Abstract
Existing methods for synthesizing p-benzoquinone have drawbacks with respect to environmental protection, production scale, or industrial value. Therefore, it is imperative that a simple and environmentally friendly alternative be developed. The approach that involves preparing p-benzoquinone by the catalytic oxidation of benzene with hydrogen peroxide (H2O2) over copper-modified titanium silicalite-1 (Cu/TS-1) has a certain superiority due to its green synthesis and mild reaction conditions. In this study, Cu/TS-1 catalyst was prepared by the wet impregnation of TS-1 with an aqueous solution of Cu(NO3)2 and then characterized by X-ray diffraction, Fourier transform infrared spectroscopy, diffuse reflectance UV–Vis spectroscopy, scanning electron microscopy, inductively coupled plasma mass spectrometry, X-ray fluorescence, and analysis of the N2 adsorption–desorption isotherms. The results reveal that Cu species exist mainly in the form of amorphous CuO that is well dispersed on the surface of catalysts, with no major change in the molecular sieve framework. After optimizing the reaction conditions, a desirable p-benzoquinone selectivity (88.4%) and benzene conversion (18.3%) were obtained when the doping of Cu in Cu/TS-1 is 1.95 wt%. In addition, Cu/TS-1 can be conveniently regenerated, showing a slight decrease in catalytic capability after initial use, which then stabilizes in subsequent circulations. The satisfactory stability and low cost of synthesizing Cu/TS-1 give this method considerable potential for further industrialization.
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References
Qin C, Matsushima T, Fujihara T et al (2017) Multifunctional benzoquinone additive for efficient and stable planar perovskite solar cells. Adv Mater 29(4):1603808
Stejskal J, Bober P, Trchova M et al (2018) Oxidation of pyrrole with p-benzoquinone to semiconducting products and their application in electrorheology. New J Chem 42(12):10167–10176
Young SM, Chu-Xia D, Hoeijmarkers JH et al (2016) A mechanism for 1,4-benzoquinone-induced genotoxicity. Oncotarget 7(29):46433–46447
Mazzei L, Cianci M, Musiani F et al (2016) Inactivation of urease by 1,4-benzoquinone: chemistry at the protein surface. Dalton Trans 45(13):5455–5459
Jonas K (1956) Process for the manufacture of benzoquinone. US 2,731,478. 1956-01-17
Cason J (1948) Synthesis of benzoquinones by oxidation. Org React 1948(4):305–361
Reilly EL (1981) Oxidation of phenol to p-benzoquinone in acetonitrile/methanol cosolvent. US 4,257,968. 1981-03-24
Maiti SK, Dinda S, Banerjee S et al (2008) Oxidoperoxidotungsten (VI) complexes with secondary hydroxamic acids: synthesis, structure and catalytic uses in highly efficient, selective and ecologically benign oxidation of olefins, alcohols, sulfides and amines with H2O2 as a terminal oxidant. Eur J Inorg Chem 12:2038–2051
Tsuji T, Zaoputra AA, Hitomi Y et al (2017) Specific enhancement of catalytic activity by a dicopper core: selective hydroxylation of benzene to phenol with hydrogen peroxide. Angew Chem Int Ed 56(27):7779–7782
Radel RJ, Sullivan JM, Hatfield JD (1982) Catalytic oxidation of hydroquinone to quinone using molecular oxygen. Ind Eng Chem Prod Res Dev 21(4):566–570
Montilla F, Morallón E, Vázquez JL (2003) Electrochemical study of benzene on Pt of various surface structures in alkaline and acidic solutions. Electrochim Acta 47(27):4399–4406
Li X, Li X, Tang S et al (2014) High selectivity of benzene electrochemical oxidation to p-benzoquinone on modified PbO2 electrode. Appl Surf Sci 311:357–361
Montilla F, Huerta F, Morallon E et al (2000) Electrochemical behaviour of benzene on platinum electrodes. Electrochim Acta 45(25–26):4271–4277
Taramasso M, Perego G, Notari B (1983) Preparation of porous crystalline synthetic material comprised of silicon and titanium oxides. US 4,410,501. 1983-10-18
Tanev PT, Chibwe M, Pinnavaia TJ (1994) Titanium-containing mesoporous molecular sieves for catalytic oxidation of aromatic compounds. Nature 368(6469):321
