Skip to main content
SpringerLink
Log in

Steady-state Measurements of Ternary Mixtures in Thermogravitational Microcolumn Using Optical Digital Interferometry

  • Original Article
  • Published:
Microgravity Science and Technology Aims and scope Submit manuscript

Abstract

Steady-state measurements in a thermogravitational microcolumn using optical digital interferometry are presented here for the first time in the literature in the case of ternary mixtures. These measurements enabled the subsequent obtaining of thermodiffusion coefficients of a ternary mixture once convection reaches the steady-state. The ternary mixture used was the benchmark one, tetrahydronaphthalene (THN) – isobutylbenzene (IBB) and n-dodecane (nC12) with mass fraction of 0.8-0.1-0.1 respectively. Contrast factors due to the change in the concentration field were measured and compared with the corresponding ones in the literature. Uncertainty in the results was found to be of similar order of magnitude as in the case of Selectable Optical Diagnostic Instrument (SODI), which means that the condition number of that contrast factor matrix is almost equal to the present one. Final values of thermodiffusion coefficients were compared with the results reported from other optical techniques, as well as with the results obtained by the traditional long opaque thermogravitational columns (TGC). Some proposals were then made in order to improve accuracy reducing the condition number of the contrast factor matrix.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  • Ahadi, A., Saghir, M.Z.: The microgravity DSC-DCMIX1 mission onboard ISS: Experiment description and results on the measurement of the Soret coefficients for isobutylbenzene, dodecane, tetralin ternary hydrocarbons mixtures. Exp. Therm. Fluid Sci. 74, 296–307 (2016)

    Article  Google Scholar 

  • Blanco, P., Bou-Ali, M.M., Platten, J.K., Alonso de Mezquia, D., Madariaga, J.A., Santamaria, C.M.: Thermodiffusion coefficients of binary and ternary hydrocarbon mixtures. J. Chem. Phys. 132(11), 114506 (2010)

    Article  Google Scholar 

  • Bou-Ali, M.M., Ecenarro, O., Madariaga, J.A., Santamaría, C.M., Valencia, J.J.: Thermogravitational measurements of the Soret coefficient of liquid mixture. J. Phys. Condens. Matter 10, 3321–3331 (1998)

    Article  Google Scholar 

  • Bou-Ali, M.M., Ahadi, A., Alonso de Mezquia, D., Galand, Q., Gebhardt, M., Khlybov, O., Köhler, W., Larranaga, M., Legros, J.C., Lyubimova, T., Mialdun, A., Ryzhkov, I., Saghir, M.Z., Shevtsova, V., Van Vaerenbergh, S.: Benchmark values for the Soret, thermodiffusion and molecular diffusion coefficients of the ternary mixture tetralin + isobutylbenzene + n-dodecane with 0.8-0.1-0.1 mass fraction. Eur. Phys. J. E 38(4), 1–6 (2015)

    Article  Google Scholar 

  • De Mezquia, DAlonso, Mounir Bou-Ali, M., Larranaga, M., Madariaga, J.A., Santamaria, C.: Determination of molecular diffusion coefficient in n-Alkane binary mixtures: empirical correlations. J. Phys. Chem. B 116(9), 2814–2819 (2012)

    Article  Google Scholar 

  • Errarte, A., Bou-Ali, M.M., Aginagalde, M., Santamaria, C.: Thermodiffusion coefficients of nanofluid binary mixtures. Microgravity Sci. Technol. 31(6), 877–882 (2019)

    Article  Google Scholar 

  • Galand, Q., Van Vaerenbergh, S.: Measurement of diffusion and Soret coefficients of ternary system tetrahydronaphtalene-isobutylbenzene-n-dodecane with mass fraction 80-10-10 at 25°C. Eur. Phys. J. E. 38(4), 1–10 (2015)

  • Galand, Q., Van Vaerenbergh, S., Köhler, W., Khlybov, O., Lyubimova, T., Mialdun, A., Melnikov, D., Shevtsova, V., Triller, T.: Results of the DCMIX1 experiment on measurement of Soret coefficients in ternary mixtures of hydrocarbons under microgravity conditions on the ISS. J. Chem. Phys. 151(13), 134502 (2019)

    Article  Google Scholar 

  • Gebhardt, M., Köhler, W.: Contribution to the benchmark for ternary mixtures: Measurement of the Soret and thermodiffusion coefficients of tetralin + isobutylbenzene + n-dodecane at a composition of (0.8/0.1/0.1) mass fraction by two-color optical beam deflection. Eur. Phys. J. E 38(4), 24 (2015)

