Skip to main content
Log in

On an Effect of Fine Ceramic Particles on the Structure of Aerogels

  • Original Article
  • Published:
Microgravity Science and Technology Aims and scope Submit manuscript

Abstract

The addition of ferroelectric microparticles embedded in a nanostructured silica aerogel modifies the dry gel microstructure in a measurable way. The pore size distribution changes as well as the specific surface area. This indicates a possible positive effect of particles on the gelation characteristics. These modifications were observed in solutions gelling during a sounding rocket experiment in which approximately three minutes microgravity provided sufficient time for a convection and sedimentation free gelation to occur. The paper describes the synthesis procedures and the microstructures obtained for the gels under microgravity conditions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13

Similar content being viewed by others

References

  • Hüsing, N., Schubert, U.: Aerogels – Airy Materials: Chemistry, Structure, and Properties. Angew. Chem. Int. Ed., 37 (1998)

  • Aegerter, M.A., Leventis, N., Koebel, M.: Handbook on Aerogels. Springer Verlag Heidelberg (2011)

  • Lisinski, S., Schaniel, D., Ratke, L., Woike, Th.: Second harmonic generation by ferroelectric microparticles in composite aerogels. Chem. Mater. 18, 1534–1538 (2006)

    Article  Google Scholar 

  • Lisinski, S., Ratke, L.: Preparation of nonlinear optical aerogels and xerogels in parabolic flights. Microgravity Sci. Techn. 20, 1–5 (2008)

    Article  Google Scholar 

  • Xu, Y.: Ferroelectric materials and their applications. North-Holland, Amsterdam (1991)

    Google Scholar 

  • Günter, P.: Nonlinear Optical Effects and Materials. Springer, Berli (1999)

    Google Scholar 

  • Primera, J., Woignier, T., Hasmy, A.: Pore Structure Simulation of Gels with a Binary Monomer Size Distribution. J. Sol-Gel Sci. Techn. 34, 273–280 (2005)

    Article  Google Scholar 

  • Fuchs, N.: The Mechanics of Aerosols. Pergamon Press, Oxford (1964)

    Google Scholar 

  • Brück, S., Reuß, M., Richter, H.E., Klein, H., Haubner, P., Ratke, L.: Gelation of aerogels in parabolic flights and on the ISS. Microgravity Sci. Technol. 16, 31–34 (2005)

    Article  Google Scholar 

  • Stamminger, A., Ettl, J., Blochberger, G., Drescher, J., Griesche, A., Hoepfner, S., Hörschgen, M., Meyer, A., Neumann, C., Ratke, L., Plescher, E., Willnecker, R.: MAPHEUS-1: Vehicle, Subsystem Design, Flight Performance and Experiments, In: Proceedings of the 19th ESA Symposium on European Rocket and Balloon Programmes and Related Research, ESA Communication Production Office, Noordwijk, ISBN 978-92-9221-235-3, pp. 411–416 (2009)

  • Sing, K.S.W., Everett, D.H., Haul, R.A.W., Moscou, L., Pierotti, R.A., Rouquérol, J., Siemieniewska, T.: Reporting Physisorption Data for Gas/Solid Systems with Special Reference to the Determination of Surface Area and Porosity. Pure & Appl. Chem. 57 (1985)

  • Lisinski, S.: Synthese und nichtlineare optische Eigenschaften von Hybrid-Aerogelen mit ferroelektrischen Nano- und Mikropartikeln, Diploma thesis. University of Cologne, Germany (2005)

    Google Scholar 

  • Lisinski, S.: Synthese und Charakterisierung von ferroelektrischen Xerogelen, PhD thesis. RWTH Aachen, Germany (2008)

    Google Scholar 

  • Christian, J., 2nd ed.: The Theory of Phase Transformation in Metals andAlloys. Pergamon Press, Elmsford NY (1975)

    Google Scholar 

Download references

Acknowledgements

2005 The authors appreciate first the help of the MAPHEUS sounding rocket team at DLR, especially Dipl.-Ing. H.E. Richter, who designed the facility to our requirements and had ingenious ideas for realizations. We highly appreciate the help of the team around Prof. Irina Smirnova from the Technical University of Hamburg, Institut für Thermische Verfahrenstechnik, providing the facilities to supercritically dry the samples.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Lorenz Ratke.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ratke, L., Milow, B., Lisinski, S. et al. On an Effect of Fine Ceramic Particles on the Structure of Aerogels. Microgravity Sci. Technol. 26, 103–110 (2014). https://doi.org/10.1007/s12217-014-9380-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12217-014-9380-2

Keywords

Navigation