Skip to main content
Log in

Microstructural and wear properties of the Al-B4C composite coating produced by hot-press sintering on AA-2024 alloy

  • Original Article
  • Published:
Journal of Mechanical Science and Technology Aims and scope Submit manuscript

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

In this study, the surface of an AA-2024 alloy was covered with reinforced composite coating using hotpress sintering method. Al and B4C powders were synthesized through mechanical alloying technique and coated on the AA-2024 substrate at different rates. The microstructure of the intermediate transition region formed between the substrate (AA-2024 Al alloy) and the coating layer (Al/B4C MMCs), the microstructure of the Al/B4C metal matrix composites (MMCs) coating, the microhardness, and the adhesive wear resistance of the Al/B4C MMCs coating layer were investigated. It was observed that B4C powders homogeneously dispersed in the microstructure of the Al/B4C MMCs coating layer, moreover, the Al matrix and B4C reinforcement particles were bonded without a gap. It was also determined that an interface bonding occurred between Al/B4C MMCs coating layer and the AA-2024 substrate. Accordingly, it was determined that with the increase of B4C reinforcement particle ratio, the hardness of the coating layer, and the wear resistance increased.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M. Dilmec, M. Tinkir and H. Arikan, Investigation on influence of conditions of precipitation hardening process on the form-ability of AA2024 alloy, Journal of the Fac. of Eng. and Arch., 30 (2015) 231–248.

    Google Scholar 

  2. S. Buytoz, A. Orhan, A. K. Gur and U. Caligulu, Microstructural development of Fe-Cr-C and B4C powder alloy coating on stainless steel by plasma-transferred arc weld surfacing, Arab. J. Sci. Eng., 38 (2013) 2197–2204.

    Article  Google Scholar 

  3. F. Castillejo, J. Olaya and J. Alfonso, Wear and corrosion resistance of chromium-vanadium carbide coatings produced via thermo-reactive deposition, Coatings, 9 (2019) 1–13.

    Article  Google Scholar 

  4. J. Li, H. Cai, X. Xue and B. Jiang, The outward-inward growth behavior of microarc oxidation coatings in phosphate and silicate solution, Mater. Lett, 64 (2010) 2102–2104.

    Article  Google Scholar 

  5. L. Wen, Y. Wang, Y. Zhou, L. Guo and J. H. Ouyang, Microstructure and corrosion resistance of modified 2024 Al alloy using surface mechanical attrition treatment combined with microarc oxidation process, Corros. Sci., 53 (2011) 473–480.

    Article  Google Scholar 

  6. H. Ni, J. Zhang, S. Lv, X. Wang, Y. Zhu and T. Gu, Preparation and performance optimization of original aluminum ash coating based on plasma spraying, Coatings, 9 (2019) 2–15.

    Article  Google Scholar 

  7. T. Laha, Y. Chen, D. Lahiri and A. Agarwal, Tensile properties of carbon nanotube reinforced aluminum nanocomposite fabricated by plasma spray forming, Compos. Part A Appl. Sci. Manuf., 40 (2009) 589–594.

    Article  Google Scholar 

  8. M. Schem et al., CeO2-filled sol-gel coatings for corrosion protection of AA2024-T3 aluminium alloy, Corros. Sci., 51 (2009) 2304–2315.

    Article  Google Scholar 

  9. T. H. Hu, H. W. Shi, T. Wei, S. H. Fan, F. C. Liu and E. H. Han, Corrosion protection of AA2024-T3 by cerium malate and cerium malate-doped sol-gel coatings, Acta Metall. Sin. (English Lett), 32 (2019) 913–924.

    Article  Google Scholar 

  10. T. Guo, C. Kong, X. Li, P. Guo, Z. Wang and A. Wang, Microstructure and mechanical properties of Ti/Al co-doped DLC films: dependence on sputtering current, source gas, and substrate bias, Appl. Surf. Sci., 410 (2017) 51–59.

    Article  Google Scholar 

  11. S. Zhou, L. Wang and Q. Xue, Controlling friction and wear of nc-WC/a-C(Al) nanocomposite coating by lubricant/additive synergies, Surf. Coatings Technol., 206 (2012) 2698–2705.

