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Spinning of polyacrylamidoximes by solution blowing technique: Synthesis and characterization

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Abstract

A novel route for the production of polyacryloamidoxime nano-fibers is described. The innovative solution blowing spinning technique is used for the production of polyacryloamidoxime nano-fibers. The polyacryloamidoxime was prepared by the amidoximation of the acrylonitrile groups in a non-aqueous medium (DMF) using the least possible amount of hydroxylamine. A comparison study was performed to evaluate the effectiveness of the amidoximation reaction in aqueous or non-aqueous media. As the presented method is acquiring only 0.5 g/g hydroxylamine, at 50 °C for 7 h to achieve 63.1 % conversions, also solution blowing is an alternative technique for manufacturing of micro- and nano-fibers. The morphological structure, the chemical nature as well as the dyeability of the obtained fibers are illustrated. The obtained nano polyacryloamidoxime fibers show superior adsorption ability toward copper ions. Results showed that the present work presents a promising synthesis root for spinnable polyacryloamidoxime.

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Authors and Affiliations

  1. Department of Textile Research Division, National Research Centre, Giza, 12622, Egypt

    A. Atef Elsayed, Tamer Hamouda, M. Salama & Tarek Salem

Authors
  1. A. Atef Elsayed
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  2. Tamer Hamouda
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  3. M. Salama
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  4. Tarek Salem
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Correspondence to A. Atef Elsayed.

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Elsayed, A.A., Hamouda, T., Salama, M. et al. Spinning of polyacrylamidoximes by solution blowing technique: Synthesis and characterization. Fibers Polym 17, 1456–1463 (2016). https://doi.org/10.1007/s12221-016-6585-6

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  • DOI: https://doi.org/10.1007/s12221-016-6585-6

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