Abstract
The training activities of the Italian Military Forces are currently being conducted in over one hundred military firing ranges over the national territory. The large-scale firing range, named “Poligono Interforze Salto di Quirra (PISQ)” is located in Sardinia. PISQ is divided into two main areas: one for ground fire training exercises, and the other for training at sea. This work summarizes and discusses the large amount of analytical data produced for the geochemical characterization of the ground firing range and the surrounding areas, with particular attention to uranium, tungsten and thorium concentration levels in soils. Mining activities, even if long since stopped, have affected the region for a long time, while, more recently, the environmental legislation was subjected to a continuous evolution imposing new limits with the aim of protecting the environment. The studies carried out in the period 2002–2015 aimed, in particular, to verify if the concentrations of uranium, thorium and tungsten in soils of the firing range area have been enhanced by military training operations, causing a risk for the environment and the human health. Results seem to exclude this hypothesis; moreover it was demonstrated that depleted uranium is practically absent in the area.
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References
Armiento G, Nardi E, Lucci F, De Cassan M, Della Ventura G, Santini C, Petrini E, Cremisini C (2016) Antimony and arsenic contamination in a catchment affected by past mining activities: influence of extreme weather events. Rend Fis Acc Lincei. doi:10.1007/s12210-016-0566-y
Benvegnù F, Brondi A, Ferretti O, Rabottino L (1974) Ricerca di concentrazioni detritiche di minerali di interesse nucleare in Sardegna. Rendiconti della Società di Mineralogia e Petrologia 30:133–157
Bleise A, Danesi PR, Burkart W (2003) Properties, use and health effects of depleted uranium (DU): a general overview. J Environ Radioact 64:93–112
Carvalho FP, Oliveira JM (2010) Uranium isotopes in the Balkan’s environment and foods following the use of depleted uranium in the war. Environ Int 36:352–360. doi:10.1016/j.envint.2010.02.003
Danesi PR, Bleise A, Burkart W, Cabianca T, Campbell MJ, Makarewicz M, Moreno J, Tuniz C, Hotchkis M (2003) Isotopic composition and origin of uranium and plutonium in selected soil samples collected in Kosovo. J Environ Radioact 64:121–131
Da Pelo S, Musu E, Cidu R, Frau F, Lattanzi P (2009) Release of toxic elements from rocks and mine wastes at the Furtei gold mine (Sardinia, Italy). J Geochem Explor 100:142–152. doi:10.1016/j.gexplo.2008.06.006
Di Lella LA, Frati L, Loppi S, Protano G, Riccobono F (2004) Environmental distribution of uranium and other trace elements at selected Kosovo sites. Chemosphere 56:861–865. doi:10.1016/j.chemosphere.2004.04.036
Di Lella LA, Nannoni F, Protano G, Riccobono F (2005) Uranium contents and 235U/238U atom ratios in soil and earthworms in western Kosovo after the 1999 war. Sci Total Environ 337(1–3):109–118. doi:10.1016/j.scitotenv.2004.07.001
Frau F, Ardau C (2003) Geochemical controls on arsenic distribution in the Baccu Locci stream catchment (Sardinia, Italy) affected by past mining. Appl Geochem 18(9):1373–1386. doi:10.1016/S0883-2927(03)00057-X
Frau F, Ardau C, Fanfani L (2009) Environmental geochemistry and mineralogy of lead at the old mine area of Baccu Locci (south-east Sardinia, Italy). J Geochem Explor 100(2, 3):105–115. doi:10.1016/j.gexplo.2008.01.005
Frau F, Cidu R, Ardau C (2012) Short-term changes in water chemistry in the Baccu Locci stream (Sardinia, Italy) affected by past mining. Appl Geochem 27(9):1844–1853. doi:10.1016/j.apgeochem.2012.02.019
Frau F, Podda F, Da Pelo S, Ardau C (2013) Comparison of pre- and post-remediation stream water chemistry in the arsenic-contaminated Baccu Locci mine watershed (Italy): preliminary data. Proc Earth Planet Sci 7:268–271. doi:10.1016/j.proeps.2013.03.070
Gulf War Illness and the Health of Gulf War Veterans: Research Update and Recommendations, 2009–2013 (2014) U.S. Government Printing Office, Washington DC (USA). https://www.bu.edu/sph/files/2014/04/RAC2014.pdf. Accessed 21 Feb 2017
Handley-Sidhu S, Keith-Roach MJ, Lloyd JR, Vaughan DJ (2010) A review of the environmental corrosion, fate and bioavailability of munitions grade depleted uranium. Sci Total Environ 408:5690–5700. doi:10.1016/j.scitotenv.2010.08.028
Hon Z, Österreicher J, Navrátil L (2015) Depleted uranium and its effects on humans. Sustainability 7:4063–4077. doi:10.3390/su7044063
JSP 392 (2014) Management of Radiation Protection in Defence Milan missile. https://www.gov.uk/government/uploads/system/uploads/attachment_data/file/383654/JSP392_Lft_29_Thorium.pdf. Accessed 17 Feb 2017