    Article  Google Scholar 

  • Khouzam, A., Charrier-Mojtabi, M.-C., Mojtabi, A., Ouattara, B.: A new process for species separation in a binary mixture using mixed convection. In: ICHMT Digital Library Online. Bath, Begel House Inc. (2012)

    Google Scholar 

  • Königer, A., Wunderlich, H., Köhler, W.: Measurement of diffusion and thermal diffusion in ternary fluid mixtures using a two-color optical beam deflection technique. J. Chem. Phys. 132(17), 174506 (2010)

    Article  Google Scholar 

  • Kozlova, S.V., Ryzhkov, I.I.: On the separation of multicomponent mixtures in a cylindrical thermogravitational column. Phys. Fluids 28(11), 117102 (2016)

    Article  Google Scholar 

  • Lapeira, E., Bou-Ali, M.M., Madariaga, J.A., Santamaria, C.: Thermodiffusion coefficients of water/ethanol mixtures for low water mass fractions. Microgravity Sci. Technol. 28(5), 553–557 (2016)

    Article  Google Scholar 

  • Lapeira, E., Gebhardt, M., Triller, T., Mialdun, A., Köhler, W., Shetvsova, V., Bou-Ali, M.M.: Transport properties of the binary mixtures of the three organic liquids touluene, methanol and cyclohexane. J. Chem. Phys. 146(9), 094507 (2017)

    Article  Google Scholar 

  • Lapeira, E., Mialdun, A., Yasnou, V., Aristimuno, P.X., Shevtsova, V.: M.M. Bou-Ali, Digital Interferometry Applied to thermogravitational technique. Microgravity Sci. Technolog 30(5), 635–641 (2018)

    Article  Google Scholar 

  • Larranaga, M., Andrew, D., Rees, S., Bou-Ali, M.M.: Determination of the molecular diffusion coefficients in ternary mixtures by sliding symmetric tubes technique. J. Chem. Phys. 140(5), 054201 (2014a)

    Article  Google Scholar 

  • Larranaga, M., Bou-Ali, M.M., Lapeira, E., Santamaria, C., Madariaga, J.A.: Effect of thermophysical properties and morphology of the molecules on thermodiffusion coefficient of binary mixtures. Microgravity Sci. Technol 26(1), 29–35 (2014)

    Article  Google Scholar 

  • Larranaga, M., Bou-Ali, M.M., de Mezquia, D.A., Andrew, D., Rees, S., Madariaga, J.A., Santamaria, C., Platten, J.K.: Contribution to the benchmark for ternary mixtures: Determination of Soret coefficients by the thermogravitational and the sliding symmetric tubes techniques. Eur. Phy. J. E 38(4), 28 (2015)

    Article  Google Scholar 

  • Larre, J.P., Platten, J.K., Chavepeyer, G.: Soret effects in ternary systems heated from bellow. Int. J. Heat Mass Tran. 40(3), 545–555 (1997)

    Article  Google Scholar 

  • Leahy-Dios, A., Bou-Ali, M.M., Platten, J.K., Firoozabadi, A.: Measurements of molecular and thermal diffusion coefficients in ternary mixtures. J. Chem. Phys. 122(23), 234502 (2005)

    Article  Google Scholar 

  • Martin-Mayor, A., Bou-Ali, M.M., Aginagalde, M., Urteaga, P.: Microfluidic separation processes using the thermodiffusion effect. Int. J. Therm. Sci. 124, 279–287 (2018)

    Article  Google Scholar 

  • Mialdun, A., Shevtsova, V.: Communication: New approach for analysis of thermodiffusion coefficients in ternary mixtures. J. Chem. Phys. 138(16), 161102 (2013)

    Article  Google Scholar 

  • Mialdun, A., Legros, J.C., Yasnou, V., Sechenyh, V., Shevtsova, V.: Contribution to the benchmark for ternary mixtures: Measurements of the Soret, diffusion and thermodiffusion coefficients in the ternary mixture THN/IBB/nC12 with 0.8/0.1/0.1 mass fractions in ground and orbital laboratories. Eur. Phys. J. E 38(4), 27 (2015)

    Article  Google Scholar 

  • Mialdun, A., Shevtsova, V.: Analysis of multi-wavelength measurements of diffusive properties via dispersion dependence of optical properties. Appl. Optics 56(3), 572–581 (2017)

    Article  Google Scholar 

  • Mialdun, A., Ryzhkov, I., Khlybov, O., Lyubimova, T., Shevtsova, V.: Measurement of Soret coefficients in a ternary mixture of toluene-methanol-cyclohexane in convection-free environment. J. Chem. Phys. 148(4), 044506 (2018)