Zhang T, Chen X, Chen G et al (2018) Synthesis of anatase-free nano-sized hierarchical TS-1 zeolites and their excellent catalytic performance in alkene epoxidation. J Mater Chem A 6(20):9473–9479
Thangaraj A, Sivasanker S, Ratnasamy P (1991) Catalytic properties of crystalline titanium silicalites III. Ammoximation of cyclohexanone. J Catal 131(2):394–400
Maspero F, Romano U (1994) Oxidation of alcohols with H2O2 catalyzed by titanium silicalite-1. J Catal 146(2):476–482
Shul’pin GB, Kirillova MV, Sooknoi T et al (2008) Oxidation of saturated hydrocarbons to alkyl hydroperoxides by a ‘H2O2/titanosilicalite-1/NaOH/MeCN’ system. Catal Lett 123(1–2):135–141
Juan Z, Dishun Z, Liyan Y et al (2010) Photocatalytic oxidation dibenzothiophene using TS-1. Chem Eng J 156(3):528–531
Bonino F, Damin A, Ricchiardi G et al (2004) Ti-peroxo species in the TS-1/H2O2/H2O system. J Phys Chem B 108(11):3573–3583
Bhaumik A, Mukherjee P, Kumar R (1998) Triphase catalysis over titanium–silicate molecular sieves under solvent-free conditions: I. Direct hydroxylation of benzene. Journal of Catalysis 178(1):101–107
Hammond C, Forde MM, Ab Rahim MH et al (2012) Direct catalytic conversion of methane to methanol in an aqueous medium by using copper-promoted Fe-ZSM-5. Angew Chem Int Ed 51(21):5129–5133
Liu Q, Zuo H, Wang T et al (2013) One-step hydrodeoxygenation of palm oil to isomerized hydrocarbon fuels over Ni supported on nano-sized SAPO-11 catalysts. Appl Catal A 468:68–74
Wang L, Kong A, Chen B et al (2005) Direct synthesis, characterization of Cu-SBA-15 and its high catalytic activity in hydroxylation of phenol by H2O2. J Mol Catal A Chem 230(1–2):143–150
Kondratenko EV, Cherian M, Baerns M et al (2005) Oxidative dehydrogenation of propane over V/MCM-41 catalysts: comparison of O2 and N2O as oxidants. J Catal 234(1):131–142
Ito S, Kunai A, Okada H et al (1988) Direct conversion of benzene to hydroquinone. Cooperative action of copper (I) ion and dioxygen. J Org Chem 53(2):296–300
Gao S, Yang H, Li J et al (2013) Method for preparing 1,4-benzoquinone by directly oxidizing benzene. CN 103,172,508 (A). 2013-06-26
Kunai A, Wani T, Uehara Y et al (1989) Catalytic oxygenation of benzene. Catalyst design and its performance. Bull Chem Soc Jpn 62(8):2613–2617
Cundy CS, Forrest JO, Plaisted RJ (2003) Some observations on the preparation and properties of colloidal silicalites. Part I: synthesis of colloidal silicalite-1 and titanosilicalite-1 (TS-1). Microporous Mesoporous Mater 66(2–3):143–156
Chou B, Tsai JL, Cheng S (2001) Cu-substituted molecular sieves as liquid phase oxidation catalysts. Microporous Mesoporous Mater 48(1):309–317
Kumar R, Mukherjee P, Bhaumik A (1999) Enhancement in the reaction rates in the hydroxylation of aromatics over TS-1/H2O2 under solvent-free triphase conditions. Catal Today 49(1–3):185–191
Song Z, Feng X, Sheng N et al (2018) Propene epoxidation with H2 and O2 on Au/TS-1 catalyst: Cost-effective synthesis of small-sized mesoporous TS-1 and its unique performance. Catal Today. https://doi.org/10.1016/j.cattod.2018.04.068
Sheng N, Liu Z, Song Z et al (2018) Enhanced stability for propene epoxidation with H2 and O2 over wormhole-like hierarchical TS-1 supported Au nanocatalyst. Chem Eng J. https://doi.org/10.1016/j.cej.2018.09.115
Bengoa JF, Gallegos NG, Marchetti SG et al (1998) Influence of TS-1 structural properties and operation conditions on benzene catalytic oxidation with H2O2. Microporous Mesoporous Mater 24(4–6):163–172
Zhang C, Lv W, Zhou G et al (2018) Vertically aligned lithiophilic CuO nanosheets on a Cu collector to stabilize lithium deposition for lithium metal batteries. Adv Energy Mater. https://doi.org/10.1002/aenm.201703404
Ni S, Lv X, Li T et al (2013) A novel electrochemical activation effect induced morphology variation from massif-like CuxO to forest-like Cu2O nanostructure and the excellent electrochemical performance as anode for Li-ion battery. Electrochim Acta 96:253–260