    Article  Google Scholar 

  12. K. Feng et al., Improved high-temperature hardness and wear resistance of inconel 625 coatings fabricated by laser cladding, J. Mater. Process. Technol., 243 (2017) 82–91.

    Article  Google Scholar 

  13. D. Zhang et al., Effect of in-situ synthesis of multilayer graphene on the microstructure and tribological performance of laser cladded Ni-based coatings, Appl. Surf. Sci., 495 (2019) 143581.

    Article  Google Scholar 

  14. C. Shang et al., CoCrFeNi (W1 — xMox) high-entropy alloy coatings with excellent mechanical properties and corrosion resistance prepared by mechanical alloying and hot pressing sintering, Mater. Des., 117 (2017) 193–202.

    Article  Google Scholar 

  15. W. Ge et al., Characterization and properties of CuZrAlTiNi high entropy alloy coating obtained by mechanical alloying and vacuum hot pressing sintering, Adv. Powder Technol., 28 (2017) 2556–2563.

    Article  Google Scholar 

  16. C. Shang, E. Axinte, W. Ge, Z. Zhang and Y. Wang, High-entropy alloy coatings with excellent mechanical, corrosion resistance and magnetic properties prepared by mechanical alloying and hot pressing sintering, Surfaces and Interfaces, 9 (2017) 36–43.

    Article  Google Scholar 

  17. M. Yang, C. Xu, C. Wu, K. Lin, Y. J. Chao and L. An, Fabrication of AA6061/Al2O3 nano ceramic particle reinforced composite coating by using friction stir processing, J. Mater. Sci., 45 (2010) 4431–4438.

    Article  Google Scholar 

  18. S. W. Cai, Y. Zong, T. S. Hua and R. G. Song, Study on the inhibition of hydrogen embrittlement of 7050 aluminum alloy in humid air by MAO coating, Anti-Corrosion Methods Mater., 67 (2020) 387–394.

    Article  Google Scholar 

  19. A. P. H. Mindivan, Wear and corrosion resistance of Ni-P coating on AA7075 aluminum alloy, Mach. Technol. Mater., 31 (2016) 29–31.

    Google Scholar 

  20. H. Asgharzadeh and M. Sedigh, Synthesis and mechanical properties of Al matrix composites reinforced with few-layer graphene and graphene oxide, J. Alloys Compd., 728 (2017) 47–62.

    Article  Google Scholar 

  21. T. Yildiz, A. K. Gur and S. Aba, Examination of the wear behavior of Cu-Ni/B4Cp composite by the Taguchi method, Mater. Test., 56 (2014) 1009–1014.

    Article  Google Scholar 

  22. X. Li, Y. Gao, S. Wei and Q. Yang, Tribological behaviors of B4C-hBN ceramic composites used as pins or discs coupled with B4C ceramic under dry sliding condition, Ceram. Int., 43 (2017) 1578–1583.

    Article  Google Scholar 

  23. L. Zhang et al., Microtopography and mechanical properties of vacuum hot pressing Al/B4C composites, Ceram. Int., 44 (2018) 3048–3055.

    Article  Google Scholar 

  24. Y. H. Celik and K. Secilmiş, Investigation of wear behaviours of Al matrix composites reinforced with different B4C rate produced by powder metallurgy method, Adv. Powder Technol., 28 (2017) 2218–2224.

    Article  Google Scholar 

  25. K. S. Kumar and V. S. Patnaik, Experimental investigation on aluminium alloy composites for wear behaviour, International Conference on Electrical, Electronics, and Optimization Techniques (ICEEOT) (2016) 3846–3852.

  26. G. H. Majzoobi and K. Rahmani, Mechanical characterization of Mg-B4C nanocomposite fabricated at different strain rates, Int. J. Miner. Metall. Mater., 27 (2020) 252–263.

    Article  Google Scholar 

  27. A. Singh et al., Effect reinforcement of boron carbide and silicon carbide on AA 2024 hardness, Int. J. Sci. Res. Eng. Trends, 5 (2019) 628–63.