    Article  Google Scholar 

  • Mialdun, A., Bataller, H., Bou-Ali, M.M., Braibanti, M., Croccolo, F., Errarte, A., Ezquerro, J.M., Fernandez, J.J., Gaponenko, Yu, Garcia-Fernandez, L., Rodriguez, J., Shevtsova, V.: Preliminary analysis of Diffusion Coefficient Measurements in ternary mIXtures 4 (DCMIX4) experiment on board the International Space Station. Eur. Phys. J. E 42(7), 87 (2019)

    Article  Google Scholar 

  • Naumann, P., Martin, A., Kriegs, H., Larranaga, M., Bou-Ali, M.M., Wiegand, S.: Development of a Thermogravitational Micro-column with an interferometric contracless detection system. J. Phys. Chem. B 116(47), 13889–13897 (2012)

    Article  Google Scholar 

  • Ning, H., Wiegand, S.: Experimental investigation of the Soret effect in acetone/water and dimethylsulfoxide/water mixtures. J. Chem. Phys. 125(22), 221102 (2006)

    Article  Google Scholar 

  • Sechenyh, V., Legros, J.C., Shevtsova, V.: Development and validation of a new setup for measurements of diffusion coefficents in ternary mixtures using the Taylor dispersion technique. CR Mechanique 341(4–5), 490–496 (2013a)

    Article  Google Scholar 

  • Sechenyh, V., Legros, J.C.. Shevtsova, V.: Optical properties of binary and ternary liquid mixtures containing tetralin, isobutylbenzene and dodecane. J. Chem. Thermodyn. 62, 64–68 (2013b)

    Article  Google Scholar 

  • Šeta, B., Lapeira, E., Dubert, D., Gavalda, F., Bou-Ali, M.M., Ruiz, X.: Separation under thermogravitational effects in binary mixtures. Eur. Phys. J. E 42(5), 58 (2019a)

    Article  Google Scholar 

  • Šeta, B., Errarte, A., Dubert, D., Gavalda, J., Bou-Ali, M.M., Ruiz, X.: Gravitational stability analysis on double diffusion convection in ternary mixtures. Acta Astronaut. 160, 442–450 (2019b)

    Article  Google Scholar 

  • Šeta, B., Gavaldà, J., Bou-Ali, M.M., Ruiz, X., Santamaria, C.: (2019c) Determining diffusion, thermodiffusion and Soret coefficients by the thermogravitational technique in binary Mixture with optical digital interferometry analysis. Int. J. Heat Mass Tran. 147, 118935 (2020)

    Article  Google Scholar 

  • Triller, T., Sommermann, D., Schraml, M., Sommer, F., Lapeira, E., Bou-Ali, M.M., Köhler, W.: The Soret effect in ternary mixtures of water + ethanol + triethylene glycol of equal mass fractions: Ground and microgravity experiments. Eur. Phys. J. E 42(3), 1–11 (2019)

    Article  Google Scholar 

  • Yahya, M., Saghir, M.Z.: Prediction and experimental measurements of refractive index in ternary hydrocarbon mixtures. J. Chem. Eng. Data 60(8), 2329–2342 (2015)

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the Ministerio de Ciencia, Innovación y Universidades and the European Regional Development Fund (FEDER) (grant numbers: ESP2017-83544-C3-1-P and ESP2017-83544-C3-3-P) and by a DCMIX (AO-2009-0858/1056) from the European Space Agency. It was also supported by the Research Group Program (IT1009-16) and µ4F (KK-2019/0010) from the Basque Government and the Universitat Rovira i Virgili (URV) (grant number DLRF4741).

Author information

Authors and Affiliations

  1. Universitat Rovira i Vigili, Tarragona, Spain

    Berin Šeta, Jna. Gavalda & Xavier Ruiz

  2. Mondragon Unibersitatea, Mondragon, Spain

    Estela Lapeira & M. Mounir Bou-Ali

Authors
  1. Berin Šeta
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Estela Lapeira
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jna. Gavalda
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. Mounir Bou-Ali
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Xavier Ruiz
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Berin Šeta.

Ethics declarations

Conflict of Interest

There are no conflicts to declare.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

This article belongs to the Topical Collection: The Effect of Gravity on Physical and Biological Phenomena

Guest Editor: Valentina ‎Shevtsova

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Šeta, B., Lapeira, E., Gavalda, J. et al. Steady-state Measurements of Ternary Mixtures in Thermogravitational Microcolumn Using Optical Digital Interferometry. Microgravity Sci. Technol. 33, 18 (2021). https://doi.org/10.1007/s12217-020-09861-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12217-020-09861-5

Keywords

Search

Navigation