Abstract
In the past decade Fe-based bulk metallic glasses (BMGs) have attracted increasing attention due to their beneficial properties, including high glass forming ability (GFA), high strength and hardness and high fracture toughness in both fundamental science and engineering application. Most research using these materials has been conducted at room temperature environment, and research that assesses their behavior especially at high temperature has been scarce. We present the results of high temperature effect on the friction and wear behavior of Fe-based bulk metallic glass (BMG), and we tested that this material may satisfy wear and oxidation resistance at high temperature as well as to explore the high temperature wear mechanism of the Fe-based BMG. The dry sliding tribological behaviors of Febased BMG against Si3N4 ceramic were conducted with a pin-on-disc friction and wear tribometer. The morphology of the worn surfaces of Fe-based BMG was examined by scanning electron microscopy (SEM) and the chemical composition characterized with energy dispersive spectroscopy (EDS) to observe the wear characteristics and investigate the wear mechanisms. The overall average friction coefficient value generally decreased with increasing temperature, and the glass transition and the formation of protective oxide film played an important role in the tribological behavior of BMG. The wear resistance of Fe-based BMG was not only from their hardness but also from the formation protective oxide layer. Analysis of the worn surface revealed abrasion, plastic deformation and oxidation during sliding test.
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J. G. Wang, B. W. Choi and T. G. Nieh, Nano-scratch behavior of a bulk Zr-10Al-5Ti-17.9Cu-14. 6Ni amorphous alloy, Journal of Material Research, 15(4) (2000) 913–922.
N. H. Tariq, B. A. Hasan, J. I. Akhter and F. Ali, Mechanical and tribological properties of Zr-Al-Ni-Cu bulk metallic glasses, Journal Alloys and Compounds, 469(1–2) (2009) 179–185.
H. X. Li and S. Yi, Corrosion behavior of bulk metallic glasses Fe66.7C7.0Si3.3B5.5P8.7Cr2.3Al2.0Mo4.5 having different crystal volume fractions, Materials Chemistry and Physics, 112(1) (2008) 305–309.
D. Zenebe, S. Yi and S. S. Kim, Sliding friction and wear behavior of Fe-based bulk metallic glass in 3.5% NaCl solution, Journal Material Science, 47(3) (2012) 1446–1451.
B. Prakash and K. Hiratsuka, Sliding wear behaviour of some Fe, Co and Ni based metallic glasses while rubbing against bearing steel, Tribology Letters, 8(2–3) (2000) 153–160.
D. H. Kwon, E. S. Park, M. Y. Huh, H. J. Kim and J. C. Bae, Wear behavior of Fe-based bulk metallic glass composites, Journal Alloys and Compounds, 509(1) (2011) 105–108.
S. Yoon, J. Kim, G. Bae, B. Kim and C. Lee, Formation of coating and tribological behavior of kinetic sprayed Fe-based bulk metallic glass, Journal Alloys and Compounds, 509(2) (2011) 347–353.
B. T. Jang, S. H. Yi and S. S. Kim, Tribological behavior of Fe-based bulk metallic glass, Journal of Mechanical Science and Technology, 24 (2010) 89–92.
H. Li and S. Yi, Fabrication of bulk metallic glasses in the alloy system Fe-C-Si-B-P-Cr-Mo-Al using hot metal and industrial ferro-alloys, Materials Science & Engineering A, 449–451(1) (2007) 189–192.
T. Murakami, J. H. Ouyang, S. Sasaki, K. Umeda and Y. Yoneyama, High-temperature tribological properties of spark-plasma-sintered Al2O3 composites containing baritetype structure sulfates, Tribology International, 40(2) (2007) 246–253.
Q. Bi, W. Liu, J. Yang, J. Ma and Q. Xue, Tribological properties of Ni-17.5Si-29.3Cr alloy at room and elevated temperatures, Tribology International, 43(1–2) (2010) 136–143.
J. Jayaraj, Y. C. Kim, K. B. Kim, H. K. Seok and E. Fleury, Corrosion behaviors of Fe45−x Cr18Mo14C15B6Y2Mx (M = Al, Co, Ni, N and x = 0, 2) bulk metallic glasses under conditions simulating fuel cell environment, Journal Alloys and Compounds, 434–435 (2007) 237–239.
H. W. Jin, R. Ayer, J. Y. Koo, R. Raghavan and U. Ramamurty, Reciprocating wear mechanisms in a Zr-based bulk metallic glass, Journal of Material Research, 22(2) (2007) 264–273.
Z. Parlar, M. Bakkal and A. J. Shih, Sliding tribological characteristics of Zr-based bulk metallic glass, Intermetallics, 16(1) (2008) 34–41.
X. Y. Fu, T. Kasai, M. L. Falk and D. A. Rigney, Sliding behavior of metallic glass: Part I. Experimental investigations, Wear, 250(1–12) (2001) 409–419.
P. J. Tao, Y. Z. Yang and Q. Ru, Effect of rotational sliding velocity on surface friction and wear behavior in Zr-based bulk metallic glass, Journal Alloys and Compounds, 492(1–2) (2010) 36–39.
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Dawit Zenebe Segu received his M.S. degree in Mechanical Engineering from Kyungpook National University in 2011. He is currently in a doctoral course at the same department, Kyungpook National University in Daegu, Korea. His research interests in the area of surface engineering and tribology.
Jae-Hyouk Choi is associate professor of Chosun University. He received his B.E. and M.S. from Kyungpook National University, Korea. He received Dr of Engineering from Tokyo University, Japan, in 2003. He is currently engaged on a large government funded research project on the development of Smart Green Construction Technology as well as being involved in ongoing development of the steel seismicresisting system of buildings.
Seock-Sam Kim received his B.S. and M.S. in Mechanical Engineering from Kyungpook National University, Korea, in 1973 and 1976, respectively. He received his Ph.D in Mechanical Engineering from Tohoku University in 1987. He is currently a Professor at the school of Mechanical Engineering, Kyungpook National University, Korea. His research interests are in the area of fracture mechanics and tribology.
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Segu, D.Z., Choi, JH. & Kim, SS. Sliding wear behavior of Fe-based bulk metallic glass at high temperature. J Mech Sci Technol 26, 3565–3570 (2012). https://doi.org/10.1007/s12206-012-0855-z
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DOI: https://doi.org/10.1007/s12206-012-0855-z