Skip to main content
SpringerLink
Log in

Absorption kinetics and thermodynamics of cationic dyeing on easily dyeable copolyester modified by 2-methyl-1,3-propanediol

  • Published:
Fibers and Polymers Aims and scope Submit manuscript

Abstract

In the paper, adsorption kinetics and thermodynamics of C.I. Basic Red 46 (BR46) on the 2-methyl-1,3-propanediol (MPD)-modified cationic dyeable copolyester (MCDP) fabric were investigated at the temperatures of 80, 90 and 100 °C. The adsorption data obtained at different temperatures were applied in pseudo-first-order and pseudo-secondorder kinetic models. The pseudo-second-order model could be used to explain the adsorption kinetics more effectively and predict the rate coefficient (k 2), equilibrium dye sorption capacity (q e ), and the half dyeing time (t 1/2) at different temperatures. In addition, the activation energy of adsorption (E a ) was determined based on the pseudo-second-order rate constant. The equilibrium data of adsorption were found to conform to Langmuir isotherm with the higher correlation. Moreover, the determined thermodynamic parameters including adsorption affinity (−Δμº) and enthalpy change (ΔHº) showed that the dye adsorption onto MCDP was a spontaneous, endothermic, and chemisorption process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Explore related subjects

Discover the latest articles, news and stories from top researchers in related subjects.