    Google Scholar 

  28. E. B. Moustafa and M. A. Taha, Evaluation of the microstructure, thermal and mechanical properties of Cu/SiC nanocomposites fabricated by mechanical alloying, Int. J. Miner. Metall. Mater., 28 (2020) 475–486.

    Article  Google Scholar 

  29. I. Ovali, H. Karakoç and H. Çinici, Optimization of the wear resistance of AA2024 matrix composites fabricated with hot pressing, J. Achiev. Mater. Manuf. Eng., 79 (2016) 19–23.

    Google Scholar 

  30. M. Rahimian, N. Parvin and N. Ehsani, The effect of production parameters on microstructure and wear resistance of powder metallurgy Al-Al2O3 composite, Mater. Des., 32 (2011) 1031–1038.

    Article  Google Scholar 

  31. C. Saravanan, K. Subramanian, V. Anandakrishnan and S. Sathish, Tribological behavior of AA7075-TiC composites by powder metallurgy, Ind. Lubr. Tribol., 70 (2018) 1066–1071.

    Article  Google Scholar 

  32. Z. C. Feng, Y. F. Liu, Y. Li, G. B. Sun, Z. Zhang and C. X. Shi, Microstructure and high temperature reciprocating sliding wear properties of MoSi2/TiC/Γ-Ni composite coating in-situ synthesized by co-axial powder feeding plasma transferred arc cladding, Tribol. Int., 129 (2018) 82–91.

    Article  Google Scholar 

  33. F. Toptan, A. Kilicarslan, A. Karaaslan, M. Cigdem and I. Kerti, Processing and microstructural characterisation of AA 1070 and AA 6063 matrix B4Cp reinforced composites, Mater. Des., 31 (2010) 87–91.

    Article  Google Scholar 

  34. P. Ashwath et al., Processing and characterization of extruded 2024 series of aluminum alloy, Mater. Today Proc., 5 (2018) 12479–12483.

    Article  Google Scholar 

  35. P. Ashwath, J. Joel, M. A. Xavior and H. G. P. Kumar, Effect of SiC and Al2O3 particles addition to AA 2900 and AA 2024 MMC’s synthesized through microwave sintering, Mater. Today Proc., 5 (2018) 7329–7336.

    Article  Google Scholar 

  36. M. Ferry at al., Techno-economic study of aluminium alloy and steel as materials for deckhouses of offshore support vessels, Indones. J. Nav. Archit., 1 (2013) 36–41.

    Google Scholar 

  37. C.-J. Wang and S.-M. Chen, The high-temperature oxidation behavior of hot-dipping Al-Si coating on low carbon steel, Surf. Coatings Technol., 200 (2006) 6601–6605.

    Article  Google Scholar 

  38. Z. Tang, F. Wang and W. Wu, Effect of a sputtered TiAlCr coating on the oxidation resistance of TiAl intermetallic compound, Oxid. Met., 48 (1997) 511–525.

    Article  Google Scholar 

  39. G. Zhong-Xiang, W. Kai, Z. Yi-Sheng and Z. Bin, Cracking and interfacial debonding of the Al-Si coating in hot stamping of pre-coated boron steel, Appl. Surf. Sci., 316 (2014) 595–603.

    Article  Google Scholar 

  40. I. Topcu, H. O. Gulsoy, N. Kadioglu and A. N. Gulluoglu, Processing and mechanical properties of B4C reinforced Al matrix composites, J. Alloys Compd., 482 (2009) 516–521.

    Article  Google Scholar 

  41. L. Zhang et al., Phase transformation and mechanical properties of B4C/Al composites, J. Mater. Res. Technol., 9 (2020) 2116–2126.

    Article  Google Scholar 

  42. M. Muratoglu and M. Aksoy, The effects of temperature on wear behaviours of Al-Cu alloy and Al-Cu/SiC composite, Mater. Sci. Eng. A, 282 (2000) 91–99.

    Article  Google Scholar 

  43. D. Mummoorthi, M. Rajkumar and S. G. Kumar, Advancement and characterization of Al-Mg-Si alloy using reinforcing materials of Fe2O3 and B4C composite produced by stir casting method, J. Mech. Sci. Technol., 33 (2019) 3213–3222.

