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Fabrication of Co/Al2O3 Composite Nanofiber via Electrospinning with Tunable Magnetic Properties

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Abstract

In this paper, Co/Al2O3 composite nanofibers with different Co content are fabricated by electrospinning combined with selective reduction. By controlling the Co content in the composite nanofiber, not only the fiber’s morphology, but also the magnetic properties can be well adjusted to meet different applications’ requirements. The magnetic hysteresis loops of composite nanofiber show two different types of shape, typical ferromagnetism and wasp-waisted ferromagnetism. Interestingly, the saturation magnetization, which has a close relationship with the content of magnetic component, is not simply shows an increasing tendency with the increases of Co content in the composite fiber. For the Co content below 50 wt%, the Ms value increases with the Co content. After that, the saturation magnetization decreases to a valley value at near 60 wt% Co content, then increases again. The coercivity also shows the same tendency. The results indicate that the dipolar coupling interaction plays a key role in the magnetic property adjustment of Co/Al2O3 composite nanofiber.

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Acknowledgement

This work was supported by National Natural Science Foundation of China [No. 51601105], China Postdoctoral Science Foundation [Grant No. 2017M622199, 2018T110687], Young Elite Scientists Sponsorship Program by CAST [Grant No. 2017QNRC001], Shandong Provincial Natural Science Foundation of China Grants (ZR2017MC028), The fundamental research fund of Shandong university (2017JC038), and Innovation Program of Shanghai Municipal Education Commission [Grant No. 2019-01-07-00-10-E00053].

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Authors and Affiliations

  1. Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan, 250061, China

    Zidong Zhang, Wenjin Zhang, Yuliang Jiang & Rui Tian

  2. School of Civil Engineering, Shandong Jiaotong University, Jinan, 250357, China

    Min Chen

  3. School of Life Science, Shandong University, Qingdao, 266237, China

    Jian Zhang

  4. College of Ocean Science and Engineering, Shanghai Maritime University, Shanghai, 201306, China

    Runhua Fan

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  1. Zidong Zhang
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  2. Wenjin Zhang
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  3. Min Chen
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  6. Jian Zhang
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Correspondence to Zidong Zhang or Jian Zhang.

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Zhang, Z., Zhang, W., Chen, M. et al. Fabrication of Co/Al2O3 Composite Nanofiber via Electrospinning with Tunable Magnetic Properties. Fibers Polym 21, 2485–2493 (2020). https://doi.org/10.1007/s12221-020-1409-0

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