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Use of 1,6-diaminohexane-functionalized glycidyl methacrylate-g-poly(ethylene terephthalate) fiber for removal of acidic dye from aqueous solution

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Abstract

In this study, removal of Congo red (CR) from aqueous solution by 1,6-diaminohexane-functionalized glycidyl methacrylate-g-poly(ethylene terephthalate) (HMDA-GMA-g-PET) fiber was investigated. A new aminated fibrous adsorbent was prepared by a reaction between amine and epoxy group in GMA-g-PET fiber prepared by grafting GMA monomer onto poly (ethylene terephthalate) (PET) fiber. Effects of various parameters such as pH, treatment time, initial, dye concentration, and reaction temperature on the adsorption amount of dye onto reactive fiber were investigated. The adsorption rates of CR were much higher on the HMDA-GMA-g-PET fiber than on GMA-g-PET and ungrafted PET fiber. The effective pH was 2.0 for adsorption on grafted PET fiber. It was found that the sufficient time to attain equilibrium was 60 min. The maximum adsorption capacity of the reactive fiber for CR is 16.6 mg/g fiber. The rates of adsorption were found to conform to the pseudo-second order kinetics with good correlation. It was found that the adsorption isotherm of CR fitted Freundlich type isotherm.

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  1. Department of Chemistry, Faculty of Science and Arts, Çankırı Karatekin University, 18100, Çankırı, Turkey

    Metin Arslan

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  1. Metin Arslan
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Arslan, M. Use of 1,6-diaminohexane-functionalized glycidyl methacrylate-g-poly(ethylene terephthalate) fiber for removal of acidic dye from aqueous solution. Fibers Polym 11, 177–184 (2010). https://doi.org/10.1007/s12221-010-0177-7

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  • DOI: https://doi.org/10.1007/s12221-010-0177-7

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