    Article  Google Scholar 

  44. P. Larsson, N. Axén and S. Hogmark, Tribofilm formation on boron carbide in sliding wear, Wear, 236 (1999) 73–80.

    Article  Google Scholar 

  45. K. M. Shorowordi, A. S. M. A. Haseeb and J. P. Celis, Tribosurface characteristics of Al-B4C and Al-SiC composites worn under different contact pressures, Wear, 261 (2006) 634–641.

    Article  Google Scholar 

  46. Y. H. Celik and E. Kilickap, Hardness and wear behaviours of al matrix composites and hybrid composites reinforced with B4C and SiC, Powder Metallurgy and Metal Ceramics, 57 (2019) 613–622.

    Article  Google Scholar 

  47. H. Alrobei, Effect of different parameters and aging time on wear resistance and hardness of SiC-B4C reinforced AA6061 alloy, J. Mech. Sci. Technol., 34 (2020) 2027–2034.

    Article  Google Scholar 

  48. J. Zhou, J. Xu, S. Huang, Z. Hu, X. Meng and X. Feng, Effect of laser surface melting with alternating magnetic field on wear and corrosion resistance of magnesium alloy, Surf. Coatings Technol., 309 (2017) 212–219.

    Article  Google Scholar 

  49. T. Courtney, Mechanical Behavior of Materials, McGraw Hill, Michigan (1990).

    Google Scholar 

  50. J.-M. Wu, S.-J. Lin, J.-W. Yeh, S.-K. Chen, Y.-S. Huang and H.-C. Chen, Adhesive wear behavior of AlxCoCrCuFeNi high-entropy alloys as a function of aluminum content, Wear, 261 (2006) 513–519.

    Article  Google Scholar 

Download references

Acknowledgments

This study was funded by the Scientific Research Project Coordination Unit of Firat University Rectorate within the scope of Project No: TEKF. 19.08.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to C. Ozay.

Additional information

Cetin Ozay was born in 1978 in Maden-Elazig. He earned his B.Sc. from Firat University, Faculty of Tech. Education, Mechanical Edu. Dept., Elazig in 2000 and his M.Sc. and Ph.D. from Firat University, Institute of Science, Mechanical Dept., Elazig in 2004 and 2009, respectively. Since 2016, he has been working as an Associate Professor at the Firat University, Turkey. He is specialized in mechanical science, manufacturing, tribology, powder metallurgy, Taguchi, ANOVA.

Hasan Ballikaya was born in 1986 in Elazig. He received his B.Sc. from Firat University, Technical Education Faculty, Elazig in 2009. He also received M.Sc. in 2011 and Ph.D. in 2017 from Firat University, Institute of Science, Mechanical Dept., Elazig, respectively. Since 2018, he has been working as a Doctor at the University of Inonu, Turkey. He is specialized in mechanical science, manufacturing, ANSYS, CAD-CAM, Taguchi, ANOVA.

Fethi Dagdelen was born in 1975 in Palu-Elazig. He earned his B.Sc. from Firat University, Faculty of Science, Department of Physics, Elazig in 1996. He also earned his M.Sc. and Ph.D. from Firat University, Institute of Science, Physics Dept., Elazig in 1999 and in 2004, respectively. He has been working as an Associate Professor at the Firat University, Turkey since 2018. He investigates thermal properties and fabrication of the materials in material science.

Omer Etem Karlidag was born in 1990 in Elazig. He studied at Firat University, Faculty of Engineering, Mechanical Eng. Dept., Elazig in 2014. He received the M.Sc. from Firat University, Institute of Science and Technology, Mechanical Dept., Elazig, Turkey in 2017. He is specialized in manufacturing, powder metallurgy, and tribology.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ozay, C., Ballikaya, H., Dagdelen, F. et al. Microstructural and wear properties of the Al-B4C composite coating produced by hot-press sintering on AA-2024 alloy. J Mech Sci Technol 35, 2895–2901 (2021). https://doi.org/10.1007/s12206-021-0613-1

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12206-021-0613-1

Keywords

Navigation