Abstract
Biodiesel is a renewable, easily biodegradable, eco-friendly and sustainable alternative energy source. In this investigation, crude oil was extracted from Spirulina maxima microalgae through biochemical conversion method with the help of soxhlet apparatus. Biodiesel production process parameters were optimized through base transesterification. Maximum biodiesel yield achieved was 87.75 % at optimal reaction condition after transesterification, when methanol to oil ratio was 6:1, catalyst loading was 1 % KOH (wt.%), temperature was 65 °C, and stirring speed was 600 rpm for a reaction time of 70 minutes. All the physicochemical properties of the produced biodiesel were determined and compared with the ASTM D6751 specification. Finally, performance and emission of an unmodified diesel engine was evaluated with 20 % and 40 % (v/v) biodiesel blends and compared the results with ordinary Diesel fuel (DF). Using biodiesel blends improves Hydrocarbon (HC) emission by 10-15 % and Carbon monoxide (CO) emission by 9.3-13.9 %. However, Brake specific fuel consumption (BSFC), Oxides of nitrogen (NOX), Carbon dioxide (CO2) and smoke opacity were found to be slightly higher for biodiesel blends, and Brake thermal efficiency (BTE) was found slightly lower than DF. Thus, Spirulina maxima serves as a potential feedstock for biodiesel production and prospective fuel in diesel engine application.
Similar content being viewed by others
References
M. A. Rahman, A. M. Ruhul, M. A. Aziz and R. Ahmed, Experimental exploration of hydrogen enrichment in a dual fuel CI engine with exhaust gas recirculation, International J. of Hydrogen Energy, 42 (2017) 5400–5409.
S. S. M. Mostafa and N. S. El-Gendy, Evaluation of fuel properties for microalgae Spirulina platensis bio-diesel and its blends with Egyptian petro-diesel, Arabian J. of Chemistry (2013) 10.1016/j.arabjc.2013.07.034.
H. I. El-Shimi, N. K. Attia, S. T. El-Sheltawy and G. I. El-Diwani, Biodiesel production from Spirulina-Platensis microalgae by in-situ transesterification process, J. of Sustainable Bioenergy Systems, 3 (2013) 224–233.
P. Tsaousis, Y. Wang, A. P. Roskilly and G. S. Caldwell, Algae to energy: Engine performance using raw algal oil, Energy Procedia, 61 (2014) 656–659.
R. Velappan and S. Sivaprakasam, Investigation of single cylinder diesel engine using bio diesel from marine algae, International J. of Innovative Science, Engineering & Technology, 1 (2014) 399–403.
H. M. El-Mashad, R. Zhang and R. J. Avena-Bustillos, A two-step process for biodiesel production from salmon oil, Biosystems Engineering, 99 (2) (2008) 220–227.
S. Zheng, M. Kates, M. A. Dubé and D. D. McLean, Acidcatalyzed production of biodiesel from waste frying oil, Biomass and Bioenergy, 30 (2006) 267–272.
T. Suganya, N. N. Gandhi and S. Renganathan, Production of algal biodiesel from marine macroalgae Enteromorpha compressa by two step process: Optimization and kinetic study, Bioresource Technology, 128 (2013) 392–400.
A. N. Phan and T. M. Phan, Biodiesel production from waste cooking oils, Fuel, 87 (2008) 3490–3496.
A. Abuhabaya, J. Fieldhouse and D. Brown, The effects of using biodiesel on CI (compression ignition) engine and optimization of its production by using response surface methodology, Energy, 59 (2013) 56–62.
D. Y. C. Leung and Y. Guo, Transesterification of neat and used frying oil: Optimization for biodiesel production, Fuel Processing Technology, 87 (10) (2006) 883–890.
L. C. Meher, V. S. S. Dharmagadda and S. N. Naik, Optimization of alkali-catalyzed transesterification of Pongamia pinnata oil for production of biodiesel, Bioresource Technology, 97 (12) (2006) 1392–1397.
U. Rashid and F. Anwar, Production of biodiesel through optimized alkaline-catalyzed transesterification of rapeseed oil, Fuel, 87 (3) (2008) 265–273.
G. Vicente, M. Martínez and J. Aracil, Optimization of Brassica carinata oil methanolysis for biodiesel production, J. of the American Oil Chemists’ Society, 82 (12) (2005) 899–904.
M. N. Nabi, M. S. Akhter and M. A. Rahman, Waste transformer oil as an alternative fuel for diesel engine, Procedia Engineering, 56 (2013) 401–406.
G. Tüccar and K. Aydin, Evaluation of methyl ester of microalgae oil as fuel in a diesel engine, Fuel, 112 (2013) 203–207.
D. Yuvarajan and M. Venkata Ramanan, Experimental analysis on neat mustard oil methyl ester subjected to ultrasonication and microwave irradiation in four stroke single cylinder Diesel engine, J. of Mechanical Science and Technology, 30 (1) (2016) 437–446.
H. Aydin and H. Bayindir, Performance and emission analysis of cottonseed oil methyl ester in a diesel engine, Renewable Energy, 35 (3) (2010) 588–592.
M. N. Nabi, M. M. Rahman and M. S. Akhter, Biodiesel from cotton seed oil and its effect on engine performance and exhaust emissions, Applied Thermal Engineering, 29 (2009) 2265–2270.
M. I. Al-Widyan, G. Tashtoush and M. Abu-Qudais, Utilization of ethyl ester of waste vegetable oils as fuel in diesel engines, Fuel Processing Technology, 76 (2) (2002) 91–103.
G. Paul, A. Datta and B. K. Mandal, An experimental and numerical investigation of the performance, combustion and emission characteristics of a diesel engine fueled with jatropha biodiesel, Energy Procedia, 54 (2014) 455–467.
R. Kumar, M. K. Mishra, S. K. Singh and A. Kumar, Experimental evaluation of waste plastic oil and its blends on a single cylinder diesel engine, J. of Mechanical Science and Technology, 30 (10) (2016) 4781–4789.
A. S. Ramadhas, C. Muraleedharan and S. Jayaraj, Performance and emission evaluation of a diesel engine fueled with methyl esters of rubber seed oil, Renewable Energy, 30 (12) (2005) 1789–1800.
Author information
Authors and Affiliations
Corresponding author
Additional information
Recommended by Associate Editor Jeong Park
M. A. Rahman received his B.Sc. in Mechanical Engineering from Rajshahi University of Engineering and Technology (RUET), Bangladesh. His research interest includes biodiesel research, IC engine combustion and emissions, combustion in IC engine and pyrolysis technology.
Rights and permissions
About this article
Cite this article
Rahman, M.A., Aziz, M.A., Ruhul, A.M. et al. Biodiesel production process optimization from Spirulina maxima microalgae and performance investigation in a diesel engine. J Mech Sci Technol 31, 3025–3033 (2017). https://doi.org/10.1007/s12206-017-0546-x
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12206-017-0546-x