References

  1. S. K. Pal, R. S. Gandhi, and V. K. Kothari, J. Appl. Polym. Sci., 61, 401 (1996).

    Article  CAS  Google Scholar 

  2. K. J. Hsiao, J. L. Kuo, J. W. Tang, and L. T. Chen, J. Appl. Polym. Sci., 98, 550 (2005).

    Article  CAS  Google Scholar 

  3. K. Silkstone, Rev. Prog. Colorat., 12, 22 (1982).

    Article  CAS  Google Scholar 

  4. B. R. Rao and K. V. Datye, Textile Chemist and Colorist, 28, 17 (1996).

    CAS  Google Scholar 

  5. M. D. Teli and B. R. Rao, Text. Res. J., 65, 693 (1995).

    Article  CAS  Google Scholar 

  6. L. Liu, L. Cheng, J. Yu, and H. Xie, J. Appl. Polym. Sci., 120, 195 (2011).

    Article  CAS  Google Scholar 

  7. M. Iwata, H. Sato, and H. Tanji, U.S. Patent, 4526738 (1983).

    Google Scholar 

  8. T. Satou, U.S. Patent, 4426516 (1984).

    Google Scholar 

  9. D. A. Timm and Y.-L. Hsieh, J. Appl. Polym. Sci., Part B: Polm. Phys., 31, 1873 (1993).

    Article  CAS  Google Scholar 

  10. K.-J. Hsiao, J.-L. Kuo, J.-W. Tang, and L.-T. Chen, J. Appl. Polym. Sci., 98, 550 (2005).

    Article  CAS  Google Scholar 

  11. J. Greener, J. R. Gillmor, and R. C. Daly, Macromolecules, 26, 6416 (1993).

    Article  CAS  Google Scholar 

  12. Z. Hong, L. Shengping, and L. Honglie, J. Appl. Polym. Sci., 34, 1353 (1987).

    Article  Google Scholar 

  13. B. Chen, L. Zhong, and L. Gu, J. Appl. Polym. Sci., 116, 2487 (2010).

    CAS  Google Scholar 

  14. C. Fu and L. Gu, J. Appl. Polym. Sci., 128, 3964 (2013).

    Article  CAS  Google Scholar 

  15. A. Itoi, I. Nishi, Y. Ishii, and T. Sato, U.S. Patent, 5178950 (1992).

    Google Scholar 

  16. S. K. Pal, R. S. Gandhi, and V. K. Kothari, Text. Res. J., 63, 71 (1993).

    Article  CAS  Google Scholar 

  17. M.-L. Zhao, F.-X. Li, J.-Y. Yu, and X.-L. Wang, J. Appl. Polym. Sci., 131, 3 (2014).

    Google Scholar 

  18. X. Hou, R. Yang, H. Xu, and Y. Yang, Ind. Eng. Chem. Res., 51, 8341 (2012).

    Article  CAS  Google Scholar 

  19. J. R. Aspland, Textile Chemist and Colorist, 25, 21 (1993).

    Google Scholar 

  20. Z. Ren, C. Qin, R.-C. Tang, and G. Chen, Color. Technol., 128, 147 (2012).

    Article  CAS  Google Scholar 

  21. P. B. Tayade and R. V. Adivarekar, J. Environ. Chem. Eng., 1, 1336 (2013).

    Article  CAS  Google Scholar 

  22. S. Rattanaphani, M. Chairat, J. B. Bremner, and V. Rattanaphani, Dyes Pigment., 72, 88 (2007).

    Article  Google Scholar 

  23. J. H. Flynn and L. A. Wall, J. Appl. Polym. Sci., Part B: Polym. Lett., 4, 323 (1966).

    Article  CAS  Google Scholar 

  24. T. Vickerstaff, “The Physical Chemistry of Dyeing”, Imperial Chemical Industries, London, 1954.

    Google Scholar 

  25. Y.-H. Mao, Y. Guan, Q.-K. Zheng, X.-N. Feng, and X.-X. Wang, Cellulose (Dordrecht, Neth.), 18, 271 (2011).

    CAS  Google Scholar 

  26. A. S. Oezcan and A. Oezcan, J. Supercrit. Fluids, 35, 133 (2005).

    Article  CAS  Google Scholar 

  27. S. Yi, Y. Dong, B. Li, Z. Ding, X. Huang, and L. Xue, Color. Technol., 128, 306 (2012).

    Article  CAS  Google Scholar 

  28. V. K. Gupta, I. Ali, I. Suhas, and D. Mohan, J. Colloid Interface Sci., 265, 257 (2003).

    Article  CAS  Google Scholar 

  29. L. Liu, J. Zhang, and R.-C. Tang, React. Funct. Polym., 73, 1559 (2013).

    Article  CAS  Google Scholar 

  30. A. Roy, B. Adhikari, and S. B. Majumder, Ind. Eng. Chem. Res., 52, 6502 (2013).

    Article  CAS  Google Scholar 

  31. M. Chairat, S. Rattanaphani, J. B. Bremner, and V. Rattanaphani, Dyes Pigment., 64, 231 (2005).

    Article  CAS  Google Scholar 

  32. I. A. W. Tan, A. L. Ahmad, and B. H. Hameed, Colloid Surf. A-Physicochem. Eng. Asp., 318, 88 (2008).

    Article  CAS  Google Scholar 

  33. A. E. Ofomaja, Chem. Eng. J., 126, 35 (2007).

    Article  CAS  Google Scholar 

  34. H.-H. Wang, C.-C. Wang, and H.-J. Kuo, J. Appl. Polym. Sci., 76, 2105 (2000).

    Article  CAS  Google Scholar 

  35. M. Espinosa-Jimenez and A. Cano-Suarez, Text. Res. J., 65, 171 (1995).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Material Science and Engineering, Donghua University, Shanghai, 201620, China

    Lixia Gu

  2. Key Laboratory of Science & Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai, 201620, China

    Jun Wang, Xiaoyan Li & Zaisheng Cai

Authors
  1. Jun Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xiaoyan Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Zaisheng Cai
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Lixia Gu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Zaisheng Cai.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, J., Li, X., Cai, Z. et al. Absorption kinetics and thermodynamics of cationic dyeing on easily dyeable copolyester modified by 2-methyl-1,3-propanediol. Fibers Polym 16, 2384–2390 (2015). https://doi.org/10.1007/s12221-015-5224-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12221-015-5224-y

Keywords

Search

Navigation