Yu J, Cao J, Du L et al (2018) Enhancement of diethyl malonate hydrogenation to 1, 3-propanediol using mesoporous Cu/SBA-15 as catalyst. Appl Catal A 555:161–170
Wu G, Lin Z, Li L et al (2017) Experiments and kinetics of the epoxidation of allyl chloride with H2O2 over organic base treated TS-1 catalysts. Chem Eng J 320:1–10
Feng X, Duan X, Yang J et al (2015) Au/uncalcined TS-1 catalysts for direct propene epoxidation with H2 and O2: effects of Si/Ti molar ratio and Au loading. Chem Eng J 278:234–239
Ricchiardi G, Damin A, Bordiga S et al (2001) Vibrational structure of titanium silicate catalysts. A spectroscopic and theoretical study. J Am Chem Soc 123(46):11409–11419
Kerton OJ, McMorn P, Bethell D et al (2005) Effect of structure of the redox molecular sieve TS-1 on the oxidation of phenol, crotyl alcohol and norbornylene. Phys Chem Chem Phys 7(13):2671–2678
Thangaraj A, Kumar R, Mirajkar SP et al (1991) Catalytic properties of crystalline titanium silicalites I. Synthesis and characterization of titanium-rich zeolites with MFI structure. J Catal 130(1):1–8
Du S, Chen X, Sun Q et al (2016) A non-chemically selective top-down approach towards the preparation of hierarchical TS-1 zeolites with improved oxidative desulfurization catalytic performance. Chem Commun 52(17):3580–3583
Wang L, Gaudet JR, Li W et al (2013) Migration of Cu species in Cu/SAPO-34 during hydrothermal aging. J Catal 306:68–77
Cao Y, Feng X, Xu H et al (2016) Novel promotional effect of yttrium on Cu-SAPO-34 monolith catalyst for selective catalytic reduction of NOx by NH3 (NH3-SCR). Catal Commun 76:33–36
Prasad MR, Kamalakar G, Kulkarni SJ et al (2002) Synthesis of binaphthols over mesoporous molecular sieves. J Mol Catal A Chem 180(1–2):109–123
Feng X, Song Z, Liu Y et al (2018) Manipulating gold spatial location on titanium silicalite-1 to enhance the catalytic performance for direct propene epoxidation with H2 and O2. ACS Catal 8(11):10649–10657
Feng X, Yang J, Duan X et al (2018) Enhanced catalytic performance for propene epoxidation with H2 and O2 over bimetallic Au–Ag/uncalcined titanium silicate-1 catalysts. ACS Catal 8(9):7799–7808
Parida KM, Rath D, Dash SS (2010) Synthesis, characterization and catalytic activity of copper incorporated and immobilized mesoporous MCM-41 in the single step amination of benzene. J Mol Catal A Chem 318(1–2):85–93
Bradu C, Frunza L, Mihalche N et al (2010) Removal of Reactive Black 5 azo dye from aqueous solutions by catalytic oxidation using CuO/Al2O3 and NiO/Al2O3. Appl Catal B 96(3–4):548–556
Potekhin VV, Kulikova VA, Kochina EG et al (2011) Decomposition of hydrogen peroxide in protic and polar aprotic solvents on TS-1 heterogeneous catalyst. Russ J Appl Chem 84(7):1195
Spinacé EV, Schuchardt U, Cardoso D (1999) Oxidation of hydrocarbons with peroxides catalyzed by chromium (III) and iron (III) incorporated in SAPO-37 framework. Appl Catal A 185(2):L193–L197
Ito S, Yamasaki T, Okada H et al (1988) Oxidation of benzene to phenols with molecular oxygen promoted by copper (I) chloride. J Chem Soc Perkin Trans 2(3):285–293
Balducci L, Bianchi D, Bortolo R et al (2003) Direct oxidation of benzene to phenol with hydrogen peroxide over a modified titanium silicalite. Angew Chem 115(40):5087–5090
Hine J, Redding RW (1970) Equilibrium in the addition of hydrogen peroxide, water, and methanol to acetone. J Org Chem 35(8):2769–2772
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This study was supported by the National Natural Science Foundation of China (No. 21376163).
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Li, C., Zhang, Q. & Zeng, A. A Novel Method for Synthesizing p-Benzoquinone by Direct Catalytic Oxidation of Benzene with Hydrogen Peroxide over Copper-Doped TS-1. Trans. Tianjin Univ. 25, 517–526 (2019). https://doi.org/10.1007/s12209-019-00216-9
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DOI: https://doi.org/10.1007/s12209-019-00216-9