Labbate S (2009) La politica energetica dell’Italia repubblicana tra interesse nazionale e vincoli atlantici (1945–1975). Dissertation, Sapienza University, Rome http://padis.uniroma1.it/bitstream/10805/929/1/TESI_VERSIONE_DEFINITIVA.pdf. Accessed 20 Feb 2017
Lind OC, Salbu B, Skipperud L, Janssens K, Jaroszewicz J, De Nolf W (2009) Solid state speciation and potential bioavailability of depleted uranium particles from Kosovo and Kuwait. J Environ Radioact 100:301–307. doi:10.1016/j.jenvrad.2008.12.018
Lumbau A, Carboni D, Ginesu S, Schinocca L, Sias S, Chessa G (2007) Territorio, radioattività naturale e salute in alcune aree della Sardegna. Prime osservazioni ed affinamento delle tecniche. In: Proceedings of Session “Geology and Health”, Geoitalia Congress, Rimini, pp 67–69
Manconi F (1999) Sulle condizioni dell’industria mineraria della Sardegna/Quintino Sella. Ilisso Edizioni, Nuoro. http://www.sardegnacultura.it/documenti/7_26_20060401172405.pdf
Mc Laughlin JP (2005) Exposure potential of depleted uranium ammunition in the environment—a review. Radioact Environ 7:95–104. doi:10.1016/S1569-4860(04)07010-X
McLaughlin JP, Vintrò LL, Smith KJ, Mitchell PI, Žunić ZS (2003) Actinide analysis of a depleted uranium penetrator from a 1999 target site in southern Serbia. J Environ Radioact 64:155–165
Oeh U, Priest ND, Roth P, Ragnarsdottir KV, Li WB, Höllriegl V, Thirlwall MF, Michalke B, Giussani A, Schramel P, Partezke HG (2007) Measurements of daily urinary uranium excretion in German peacekeeping personnel and residents of the Kosovo region to assess potential intakes of depleted uranium (DU). Sci Total Environ 381:77–87. doi:10.1016/j.scitotenv.2007.03.024
Protocollo d’intesa in materia di tutela ambientale ed attività esercitative miliari (2015) MATTM/MOD Agreement. http://www.minambiente.it/sites/default/files/archivio_immagini/Galletti/PROTOCOLLO%20AMBIENTE%20DIFESA%20definitivo.pdf. Accessed 21 Feb 2017
Sahoo KS, Mishra S, Žunić ZS, Arae H, Gjiergj F, Stegnar P, Benedik L, Repinic U, Kristsananuwat R (2014) Distribution of uranium and selected trace metals in Balkan human scalp hair using inductively coupled plasma mass spectrometry. Int J Mass Spectrom 373:15–21. doi:10.1016/j.ijms.2014.08.020
Salbu B, Janssens K, Lind OC, Proost K, Gijsels L, Danesi PR (2005) Oxidation states of uranium in depleted uranium particles from Kuwait. J Environ Radioact 78:125–135. doi:10.1016/j.jenvrad.2004.04.001
Sansone U, Danesi PR, Barbizzi S, Belli M, Campbell M, Gaudino S, Guogang J, Ocone R, Pati A, Rosamilla S, Stellato L (2001) Radioecological survey at selected sites hit by depleted uranium ammunitions during the 1999 Kosovo conflict. Sci Total Environ 281:23–35
Single European Act (1987) VII art. 130R. http://www.consilium.europa.eu/uedocs/cmsUpload/SingleEuropeanAct_Crest.pdf. Accessed 21 Feb 2017
Technical Board Report (2011) Progetto di caratterizzazione ambientale e sanitaria nelle aree adiacenti il PISQ—Relazione finale della Commissione Tecnica Mista di Esperti. http://www.sardegnafuturo.it/wp-content/uploads/2016/03/Relazione%20comitato%20tecnico%20di%20esperti.%202011.pdf. Accessed 21 Feb 2017
Toxicological Profile for Uranium (2011) Agency for Toxic Substances and Disease Registry—Division of Toxicology and Environmental Medicine—Applied Toxicology Branch, pp 289–291. https://www.atsdr.cdc.gov/toxprofiles/tp150.pdf. Accessed 21 Feb 2017
Yousefi H, Najafi A (2013) Assessment of depleted uranium in South-Western Iran. J Environ Radioact 124:160–162. doi:10.1016/j.jenvrad.2013.05.001
Zampetti G, Nicoletti A (2014) Indagine conoscitiva in materia di servitù militari—Memoria depositata nell’ambito dell’audizione dei rappresentati di Legambiente presso la Commissione Difesa della Camera dei deputati nell’ambito dell’indagine conoscitiva in materia di servitù militari. http://documenti.camera.it/leg17/resoconti/commissioni/stenografici/pdf/04/indag/c04_militari/2014/05/29/leg.17.stencomm.data20140529.U1.com04.indag.c04_militari.0008.pdf. Accessed 20 Feb 2017
Acknowledgements
Authors wish to thank Prof. Francesco Riccobono, Prof. Mario Mariani, SGS and Ambiente SC Analytical Laboratories for their fundamental contribution to the development of this work. Authors wish to thank also Salvatore Mannino and Fabio Molteni for their steady motivation and support to complete this work. Finally authors wish to thank Ph.D. Ferdinando F. Bruno for his useful suggestions.
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Bernabei, M., Chiappa, A., Bandiera, A. et al. Uranium, thorium and tungsten concentration measured in the soil of Italian Military Forces firing range “Poligono Interforze Salto di Quirra”: natural background or enhancement of concentration levels caused by military activities?. Rend. Fis. Acc. Lincei 28, 329–339 (2017). https://doi.org/10.1007/s12210-017-0614-2
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DOI: https://doi.org/10.1007/s12210-017-0614-2