “Standard Test Method for Specular Gloss”, ASTM International, 2018.
TS EN ISO 105-X12, “Textiles — Tests for Colour Fastness — Part X12: Colour Fastness to Rubbing”, 2016.
T. Reddy Ravindra, S. Kaneko, T. Endo, and S. Lakshmi Reddy, J. Lasers Opt. Photonics, doi:https://doi.org/10.4172/2469-410X.1000171 (2017).
S. S. Bhattacharya, K. K. Sen, S. O. Sen, S. Banerjee, S. Kaity, A. K. Ghosh, and A. Ghosh, Int. J. Polym. Mater. Polym. Biomater., 60, 1015 (2011).
M. Hayati-Ashtiani, Part. Part. Syst. Charact., 28, 71 (2011).
H. Yao, Z. You, L. Li, S. W. Goh, C. H. Lee, Y. K. Yap, and X. Shi, Constr. Build. Mater., 38, 327 (2013).
P. Tingaut, R. Hauert, and T. Zimmermann, J. Mater. Chem., 21, 16066 (2011).
C. Decker, Macromol. Rapid Commun, 23, 1067 (2002).
J. M. Park, J. H. Jeon, Y. H. Lee, D. J. Lee, H. Park, H. H. Chun, and H. D. Kim, Polym. Bull., 72, 1921 (2015).
H.-D. Hwang, C.-H. Park, J.-I. Moon, H.-J. Kim, and T. Masubuchi, Prog. Org. Coat., 72, 663 (2011).
S. Tasic, B. Bozic, and B. Dunjic, Prog. Org. Coat., 51, 320 (2004).
K. H. Hsieh, C. H. Kuo, C. A. Dai, W. C. Chen, T. C. Peng, and G. H. Ho, J. Appl. Polym. Sci., 91, 3162 (2004).
D. Kunwong, N. Sumanochitraporn, and S. Kaewpirom, Songklanakarin J. Sci. Technol., 33, 201 (2011).
I. V. Khudyakov, D. R. Zopf, and N. J. Turro, Des. Monomers Polym., 12, 279 (2009).
M. A. G. Bardi, M. de M. L. Munhoz, H. A. de Oliveira, R. Auras, and L. D. B. Machado, J. Appl. Polym. Sci., 131, 41116 (2014).
M. A. G. Bardi, M. M. L. Munhoz, R. A. Auras, and L. D. B. Machado, Ind. Crops Prod., 60, 326 (2014).
M. A. G. Bardi and L. D. B. Machado, Radiat. Phys. Chem., 81, 1332 (2012).
C. Wang, L. Wang, Y. Huang, X. Nan, Q. Fan, and J. Shao, Dyes Pigment., 139, 453 (2017).
Z. Li, H. Chen, C. Wang, L. Chen, J. Liu, and R. Liu, J. Polym. Sci. Part Polym. Chem., 56, 994 (2018).
P. Mangiacapra, G. Gorrasi, A. Sorrentino, and V. Vittoria, Carbohydr. Polym., 64, 516 (2006).
A. Barzegar and T. Ghaffari, Dent. Res. J., 15, 295 (2018).
A. Samariha, A. H. Hemmasi, I. Ghasemi, B. Bazyar, and M. Nemati, Maderas Cienc. Tecnol., 17, 637 (2015).
L. Ben Ammar, S. Fakhfakh, O. Jbara, A. Hadjadj, and S. Rondot, IEEE Trans. Dielectr. Electr. Insul., 24, 1878 (2017).
N. Vdović, I. Jurina, S. D. Škapin, and I. Sondi, Appl. Clay Sci., 48, 575 (2010).
F. Dellisanti and G. Valdre, Appl. Clay Sci., 28, 233 (2005).
G. Suraj, C. S. P. Iyer, S. Rugmini, and M. Lalithambika, Appl. Clay Sci., 12, 111 (1997).
B. M. Abu-Zied, W. Schwieger, and A. M. Asiri, Micropor. Mesopor. Mat., 218, 153 (2015).
A. R. Ramadan, A. M. K. Esawi, and A. A. Gawad, Appl. Clay Sci., 47, 196 (2010).
M. Galimberti, M. Coombs, S. Pandini, T. Riccò, V. Cipolletti, L. Conzatti, and G. Guerra, Appl. Clay Sci., 104, 8 (2015).
U. Chatterjee, B. S. Butola, and M. Joshi, Appl. Clay Sci., 140, 10 (2017).
I. Sondi, M. Stubicar, and V. Pravdic, Colloid. Surf. A Physicochem. Eng. Asp., 127, 141 (1997).
S. A. Kapole, R. D. Kulkarni, and S. H. Sonawane, Can. J. Chem. Eng., 89, 1590 (2011).
G. E. Christidis, P. Makri, and V. Perdikatsis, Clay Miner., 39, 163 (2004).
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Kalav, B., Göcek, İ. & Kayaoǧlu, B.K. Effect of Hydrophilic Bentonite as a Filler on Curing Performance of Pigmented UV Curable Polyurethane Acrylate Coating. Fibers Polym 22, 1800–1809 (2021). https://doi.org/10.1007/s12221-021-0315-4
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DOI: https://doi.org/10.1007/s12221-021-0315-4