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Transactions of Tianjin University

, Volume 23, Issue 3, pp 221–229 | Cite as

Synthesis and Application of Novel Triazine-Based Charring-Foaming Agents in Intumescent Flame Retardant Polypropylene

  • Ligong Chen
  • Yanyan Yuan
  • Bowei Wang
  • Na Liu
  • Yuzhi Xing
  • Yang Li
Research article
  • 128 Downloads

Abstract

Three novel triazine-based charring-foaming agents (M2-CFA, M4-CFA, and M6-CFA) were synthesized successfully with only water as the solvent and were characterized by FT-IR and thermal gravimetric analysis (TGA). These three charring-foaming agents and the byproduct 944-by were employed to study the effectiveness of the novel intumescent flame retardant dopant on the fire retardancy of polypropylene(PP) investigated through UL-94 and limiting oxygen index (LOI) tests. TGA results showed that the M4-CFA presented good char formation ability (char residue: 26.8% at 700 °C). It was found that the sample with a 2/1 mass ratio of APP to M4-CFA exhibited the best flame retardancy among all the PP composites: 35.5% LOI and a V-0 rating of UL-94. Additionally, the microstructure and morphology of char residues were further studied by XRD, Raman spectroscopy and SEM.

Keywords

Triazine-based charring-foaming agent Intumescent flame retardant Thermal stability Polypropylene 

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Copyright information

© Tianjin University and Springer-Verlag Berlin Heidelberg 2017

Authors and Affiliations

  • Ligong Chen
    • 1
    • 2
  • Yanyan Yuan
    • 1
    • 2
  • Bowei Wang
    • 1
    • 2
  • Na Liu
    • 1
    • 2
  • Yuzhi Xing
    • 1
    • 2
  • Yang Li
    • 1
    • 2
  1. 1.School of Chemical Engineering and TechnologyTianjin UniversityTianjinChina
  2. 2.Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)TianjinChina

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